BioSciences - Polysciences, Inc.

Monomers
New! 1-(Acryloyloxy)-3-(Methacryloyloxy)-2-Propanol [1709-71-3] . . . . . . . . . . . . . . . . . .
MW 214 .22 n 20
D 1 .473 200 ppm MEHQ d 1 .14 g/mL at 25º C
Colorless to pale yellow viscous liquid
Will increase the hydrophilic properties of polymers when copolymerized into
a range of acrylate and methacrylate systems . This monomer has been used in
antibacterial, liquid crystalline and phosphorous containing resins . The methacrylate
and acrylate functionality provide increased reactivity relative to the
dimethacrylate crosslinker .
Duygu Avci and Lon J. Mathias, Polymer Bulletin, 2005, 54 (1-2), 11-19 Senhaji, O.; Monge, S.; Chougrani, K.; Robin, J. Macromolecular
Chemistry and Physics, 2008, 209(16), 1694–1704. Dizman, B.; Elasri, M.O.; Mathias, L.J. Biomacromolecules, 2005, 6 (1), 514–520.
Allyl glycidyl ether [106-92-3] EHO5g . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
MW 114 .1 bp 154° n 20
D 1 .433 TSCA
Reactive allyl ether . Can be used to introduce epoxide functionality into polymers
made by free-radical polymerization .
Allyl methacrylate [96-05-9] CH5g . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
MW 126 .2 bp 55º/30mm n 20
D 1 .436 Requires Poison Pack 200 ppm MEHQ
TSCA H 2 C=C(CH 3 )CO 2 CH 2 CH=CH 2
Contains polymerizable units of differing reactivity, methacrylate moiety being
more reactive than allyl .
Allyl Phenyl Ether, 98% [1746-13-0] H4d . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
MW 134 bp 185 n 20
D 1 .52 Amber Liquid TSCA Specific gravity (20°C): 0 .97
High purity monomer which has a high refractive index allowing it to be used as
a synthon in modifying polymer refractive index properties .
N-(2-Aminoethyl) methacrylamide hydrochloride U7d . . . . . . . . . . . . . . . . . . . . . . . . . . . .
mp 121-123°C (polymerization is initiated around 122°C) (C 6 H 12 N 2 O)HCL
White to off-white free flowing powder .
Monomer building block for polymerization reactions which may yield
a primary amine functional polymer .
2-Aminoethyl methacrylate hydrochloride, min. 95% [2420-94-2] B6e . . . . . . . . . . . . . .
MW 166 .6 mp 121-124º uninhibited TSCA
O
H C=C(CH )CO CH CH NH 2 3 2 2 2 2
For preparation of polymers containing primary amine groups and preparation
of specialty methacrylate monomers . Technical Data Sheet #522
O
NH • HCI 2
N-(t-BOC-aminopropyl)methacrylamide [2197-397-94] U2bd . . . . . . . . . . . . . . . . . . . . . . .
MW 242 mp 81-83°C uninhibited solid white powder C 12 H 22 O 3 N 2
A solvent soluble, blocked primary amine monomer, it is soluble in a range of
organic solvents and it polymerizes readily with other vinylic monomers . The
t-BOC group is widely known to those in the peptide field and is easily deprot-
ected to the free amine with a variety of reagents including HCl/MeOH, Me 3 Sil, or heat (185° C) .
Copolymers containing N-(N-BOC-aminopropyl)methacrylamide can be readily converted to
primary amino copolymers which can be further modified by coupling to peptides, dyes, etc .
N-(3-Aminopropyl)methacrylamide hydrochloride, >98% [72607-53-5] U2bd . . . . . . . .
MW 178 .7 mp 122-124º uninhibited TSCA (C 7 H 14 N 2 O)HCL
Primary amine monomer . Hydrolytically stable for preparation of polymers
containing primary amine functionality . Technical Data Sheet #522
For use of N-(3-Aminopropyl)methacrylamide hydrochloride to make reductively biodegradable hydrogels
for tissue engineering, see: Vetrik, M. et al, Polymer Degradation and Stability 96 (2011) 892-897
O
O
H
N
O O
OH
N
H
O
H
N O
O O
O
N
H
NH 2 • HCl
NH 2 • HCI
Catalog Size
25351-50 50 ml
25351-100 100 ml
19191-50 50 g
01643-500 500 g
24894-100 100 g
24833-5 5 g
21002-10 10 g
24318-10 10 g
21200-5 5 g
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