Dissertation Martin Krause.pdf - KLUEDO - Universität Kaiserslautern

41
40
39
38
42 43
33
32
34
44
O
O
O
8
20 19
3
4
2
15
16
1
10
18
17
11
5 6 7 12
O
37
36
35
30
29
31
9
1 H NMR (600 MHz, [D6]Aceton, 25°C)
δ = 1.06 – 1.41 + 1.52 – 1.68 + 1.82 – 1.88 (m, 10H, H-(32) + H-(33) + H-(34)), 2.31 – 2.40 (m, 1H,
H-(31)), 3.63 – 3.65 (m, 16H, H-(23) + H-(24) + H-(27) + H-(28)), 3.73 – 3.76 + 3.79 – 3.82 (m, 8H,
H-(22) + H-(26)), 3.93 – 3.97 + 4.03 – 4.05 + 4.07 – 4.08 (m, 8H, H-(21) + H-(25)), 6.80 – 6.87 (m,
2H, H-(7) + H-(8)), 6.90 – 6.92 (m, 3H, H-(10) + H-(13) + H-(14)), 7.07 – 7.12 (m, 2H, H-(17) + H-
(20)), 7.17 (d, 2H, 3 J(H,H) = 3.78 Hz, H-(16)), 7.33 (t, 1H, 3 J(H,H) = 7.6 Hz, H-(37)), 7.37 (t, 1H,
3 J(H,H) = 7.7 Hz, H-(41)), 7.45 (t, 1H, 3 J(H,H) = 7.14 Hz, H-(42)) 7.56 – 7.65 (m, 4H, H-(1) + H-(3)
+ H-(4) + H-(5)), 8.00 (d, 1H, 3 J(H,H) = 7.7 Hz, H-(40)), 8.18 (t, 1H, 3 J(H,H) = 8.1 Hz, H-(38), 8.34
(t, 1H, 3 J(H,H) = 5.6 Hz, H-(36)), 8.88 (d, 1H, 3 J(H,H) = 8.5 Hz, H-(43)).
13C NMR (151 MHz, [D6]Aceton, 25°C)
δ = 25.0 + 25.1 (C-33), 25.5 + 25.6 (C-34), 28.8 + 29.7 (C-32), 42.8 (C-31), 69.1 + 69.3 + 69.4 (C-21
+ C-25), 70.4 + 70.5 (C-22 + C-26), 71.1 (C-23 + C-24 + C-27 + C-28), 75.9 (C-8), 77.3 + 77.4 (C-7),
112.9 + 113.0 (C-20), 113.5 + 113.6 (C-14), 113.7 (C-18), 119.8 (C-11), 119.9 (C-16), 120.1 + 120.2
(C-10), 124.4 + 124.6 (C-3), 124.9 (C-5), 125.5 (C-37), 127.8 (C-43), 128.6 (C-35), 128.7 (C-1), 129.8
(C-41), 129.9 (C-42), 131.3 (C-4), 133.2 (C-9), 133.3 (C-15), 133.3 (C-40), 133.5 (C-36), 133.6 (C-
38), 134.0 (C-39), 141.3 + 141.4 (C-12 + C-18), 141.7 + 141.8 (C-13 + C-19), 149.0 (C-44), 149.2 +,
149.3 (C-2 + C-6), 165.8 + 165.9 (C-30), 173.8 (C-29).
MS (ESITOF, positive mode): m/z (%): 957.3 (100 %) [M+Na + ], 973.2 (81%) [M+K + ].
IR (KBr, cm -1 ): 2927, 2855, 1733, 1718, 1508, 1264, 1237, 1129, 782.
Elementaranalyse: berechnet (%) für C54H62O14·2H2O: C 66.79, H 6.85;
gefunden: C 66.77, H 6.95.
14
79
21
O
13
O
22
O
O
O
25
O
23
O
O
26
O
O
24
28
27