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W. Richard Bowen and Nidal Hilal 4

W. Richard Bowen and Nidal Hilal 4

W. Richard Bowen and Nidal Hilal 4

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GREEk SyMBOLS 73<br />

Z cl � Number of bound chloride ions �<br />

Z COO ˆ Charge number due to ionisation of carboxyl<br />

groups<br />

Z T Total charge number of BSA molecule �<br />

GREEk SyMbolS<br />

� Hydrodynamic radius (� a � d) m<br />

� 0i Electronic polarisability of molecule i m 3<br />

� Activity coefficient of chloride ion in NaCl solution �<br />

� i Reduced surface potential i �<br />

� ik Interfacial energy between components i <strong>and</strong> k J m �2<br />

ε 0 Permittivity of vacuum (8.854 � 10) C V �1 m �1<br />

ε ri Dielectric constant of component i �<br />

� Zeta potential V<br />

�i Number of atoms per unit volume of the interacting<br />

material<br />

m�3 � Distance parameter in Lennard-Jones equation m<br />

�d Charge density of diffuse double layer C m�2 �m Molecular diameter m<br />

�o Surface charge density C m�2 � Debye–Hückel parameter m�1 � Characteristic wavelength m<br />

�c Correction applied to Stoke’s law �<br />

� Viscosity of fluid N s m�2 �R Ratio of the elastic deformation to the applied load <strong>and</strong><br />

adhesion to the effective range of the surface forces<br />

� Electrostatic potential V<br />

�� Electrostatic potential at outer cell boundary V<br />

�d Electrostatic potential at OHP (� zeta potential) V<br />

�o Electrostatic potential at particle surface V<br />

wi Characteristic frequency of electromagnetic radiation rad s�1 wUV UV characteristic frequency of electromagnetic<br />

radiation<br />

rad s�1 ε Depth of the potential energy well J<br />

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