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Prof. Dr. Jürgen Röpcke "On Recent Progress in diagnostics of ...

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EINLADUNG ZUM<br />

INSTITUTSKOLLOQUIUM<br />

<strong>Pr<strong>of</strong></strong>. <strong>Dr</strong>. <strong>Jürgen</strong> <strong>Röpcke</strong><br />

INP Greifswald and neoplas control GmbH<br />

IGAFA<br />

"<strong>On</strong> <strong>Recent</strong> <strong>Progress</strong> <strong>in</strong> <strong>diagnostics</strong> <strong>of</strong><br />

molecular plasmas and <strong>in</strong> Trace Gas Detection<br />

us<strong>in</strong>g Infrared techniques”<br />

Datum: Donnerstag, 1. März 2007<br />

Zeit: 15 Uhr<br />

Ort: WISTA-Gelände, Berl<strong>in</strong>-Adlersh<strong>of</strong><br />

Wilhelm-Ostwald-Straße 3 (IBZ)<br />

(Querstraße Am Studio, ehemals Agastraße)<br />

12489 Berl<strong>in</strong><br />

Gäste s<strong>in</strong>d herzlich willkommen !


ABSTRACT<br />

ON RECENT PROGRESS IN DIAGNOSTICS OF MOLECULAR<br />

PLASMAS AND IN TRACE GAS DETECTION USING INFRARED<br />

TECHNIQUES<br />

J. <strong>Röpcke</strong><br />

INP Greifswald, 17489 Greifswald, Germany<br />

With<strong>in</strong> the last decade mid <strong>in</strong>frared absorption spectroscopy over the region<br />

from 3 to 17µm and based on tuneable lead salt diode lasers, <strong>of</strong>ten called Tuneable<br />

Diode Laser Absorption Spectroscopy or TDLAS, has progressed considerably as a<br />

powerful diagnostic technique for <strong>in</strong> situ studies <strong>of</strong> the fundamental physics and<br />

chemistry <strong>in</strong> molecular plasmas and for trace gas detection. The <strong>in</strong>creas<strong>in</strong>g <strong>in</strong>terest<br />

<strong>in</strong> process<strong>in</strong>g plasmas conta<strong>in</strong><strong>in</strong>g hydrocarbons, fluorocarbons, organo-silicon and<br />

boron compounds and <strong>in</strong> trace gas problems has lead to further applications <strong>of</strong><br />

TDLAS because most <strong>of</strong> these compounds and their decomposition products are<br />

<strong>in</strong>frared active. S<strong>in</strong>ce plasmas with molecular feed gases are used <strong>in</strong> many<br />

applications such as th<strong>in</strong> film deposition, semiconductor process<strong>in</strong>g, surface<br />

activation and clean<strong>in</strong>g, and materials and waste treatment, this has stimulated the<br />

adaptation <strong>of</strong> <strong>in</strong>frared spectroscopic techniques to <strong>in</strong>dustrial requirements. The<br />

recent development <strong>of</strong> Quantum Cascade Lasers (QCL) <strong>of</strong>fers an attractive new<br />

option for fundamental studies and for the monitor<strong>in</strong>g and control <strong>of</strong> <strong>in</strong>dustrial plasma<br />

processes. The aim <strong>of</strong> the present paper is threefold: (i) to review recent<br />

achievements <strong>in</strong> our understand<strong>in</strong>g <strong>of</strong> molecular phenomena <strong>in</strong> plasmas and gases,<br />

(ii) to report on selected studies <strong>of</strong> the spectroscopic properties and k<strong>in</strong>etic behaviour<br />

<strong>of</strong> radicals, and (iii) to describe the current status <strong>of</strong> advanced <strong>in</strong>strumentation for<br />

TDLAS and QCLAS <strong>in</strong> the mid <strong>in</strong>frared.

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