Integrierte Vermeidung und Verminderung der Umweltverschmutzung

Integrierte Vermeidung und Verminderung der Umweltverschmutzung Integrierte Vermeidung und Verminderung der Umweltverschmutzung

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Chapter 2 Before bottling, the beer is filtered through a filter cake. Proven materials for this purpose are mud-free kieselguhr; calcined and screened diatomaceous earth of various particle size distribution; and perlite from ground and calcined glassy rock of volcanic origin. Activated carbon may be used to correct a mild off-taste. For example, it is usually used in the treatment of rest beers. Shortly before filtration, hydro- and xero-silica gels may be added to contribute to the build-up of the filter cake. Fining, by the addition of, e.g cross-linked polyvinylpyrrolidone (PVP) and polyvinylpolypyrrolidine (PVPP) is carried out to clarify the beer and, e.g. reduce the polyphenol concentration. Cleaning agents and disinfectants are also used. 2.2.17 Distilling The use of distillation in the FDM sector can be illustrated by the following two examples; the distillations of Scotch whisky and cognac. 2.2.17.1 Scotch whisky Distillation units in the production of scotch whisky range from simple pot stills to continuous multicolumn stills. Energy is introduced in the form of steam to the bottom of the still and selectively volatilises the alcohol and other components from the fermented liquids and predistilled alcohol/water mixtures. The volatile components are recirculated within the still to achieve the correct separation, selection and concentration of alcoholic/aqueous compounds for the many varied and desirable congener profiles required by the various types and brands of products. Stills can be operated singly or in series. The volatile components are condensed by heat-exchange with water in condensers and removed as a liquid spirit. The residual material known as pot ale, spent lees, stillage or spent wash, is discharged from the bottom of the still. In column stills other fractions are also removed such as fusel oils and high feints. The high feints are fed back into the stills and the fusel oils, which are mainly amyl alcohol, are sold as a coproduct. 2.2.17.2 Cognac Cognac is obtained by the distillation of white wines harvested in the controlled appellation area. The distillation of Cognac is a two-stage process. In the first stage, a first distillate, known as “brouillis” is obtained. This has an alcoholic strength of between 28 to 32 % volume. In the second stage, the brouillis is returned to the boiler for a second heating, known as “la bonne chauffe”. The distillation heads, secondes and tails are separated, leaving only the heart of the spirit. There is a restriction on the maximum strength of distillation, which must not exceed 72 vol-% alcohol. The time of each stage is about 12 hours. Distillation is carried out in two separate heatings or chauffes in a special Charentais copper pot still comprising a characteristically shaped boiler, heated with a naked flame and topped with a cowl shaped like a turban, an olive or an onion. A Charentais still often has an energy saving wine reheater. This device, in which the heat is provided by the alcohol vapours passing through it, preheats the wine, which is to be distilled in the next cycle. The final day for distillation is 31 March of the year following harvesting. Maturation must be carried out in Limousin or Tronçais oak casks. As with other brandies and matured wine spirits, maturation was aided by the use of oak extracts, but this practice is becoming less common in Cognac. French regulations prohibit the use of additives in the final product, other than water and sugar or caramel, and restrict the minimum strength to 40 vol-% alcohol. 108 January 2006 RHC/EIPPCB/FDM_BREF_FINAL

