Integrierte Vermeidung und Verminderung der Umweltverschmutzung
Integrierte Vermeidung und Verminderung der Umweltverschmutzung Integrierte Vermeidung und Verminderung der Umweltverschmutzung
Chapter 2 Batters are typically deposited into oil sprayed trays or continuous sheets for products such as Swiss rolls. After baking, the cakes are removed from the tins and cooled. The empty tins are cleaned, rinsed, dried and cooled. 2.2.11.3 Cocoa Drinking cocoa typically consists of cocoa powder, vanillin, cinnamon, salt, cassia and other powdered spices. Raw beans are received and subjected to a series of washing operations to remove extraneous matter such as fibre, stones, grit, metal, bean clusters and immature beans. The latter two materials may be used for the manufacture of cocoa butter. The beans are roasted. Roasting conditions vary depending on the equipment and the desired product, but are typically in the range of 100 to 140 °C for 4 to 6 minutes. Whole beans or the separated nibs may be roasted. Winnowing is the separation of the outer shell of the bean from the edible nibs and typically consists of cracking the roasted bean between rollers, followed by air classification to remove the shell fragments. The nibs are ground to produce a cocoa liquor whose particle size is further reduced by grinding mills, which are water-cooled. The particle size is important for the manufacture of chocolate drink but less important for chocolate since this requires some further refining. The liquor or nibs from roasted or unroasted beans are likely to be subjected to a process known as alkalisation which increases the dispensability of cocoa powder in milk or water when used in drinks. It is also used to modify the colour of the cocoa. Only permitted acids, alkalis and emulsifiers may be used for this process. Cocoa powder is produced by the hydraulic pressing of cocoa liquor to express cocoa butter and to reduce the fat content of the press cake to the desired level. The expressed cocoa butter is used in the manufacture of chocolate. The press cake is pulverised to produce a cocoa powder. The final product is then packaged. 2.2.11.4 Chocolate The basic ingredients for the manufacture of chocolate include cocoa liquor, sugar, other sweeteners, cocoa butter, butter fat, milk powder, milk crumb and emulsifiers. The basic operations involved in chocolate production are the preparation and mixing of ingredients, refining and conching. Conching involves agitating the refined material to induce desirable physical changes in the final product and to improve the flavour. Chocolate production has traditionally been undertaken in a device called a melangeur, which accommodates all of the steps involved. Melangeurs are, however, being increasingly replaced by large specialist machines. The refining stage in the manufacture of chocolate is intended to reduce the size of the particles of cocoa solids in the mix, thus ensuring that the mixture has a smooth consistency. This is achieved by passing the mixture through vertically mounted rollers which need to be water cooled to prevent distortions arising from frictional heating. A number of systems are available for conching, which is a specialised activity inducing complex changes in the chocolate. Processing milk chocolate in a traditional batch conch takes in excess of a day, whilst modern, continuous systems achieve the same result in around 4 hours. Finished chocolate is typically stored in bulk and must be tempered through a cooling and warming cycle before final use. Chocolate products may be produced by casting the chocolate into moulds, followed by cooling and demoulding. Such methods may be used to produce solid chocolate blocks or shells, which may be hollow or filled with a confectionery such as fondant. Alternatively, liquid chocolate may be used to coat confectionery using units known as enrobers. 100 January 2006 RHC/EIPPCB/FDM_BREF_FINAL
2.2.11.5 Boiled sweets Chapter 2 Boiled sweets are highly concentrated solutions of sugar, glucose syrup and sometimes invert sugar, with added flavourings. These are metered into continuous dissolvers. This mixture feeds cookers, of which there are a number of designs such as thin film, coil cookers or batch vacuum cookers. Water is rapidly evaporated from the syrup, which is then discharged and partially cooled due to evaporative cooling. The boiled sweet mass is transferred to water-cooled tables and acid, flavour and colours, are added to the partially cooled mass in a batch or continuous process. The mix is then transferred to forming machinery. The formed sweets are cooled and wrapped in moisture proof packs as rapidly as possible. 2.2.12 Sugar Sugar (sucrose) is produced from two principal sources, sugar beet and sugar cane. Sugar beet tends to be grown in Europe and sugar cane in hotter climates [134, AWARENET, 2002] such as the West Indies, so it is not extracted in Europe. Sucrose is also available in a liquid form as an aqueous solution, in some cases all or partially inverted. Sugar crystals may be ground to make powdered or confectioner’s sugars. Anti-caking agents such as maize starch are added to keep these sugars free flowing. 