Detailed table of contents (pdf)

Table of Contents XLI
17.4.2.2.2.2 Method 2: Of 2-Benzofuran-1(3H)-ones ............................... 677
17.4.2.2.2.3 Method 3: Of 1,4-Dihydronaphthalene ................................ 677
17.4.2.2.2.4 Method 4: Of 1-Acetoxy-2,4-dibromotetrahydronaphthalenes ......... 678
17.4.2.2.2.5 Method 5: Of 2H-Benzopyrans ........................................ 678
17.4.2.2.2.6 Method 6: Of Xanthenes ............................................. 680
17.4.2.2.2.6.1 Variation 1: By Addition of Diazomethane .............................. 680
17.4.2.2.2.6.2 Variation 2: By Dehydration ........................................... 680
17.4.2.3 Aromatization ............................................................ 680
17.4.2.3.1 Method 1: By Dehydrohalogenation .................................. 681
17.4.2.3.2 Method 2: By Dehalogenation ........................................ 683
17.4.2.3.3 Method 3: By Dehydration ........................................... 683
17.4.2.3.3.1 Variation 1: Of Secondary Alcohols .................................... 683
17.4.2.3.3.2 Variation 2: Of Tertiary Alcohols ....................................... 685
17.4.2.3.4 Method 4: By Deamination ........................................... 686
17.4.2.3.4.1 Variation 1: Of Quaternary Ammonium Salts (Hofmann Degradation) ... 686
17.4.2.3.4.2 Variation 2: Of N-Oxides (Cope Elimination) ............................ 687
17.4.2.3.4.3 Variation 3: Of Acetylamines .......................................... 687
17.4.2.3.5 Method 5: By Decarbonylation ....................................... 688
17.4.2.4 Synthesis by Substituent Modification ..................................... 688
17.4.2.4.1 Substitution of Existing Substituents ....................................... 688
17.4.2.4.1.1 Of Hydrogen .............................................................. 688
17.4.2.4.1.1.1 Method 1: By Deuteration or by Nitration ............................. 688
17.4.2.4.1.2 Of Carbon Functionalities ................................................. 689
17.4.2.4.1.2.1 Method 1: By Decarboxylation ....................................... 689
17.4.2.4.1.3 Of Heteroatoms .......................................................... 689
17.4.2.4.1.3.1 Method 1: Substitution of Halogen ................................... 689
17.4.2.4.1.3.1.1 Variation 1: Of Bromine ............................................... 689
17.4.2.4.1.3.1.2 Variation 2: Of Amino Groups ......................................... 691
17.4.2.4.1.3.1.3 Variation 3: Of Hydroxy Groups ........................................ 691
17.4.2.4.2 Addition Reactions ....................................................... 694
17.4.2.4.2.1 Of Benzoxepinones and Benzoxepindiones ................................. 694
17.4.2.4.2.1.1 By O-Alkylation ........................................................... 694
17.4.2.4.2.1.1.1 Method 1: O-Methylation of 1-Benzoxepin-3(2H)-ones and
1-Benzoxepin-5(4H)-ones .................................. 694
17.4.2.4.2.1.1.2 Method 2: O-Methylation of 1-Benzoxepin-3,5(2H,4H)-diones .......... 695
17.4.2.4.2.1.1.3 Method 3: O-Ethylation of Dibenz[b,f]oxepin-10(11H)-ones ............ 696
17.4.2.4.2.1.1.4 Method 4: O-Methylation of 11-Hydroxydibenz[b,f]oxepin-10(11H)-one . 697
17.4.2.4.2.1.2 By O-Acylation ............................................................ 697
17.4.2.4.2.1.2.1 Method 1: O-Acetylation of 2,3-Dihydro-1-benzoxepin-3-ones and
2,5-Dihydro-1-benzoxepin-5-ones .......................... 697
17.4.2.4.2.1.2.2 Method 2: O-Acetylation of Benzoxepindiones and Dibenzoxepindiones 698