2.2.18 Wine This section includes red and white wine manufacturing [134, AWARENET, 2002]. 2.2.18.1 Reception Chapter 2 When grapes are received at the winery, they are sorted by variety, quality and quantity. Containers are emptied directly into either crushing or transport equipment. Emptied containers are cleaned. The cleaning water is drained. 2.2.18.2 Grape crushing and destemming Grape crushing or mashing takes place in grape mills. If maceration is intended, the mash can be stored in mash containers. To prevent the mash from oxidation H2SO3 is added. The decision as to whether destemming of the white grapes is necessary before the grape mash is made depends on the variety and ripeness of the grapes as well as on the further processing of the mash. 2.2.18.3 Pressing For white wine, the mash is transported to the wine press. The resulting unfermented grape juice is referred to as must. Sulphur dioxide is often added at this stage at the rate of 100 – 150 mg/l to suppress undesirable micro-organisms, e.g. grape skins are often covered with bacteria and moulds, as well as the yeasts used in the process. The solid residues, e.g. pomace and marc, are then separated. For red wine, when the fermentation process is finished, i.e. when the sugar levels are under 0.1 %, the wine is taken from the bottom of the tank and the marcs are transferred to the wine press to extract the remaining wine. 2.2.18.4 Fining The fining agents used in winemaking are gelatine, casein, isinglass, chitin, albumin or egg white; natural mineral adsorbents, e.g. bentonite, diatomaceous earth or silica; and synthetic polymers, e.g. PVPP. It is reported that sediments from clarification are separated by centrifugation or filtration. This removes unwanted particles left in suspension. 2.2.18.5 Fermentation Alcoholic fermentation takes place in large stainless steel fermentation reactors or vats with or without the addition of pre-cultivated yeast, e.g. usually Saccharomyces cerevisiae, and under rigorous temperature control. White wine is fermented after marc separation, while red wine is fermented together with grape marcs. Red wine, and sometimes white wine as well, goes through a second malolactic fermentation. This is a bacterial fermentation that converts the malic acid into lactic acid. 2.2.18.6 Ageing After fermentation, wine is cooled to 4 – 5 ºC and transferred to barrels or wooden vats made of oak for ageing. This allows the wine to stabilise and to develop softer tannins and complex flavours. Lees are separated from the wine every 3 to 4 months. The barrels are then washed and refilled. RHC/EIPPCB/FDM_BREF_FINAL January 2006 109

2.2.18 Wine<br />

This section includes red and white wine manufacturing [134, AWARENET, 2002].<br />

2.2.18.1 Reception<br />

Chapter 2<br />

When grapes are received at the winery, they are sorted by variety, quality and quantity.<br />

Containers are emptied directly into either crushing or transport equipment. Emptied containers<br />

are cleaned. The cleaning water is drained.<br />

2.2.18.2 Grape crushing and destemming<br />

Grape crushing or mashing takes place in grape mills. If maceration is intended, the mash can be<br />

stored in mash containers. To prevent the mash from oxidation H2SO3 is added. The decision as<br />

to whether destemming of the white grapes is necessary before the grape mash is made depends<br />

on the variety and ripeness of the grapes as well as on the further processing of the mash.<br />

2.2.18.3 Pressing<br />

For white wine, the mash is transported to the wine press. The resulting unfermented grape juice<br />

is referred to as must. Sulphur dioxide is often added at this stage at the rate of 100 – 150 mg/l<br />

to suppress <strong>und</strong>esirable micro-organisms, e.g. grape skins are often covered with bacteria and<br />

moulds, as well as the yeasts used in the process. The solid residues, e.g. pomace and marc, are<br />

then separated.<br />

For red wine, when the fermentation process is finished, i.e. when the sugar levels are <strong>und</strong>er<br />

0.1 %, the wine is taken from the bottom of the tank and the marcs are transferred to the wine<br />

press to extract the remaining wine.<br />

2.2.18.4 Fining<br />

The fining agents used in winemaking are gelatine, casein, isinglass, chitin, albumin or egg<br />

white; natural mineral adsorbents, e.g. bentonite, diatomaceous earth or silica; and synthetic<br />

polymers, e.g. PVPP. It is reported that sediments from clarification are separated by<br />

centrifugation or filtration. This removes unwanted particles left in suspension.<br />

2.2.18.5 Fermentation<br />

Alcoholic fermentation takes place in large stainless steel fermentation reactors or vats with or<br />

without the addition of pre-cultivated yeast, e.g. usually Saccharomyces cerevisiae, and <strong>und</strong>er<br />

rigorous temperature control. White wine is fermented after marc separation, while red wine is<br />

fermented together with grape marcs. Red wine, and sometimes white wine as well, goes<br />

through a second malolactic fermentation. This is a bacterial fermentation that converts the<br />

malic acid into lactic acid.<br />

2.2.18.6 Ageing<br />

After fermentation, wine is cooled to 4 – 5 ºC and transferred to barrels or wooden vats made of<br />

oak for ageing. This allows the wine to stabilise and to develop softer tannins and complex<br />

flavours. Lees are separated from the wine every 3 to 4 months. The barrels are then washed and<br />

refilled.<br />

RHC/EIPPCB/FDM_BREF_FINAL January 2006 109

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