2.2.12.1 Sugar beet extraction In general, the extraction of sugar from sugar beet and sugar cane is similar. The beets are cut into thin slices called cossettes. They are passed into a water-based countercurrent extraction apparatus called a diffuser and emerge as impure sugar juice and beet pulp. The fresh water used in the extraction process is actually condensed water from the subsequent evaporation steps together with recirculated water from the pulp pressing. The temperature inside the diffuser is 68 to 72 ºC. Three types of diffusers are used. Horizontal diffusers are large revolving drums, separated into cells by a helix attached to the interior surface. As the drum and helix revolve, the juice, which stays at the bottom of the vessel, is transported countercurrently to the cossettes, i.e. the exhausted beet pulp leaves the diffuser at the same end where the fresh water enters. Vertical diffusers are composed of an extractor with two main and distinct parts, i.e. the countercurrent mixer and the extraction tower. The tower is a 14 to 20 metres high cylinder. Inside the tower, a tubular shaft rotates slowly. Special helicoidal steel pieces, or flights, are fitted on the shaft and move the cossettes upwards. The juice and the cossettes move countercurrently. Slope diffusers consist essentially of a U-shaped sloping vessel in which two overlapping screws with opposite pitches rotate. Fresh cossettes fall from a conveyor belt into the lower end. The cossettes are transported upwards by the two screws to a paddle wheel, which lifts the exhausted cossettes out of the extractor. Fresh water is introduced at the upper end and the sugar juice leaves the extractor through a screen at the lower end. The crystallisation process takes place in vacuum pans in which the juice is boiled under vacuum to minimise the temperatures involved. The growth of the sucrose crystal only involves sucrose and water. The non-sugars contained in the sugar juice are not incorporated into the crystal structure, instead most of them remain in the liquid phase while some are released to the vapour phase. The sugar crystals are removed from the liquid phase by centrifugation. Sugar to be stored in silos must be dedusted and cooled to the storage temperature. This is carried out in a sugar cooler, which is a device in which warm and dried sugar is intensively aerated by cold filtered external air to cool the sugar to the storage temperature, approximately 20 to 30 ºC. The most common systems in use are typically drum or fluidised bed coolers with chilling systems that have a countercurrent or cross-current phase flow. RHC/EIPPCB/FDM_BREF_FINAL January 2006 101
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Chapter 2<br />
Batters are typically deposited into oil sprayed trays or continuous sheets for products such as<br />
Swiss rolls. After baking, the cakes are removed from the tins and cooled. The empty tins are<br />
cleaned, rinsed, dried and cooled.<br />
2.2.11.3 Cocoa<br />
Drinking cocoa typically consists of cocoa pow<strong>der</strong>, vanillin, cinnamon, salt, cassia and other<br />
pow<strong>der</strong>ed spices. Raw beans are received and subjected to a series of washing operations to<br />
remove extraneous matter such as fibre, stones, grit, metal, bean clusters and immature beans.<br />
The latter two materials may be used for the manufacture of cocoa butter. The beans are roasted.<br />
Roasting conditions vary depending on the equipment and the desired product, but are typically<br />
in the range of 100 to 140 °C for 4 to 6 minutes. Whole beans or the separated nibs may be<br />
roasted.<br />
Winnowing is the separation of the outer shell of the bean from the edible nibs and typically<br />
consists of cracking the roasted bean between rollers, followed by air classification to remove<br />
the shell fragments. The nibs are gro<strong>und</strong> to produce a cocoa liquor whose particle size is further<br />
reduced by grinding mills, which are water-cooled. The particle size is important for the<br />
manufacture of chocolate drink but less important for chocolate since this requires some further<br />
refining. The liquor or nibs from roasted or unroasted beans are likely to be subjected to a<br />
process known as alkalisation which increases the dispensability of cocoa pow<strong>der</strong> in milk or<br />
water when used in drinks. It is also used to modify the colour of the cocoa. Only permitted<br />
acids, alkalis and emulsifiers may be used for this process.<br />
Cocoa pow<strong>der</strong> is produced by the hydraulic pressing of cocoa liquor to express cocoa butter and<br />
to reduce the fat content of the press cake to the desired level. The expressed cocoa butter is<br />
used in the manufacture of chocolate. The press cake is pulverised to produce a cocoa pow<strong>der</strong>.<br />
The final product is then packaged.<br />
2.2.11.4 Chocolate<br />
The basic ingredients for the manufacture of chocolate include cocoa liquor, sugar, other<br />
sweeteners, cocoa butter, butter fat, milk pow<strong>der</strong>, milk crumb and emulsifiers. The basic<br />
operations involved in chocolate production are the preparation and mixing of ingredients,<br />
refining and conching. Conching involves agitating the refined material to induce desirable<br />
physical changes in the final product and to improve the flavour. Chocolate production has<br />
traditionally been <strong>und</strong>ertaken in a device called a melangeur, which accommodates all of the<br />
steps involved. Melangeurs are, however, being increasingly replaced by large specialist<br />
machines.<br />
The refining stage in the manufacture of chocolate is intended to reduce the size of the particles<br />
of cocoa solids in the mix, thus ensuring that the mixture has a smooth consistency. This is<br />
achieved by passing the mixture through vertically mounted rollers which need to be water<br />
cooled to prevent distortions arising from frictional heating. A number of systems are available<br />
for conching, which is a specialised activity inducing complex changes in the chocolate.<br />
Processing milk chocolate in a traditional batch conch takes in excess of a day, whilst mo<strong>der</strong>n,<br />
continuous systems achieve the same result in aro<strong>und</strong> 4 hours. Finished chocolate is typically<br />
stored in bulk and must be tempered through a cooling and warming cycle before final use.<br />
Chocolate products may be produced by casting the chocolate into moulds, followed by cooling<br />
and demoulding. Such methods may be used to produce solid chocolate blocks or shells, which<br />
may be hollow or filled with a confectionery such as fondant. Alternatively, liquid chocolate<br />
may be used to coat confectionery using units known as enrobers.<br />
100 January 2006 RHC/EIPPCB/FDM_BREF_FINAL