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BioSciences - Polysciences, Inc.

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Monomers<br />

N-[3-(N,N-Dimethylamino)propyl]methacrylamide [5205-93-6] BH4g . . . . . . . . . . . . . . . .<br />

MW 170 .3 bp 141°/2mm n 20<br />

D 1 .479 600-750ppm MEHQ TSCA<br />

H 2 C=C(CH 3 )CONH(CH 2 ) 3 N(CH 3 ) 2<br />

For preparation of cationic polymers, especially quaternary ammonium<br />

polymers . Monomer is more hydrolytically stable than corresponding esters .<br />

3-Dimethylamino neopentyl acrylate EHVWX6d . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<br />

MW 185 .3 bp 53°/1 .4mm n 20<br />

D 1 .439 100 MEHQ<br />

Amine containing monomer . For preparation of polymers containing<br />

tertiary amine functionality .<br />

N,N-Dimethylmethacrylamide [6976-91-6] U4d . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<br />

MW 113 .2 bp 65-67°/10mm n 20<br />

D 1 .460 100 ppm MEHQ<br />

(H 3 C) 2 NHCOC(CH 3 )=CH 2<br />

Substituted amide monomer .<br />

2,2-Dimethylpropanediol dimethacrylate [1985-51-9] EHOV7d . . . . . . . . . . . . . . . . . . . . .<br />

MW 240 .3 bp 112°/1 .2mm n 20<br />

D 1 .453 60 ppm MEHQ TSCA<br />

[H 2 C=C(CH 3 )CO 2 CH 2 ] 2 C(CH 3 ) 2<br />

Crosslinking monomer .<br />

Dipentaerythritol pentaacrylate (mixture of tetra-, penta-, hexaacrylate)<br />

[60506-81-2] HO5g . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<br />

MW 524 .5 n 20<br />

D 1 .490 270 ppm MEHQ Tg 90° TSCA<br />

O[CH 2 C(CH 2 OR) 23 ] 2 R=COCH=CH 2<br />

Highly efficient crosslinking monomer, used especially in UV curing coatings .<br />

N-Diphenylmethylacrylamide [10254-08-7] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<br />

MW 237 .3 bp 178° n 20<br />

D 1 .448 50 ppm MEHQ<br />

(C 6 H 5 ) 2 NCOC(CH 3 )=CH 2<br />

Bulky arylalkyl-substituted amide monomer .<br />

New! Divinyl Adipate [4074-90-2] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<br />

MW 198 .22 mp 28° C (freezing point) MEHQ C H O 10 14<br />

O<br />

Divinyl adipate is a reactive double vinyl ester that can be used as<br />

O<br />

a crosslinker to crosslink hydroxyl containing polymers . It has been<br />

O<br />

used to synthesize biodegradable hydrogels and other crosslinked<br />

O<br />

biodegradable polymers .<br />

For use as a linker to synthesize biodegradable block copolymers of poly[(R)-3-hydroxybutyrate] diol and poly[(R)-3-hydroxyoctanoate]<br />

diol, see: “Enzyme-Catalyzed Polycondensation of Polyester Macrodiols with Divinyl Adipate: A Green Method for the<br />

Preparation of Thermoplastic Block Copolyesters” Dai, S.; et al. Biomacromolecules, 2009, 10 (12), pp 3176–3181 For use as a<br />

crosslinker to make biodegradable glycol chitosan hydrogels, see: “Facile Preparation of Biodegradable Glycol Chitosan Hydrogels<br />

Using Divinyladipate as a Crosslinker” Kim, B.S.; et al. Macromolecular Research, Vol. 17, No. 10, pp 734-738 (2009)<br />

Divinyl glycol [1069-23-4] H4g . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<br />

(1,5-hexadiene-3,4-diol) MW 114 .1 bp 89-90°/8mm n 20<br />

D 1 .479<br />

0 .25% BHT inhibitor<br />

Crosslinking monomer .<br />

Divinyl sebacate [10355-50-7] A2d . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .<br />

MW 254 .3 bp 142-144°/3mm n 20<br />

D 1 .454 120 ppm HQ<br />

[H 2 C=CHO 2 C(CH 2 ) 4 ] 2<br />

Crosslinking vinyl ester monomer .<br />

CH 3<br />

O<br />

(H3C)2NCH2CCH2OCCH<br />

CH3<br />

CH2<br />

Catalog Size<br />

09656-100 100 g<br />

17970-10 10 g<br />

02270-25 25 g<br />

02276-100 100 g<br />

16311-500 500 g<br />

19663-5 5 g<br />

25338-100 1 g<br />

18252-25 25 g<br />

04632-5 5 g<br />

For more information please call (800) 523-2575 or visit: polysciences.com 139

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