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Design specific variation in pattern transfer by via/contact etch ...

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Intra-Feature Radical Transport Resistance<br />

Mechanisms of the neutrals transport <strong>in</strong>side a feature:<br />

• The “l<strong>in</strong>e-of-sight” – reagents are disappeared after first collision with wall<br />

• “Knudsen diffusion” – reagents do not react with walls<br />

For Knudsen diffusion - Claus<strong>in</strong>g factor is the probability that<br />

a randomly directed species <strong>in</strong>cident at the top of a verticalwalled<br />

feature will reach the other end.<br />

For the Claus<strong>in</strong>g factor k we can use :<br />

1<br />

for round <strong>via</strong> of the depth L and radius R k =<br />

1<br />

3 PL<br />

1+<br />

16 S<br />

3 L<br />

1+<br />

8 R<br />

And k = for the rectangular shaped feature of the<br />

perimeter P, area S and the depth L.<br />

CF 2 flux imp<strong>in</strong>ged the <strong>via</strong> bottom<br />

2π<br />

λ<br />

π<br />

c λ<br />

⎛ 2 R<br />

B 1 CF<br />

⎜<br />

2<br />

Γ =<br />

N CF ( r1<br />

, ϕ )<br />

2<br />

2 2<br />

2<br />

3 h<br />

1 k<br />

8π<br />

R ∫∫<br />

⎜ ∫∫<br />

+<br />

0 0 ⎜<br />

D<br />

8 R<br />

⎝<br />

rdrdψ<br />

2 2 2 [ λ + r + r − 2r<br />

r cos(<br />

ϕ −ψ<br />

) ]<br />

⎞<br />

⎟<br />

⎟r1dr<br />

dϕ<br />

⎟<br />

⎠<br />

CF 3 1<br />

0 0<br />

1<br />

1<br />

2<br />

2π<br />

⎝<br />

B cO<br />

( )<br />

( h + λ)<br />

ΓO r,<br />

ψ = ∫ ∫<br />

8π<br />

0<br />

⎛ λ ⎞<br />

R⎜1+<br />

⎟<br />

h ⎠<br />

0<br />

N<br />

O-atom flux imp<strong>in</strong>ged the <strong>via</strong> bottom<br />

O<br />

( r , ϕ)<br />

1<br />

⎡<br />

⎢<br />

⎢⎣<br />

λ<br />

h<br />

ψ<br />

Reactiv<br />

e<br />

surface<br />

r<br />

r<br />

1<br />

θ<br />

Copyright ©2008, Mentor Graphics.<br />

2<br />

r<br />

1<br />

2<br />

( ) ( ) 2<br />

2 2 2⎛<br />

⎞ ⎛ ⎞<br />

h + λ + r + r 1+<br />

+ 2r<br />

r 1+<br />

cos ϕ −ψ<br />

1<br />

⎜<br />

⎝<br />

r dϕdr<br />

1<br />

λ<br />

⎟<br />

h ⎠<br />

1<br />

1<br />

⎜<br />

⎝<br />

ϕ<br />

λ<br />

⎟<br />

h ⎠<br />

12<br />

⎤<br />

⎥<br />

⎥⎦<br />

3

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