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BioSciences - Polysciences, Inc.

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Poly(ethylene/vinyl alcohol) [25067-34-9] A2g<br />

TSCA (-CH2CH2-)x[-CH2CH(OH)-]y<br />

Polymer containing both hydrophilic and hydrophobic segments . Could be used to prepare other<br />

ethylene copolymers . Used in packaging films .<br />

Polymers<br />

Catalog Size<br />

85:15 (wt) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18099-25 25 g<br />

74:26 (wt) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18100-25 25 g<br />

44:56 (wt) d 1 .14 Tg 61° mp 164° Soluble in: DMF, DMSO, n-propanol . . . . . . . . . . . . . . . 17402-25 25 g<br />

74:26 (wt) d 1 .19 Tg 69° mp 181° Soluble in: DMF, DMSO, n-propanol . . . . . . . . . . . . . . . 17403-25 25 g<br />

Poly(ethylene/maleic anhydride) 1:1 (molar) [9006-26-2] H3g . . . . . . . . . . . . . . . . . . . . . .<br />

MW 400,000 Viscosity 2% 5cps TSCA<br />

Reactive with alcohols, amines . Hydrolyzes in water to a water-soluble anionic polymer .<br />

Polyethylenimine Linear [9002-98-6]<br />

TSCA (C 2 H 5 N) x<br />

All-secondary amine polymer, unlike branched polyethylenimines which contain<br />

primary, secondary and tertiary amino groups and are liquids at all molecular<br />

weights . Soluble in hot water, cold water at low pH, methanol, and ethanol .<br />

Insoluble in benzene, ethyl ether, acetone, and cold water .<br />

Contains up to 7-8% of poly(2-ethyl-2-oxazoline) .<br />

MW 2,500 mp 73-79° powder U5g . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24313-2 2 g<br />

MW 25,000 mp 73-75° powder H5g . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23966-2 2 g<br />

MW 250,000 mp ~72° powder U5g . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24314-2 2 g<br />

Polyethylenimine “Max” High Potency Linear PEI [9002-98-6] H6g<br />

A nearly fully hydrolyzed linear polyethylenimine with longer contiguous<br />

ethyleneimine segments . Although N-deacylation reactions are notoriously<br />

difficult, our new linear polyethylenimine material is believed to contain<br />

more than 11% additional free (protonatable) nitrogens than our standard<br />

linear polyethylenimine material . Easy to handle hydrochloride salt form .<br />

Insoluble in common organic solvents (ethanol, acetone, tetrahydrofuran)<br />

Soluble in: cold and room temperature water .<br />

Polyethylenimine “Max” (MW 4,000*) nominal (Equivalent to MW ~2,500 in Free Base Form) . . . . . . .<br />

White to off-white free flowing solid TSCA<br />

Molecular Weight: ~2,500 Mw in free base form . Nominal 4,000 Mw in hydrochloride salt form .<br />

Comparable to Cat . #24313 - Polyethylenimine, Linear, Mw 2,500 which is not in the hydrochloride<br />

salt form .<br />

(Equivalent to MW ~2,500 in Free Base Form)<br />

Elemental Analysis (Mw 4,000)<br />

%C %H %N %Cl Total<br />

Theoretical* 28 .6 7 .8 16 .7 42 .2 95 .30<br />

Found 28 .99 7 .47 16 .52 42 .06 95 .042<br />

(*based on 5 .4% water content)<br />

104.9<br />

104<br />

102<br />

100<br />

98<br />

96<br />

104<br />

92<br />

90<br />

88<br />

86<br />

84<br />

82<br />

80<br />

78<br />

76<br />

74<br />

72<br />

70<br />

68<br />

% Transmittance<br />

2980<br />

2950<br />

66<br />

65.1<br />

4000.0 3000<br />

Cl-<br />

H<br />

+<br />

N<br />

H<br />

2034<br />

Wave Number<br />

Cl- H<br />

+<br />

N<br />

H<br />

1699<br />

1558<br />

668 558<br />

1354<br />

955<br />

818<br />

1282<br />

764<br />

1061<br />

1476<br />

2000 1500 1000 540.0<br />

n<br />

02308-50 50 g<br />

24885-2 2 g<br />

For more information please call (800) 523-2575 or visit: polysciences.com 191

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