Detailed table of contents (pdf)

XLVI Table of Contents
17.4.5.2.1.5 Of Six-Membered Arenes .................................................. 776
17.4.5.2.1.5.1 Method 1: Intramolecular Insertion of Arylnitrenes .................... 776
17.4.5.2.1.5.1.1 Variation 1: Thermal Decomposition of Aryl Azides ..................... 776
17.4.5.2.1.5.1.2 Variation 2: Photolytic Decomposition of Aryl Azides ................... 778
17.4.5.2.1.5.1.3 Variation 3: Deoxygenation of Nitrosoarenes ........................... 783
17.4.5.2.1.5.1.4 Variation 4: Deoxygenation of Nitroarenes ............................. 784
17.4.5.2.1.5.1.5 Variation 5: Thermal Decomposition of N-Phenyl-N,O-bis(trimethylsilyl)hydroxylamine
........................................ 787
17.4.5.2.1.5.2 Method 2: From the Insertion of Nitrenes into Arenes ................. 787
17.4.5.2.1.5.2.1 Variation 1: Thermolysis of Azidoformates ............................. 788
17.4.5.2.1.5.2.2 Variation 2: Pyrolysis of 2-Haloindan-1-yl Azidoformates ................ 790
17.4.5.2.1.5.2.3 Variation 3: Photolysis of Azidoformates ............................... 791
17.4.5.2.1.5.2.4 Variation 4: Decomposition of N-[(4-Nitrophenyl)sulfonyloxy]carbamates 792
17.4.5.2.1.5.2.5 Variation 5: Thermolysis of Arenesulfonyl Azides ........................ 792
17.4.5.2.1.5.2.6 Variation 6: Reaction of Phthalimidonitrene with Activated Benzenes .... 796
17.4.5.2.1.5.2.7 Variation 7: Thermolysis of Cyanogen Azide ............................ 796
17.4.5.2.1.5.2.8 Variation 8: Deoxygenation of Nitrosobenzenes and Nitrosoformates .... 797
17.4.5.2.1.5.2.9 Variation 9: Photolysis of 2-Azido-1,3,5-triazines ....................... 798
17.4.5.2.1.5.3 Method 3: From Anilides ............................................. 798
17.4.5.3 Aromatization ............................................................ 800
17.4.5.3.1 Method 1: Isomerization with Meerwein s Reagent .................... 800
17.4.5.3.1.1 Variation 1: Of 1,5-Dihydro-2H-azepin-2-ones .......................... 800
17.4.5.3.1.2 Variation 2: Of 1,2-Dihydro-3H-azepin-3-ones .......................... 801
17.4.5.3.2 Method 2: Bromination–Dehydrobromination of
4-Ethoxy-1,2,6,7-tetrahydrocyclopent[d]azepine ............ 801
17.4.5.3.3 Method 3: Dehydrobromination of 3,6-Dibromo-1-phenyl-2,3,6,7tetrahydro-1H-phosphepin
1-Oxide ........................ 802
17.4.5.4 Synthesis by Substituent Modification ..................................... 803
17.4.5.4.1 Substitution of Existing Substituents ....................................... 803
17.4.5.4.1.1 Of Hydrogen .............................................................. 803
17.4.5.4.1.1.1 Method 1: Tautomerization .......................................... 803
17.4.5.4.1.1.1.1 Variation 1: Rearrangement of 1H- to3H-Azepines ..................... 803
17.4.5.4.1.1.1.2 Variation 2: Rearrangement of 2H- to3H-Azepines ..................... 804
17.4.5.4.1.1.1.3 Variation 3: Rearrangement of 4H- to3H-Azepines ..................... 805
17.4.5.4.1.1.1.4 Variation 4: Rearrangement of 3H- to3H-Azepines ..................... 805
17.4.5.4.1.1.2 Method 2: Metalation ................................................ 807
17.4.5.4.1.1.3 Method 3: C-Acylation ............................................... 807
17.4.5.4.1.1.4 Method 4: C-Alkylation .............................................. 808
17.4.5.4.1.1.5 Method 5: C-Halogenation ........................................... 810
17.4.5.4.1.1.6 Method 6: C-Thiolation .............................................. 811
17.4.5.4.1.1.7 Method 7: C-Amination .............................................. 811
17.4.5.4.1.1.8 Method 8: N-Substitution ............................................ 812
17.4.5.4.1.2 Of Carbon Functionalities ................................................. 812
17.4.5.4.1.2.1 Method 1: N-Decarboxylation ........................................ 812
17.4.5.4.1.3 Of Heteroatoms .......................................................... 813