Substitution von molekularen Klammern an den Naphthalin ...
Substitution von molekularen Klammern an den Naphthalin ... Substitution von molekularen Klammern an den Naphthalin ...
Experimenteller Teil Tabelle 4.4.1.2-3 : Bindungslängen [Å] von 31c. O(1)-C(1) 1.389(4) O(1)-C(31) 1.434(4) O(2)-C(32) 1.350(5) O(2)-C(16) 1.377(4) O(3)-C(35) 1.241(4) O(4)-C(37) 1.194(4) O(4)-H(40A) 2.46(4) O(5)-C(37) 1.339(4) O(5)-C(38) 1.453(4) O(6)-C(39) 1.244(4) O(7)-C(41) 1.202(4) O(8)-C(41) 1.332(4) O(8)-C(42) 1.490(4) O(8)-H(39C) 3.24(4) N(1)-C(35) 1.340(4) N(1)-C(36) 1.450(4) C(1)-C(2) 1.384(4) C(1)-C(30) 1.387(5) N(2)-C(39) 1.345(4) N(2)-C(40) 1.441(4) C(2)-C(15) 1.402(5) C(2)-C(3) 1.521(5) C(3)-C(4) 1.516(5) C(3)-C(33) 1.548(5) C(4)-C(5) 1.355(5) C(4)-C(13) 1.431(5) C(5)-C(6) 1.421(4) C(6)-C(7) 1.397(5) C(6)-C(11) 1.427(5) C(7)-C(8) 1.375(4) C(8)-C(9) 1.403(5) C(8)-C(39) 1.486(5) C(9)-C(10) 1.362(5) C(10)-C(11) 1.410(4) C(11)-C(12) 1.433(5) C(12)-C(13) 1.364(5) C(13)-C(14) 1.527(5) C(14)-C(15) 1.528(5) C(14)-C(33) 1.548(5) C(15)-C(16) 1.392(5) C(16)-C(17) 1.393(5) C(17)-C(30) 1.401(4) C(17)-C(18) 1.518(5) C(18)-C(19) 1.519(4) C(18)-C(34) 1.545(5) C(19)-C(20) 1.354(4) C(19)-C(28) 1.430(5) C(20)-C(21) 1.419(4) C(21)-C(22) 1.415(4) C(21)-C(26) 1.430(4) C(22)-C(23) 1.369(4) C(23)-C(24) 1.410(5) C(24)-C(25) 1.366(4) C(24)-C(35) 1.495(5) C(25)-C(26) 1.416(4) C(26)-C(27) 1.439(4) C(27)-C(28) 1.355(4) C(28)-C(29) 1.536(5) C(29)-C(30) 1.524(5) C(29)-C(34) 1.543(5) C(36)-C(37) 1.503(5) C(40)-C(41) 1.495(5) 350
Experimenteller Teil Tabelle 4.4.1.2-4: Bildungswinkel [°] von 31c. C(1)-O(1)-C(31) 112.1(2) C(32)-O(2)-C(16) 118.3(3) C(37)-O(5)-C(38) 115.7(3) C(41)-O(8)-C(42) 116.3(3) C(35)-N(1)-C(36) 122.0(3) C(2)-C(1)-C(30) 117.9(3) C(2)-C(1)-O(1) 120.6(3) C(30)-C(1)-O(1) 121.5(3) C(39)-N(2)-C(40) 123.6(3) C(1)-C(2)-C(15) 121.6(3) C(1)-C(2)-C(3) 130.6(3) C(15)-C(2)-C(3) 107.1(3) C(4)-C(3)-C(2) 102.9(3) C(4)-C(3)-C(33) 99.9(3) C(2)-C(3)-C(33) 100.2(3) C(5)-C(4)-C(13) 121.2(3) C(5)-C(4)-C(3) 132.1(3) C(13)-C(4)-C(3) 105.9(3) C(4)-C(5)-C(6) 119.8(3) C(7)-C(6)-C(5) 121.6(3) C(7)-C(6)-C(11) 118.8(3) C(5)-C(6)-C(11) 119.1(3) C(8)-C(7)-C(6) 122.5(3) C(7)-C(8)-C(9) 118.0(3) C(7)-C(8)-C(39) 118.2(3) C(9)-C(8)-C(39) 123.6(3) C(10)-C(9)-C(8) 121.1(3) C(9)-C(10)-C(11) 121.6(3) C(10)-C(11)-C(6) 117.6(3) C(10)-C(11)-C(12) 122.0(3) C(6)-C(11)-C(12) 120.0(3) C(13)-C(12)-C(11) 118.8(3) C(12)-C(13)-C(4) 121.0(3) C(12)-C(13)-C(14) 132.5(3) C(4)-C(13)-C(14) 106.1(3) C(13)-C(14)-C(15) 103.1(3) C(13)-C(14)-C(33) 99.3(3) C(15)-C(14)-C(33) 100.4(3) C(16)-C(15)-C(2) 120.7(3) C(16)-C(15)-C(14) 133.0(3) C(2)-C(15)-C(14) 106.0(3) O(2)-C(16)-C(15) 123.6(3) O(2)-C(16)-C(17) 118.9(3) C(15)-C(16)-C(17) 117.4(3) C(16)-C(17)-C(30) 121.6(3) C(16)-C(17)-C(18) 130.9(3) C(30)-C(17)-C(18) 107.2(3) C(17)-C(18)-C(19) 104.3(3) C(17)-C(18)-C(34) 99.3(3) C(19)-C(18)-C(34) 98.9(3) C(20)-C(19)-C(28) 121.4(3) C(20)-C(19)-C(18) 132.0(3) C(28)-C(19)-C(18) 106.4(3) C(19)-C(20)-C(21) 119.8(3) C(22)-C(21)-C(20) 122.3(3) C(22)-C(21)-C(26) 118.3(3) C(20)-C(21)-C(26) 119.3(3) C(23)-C(22)-C(21) 121.5(3) C(22)-C(23)-C(24) 120.6(3) C(25)-C(24)-C(23) 119.0(3) C(25)-C(24)-C(35) 117.8(3) C(23)-C(24)-C(35) 123.2(3) C(24)-C(25)-C(26) 122.4(3) C(25)-C(26)-C(21) 118.2(3) C(25)-C(26)-C(27) 122.5(3) C(21)-C(26)-C(27) 119.3(3) C(28)-C(27)-C(26) 119.3(3) C(27)-C(28)-C(19) 120.7(3) C(27)-C(28)-C(29) 133.4(3) C(19)-C(28)-C(29) 105.8(3) C(30)-C(29)-C(28) 105.6(3) C(30)-C(29)-C(34) 98.8(3) C(28)-C(29)-C(34) 98.5(3) C(1)-C(30)-C(17) 120.6(3) C(1)-C(30)-C(29) 133.1(3) C(17)-C(30)-C(29) 106.3(3) C(3)-C(33)-C(14) 94.3(3) C(29)-C(34)-C(18) 95.1(2) O(3)-C(35)-N(1) 121.2(3) O(3)-C(35)-C(24) 121.2(3) N(1)-C(35)-C(24) 117.6(3) N(1)-C(36)-C(37) 113.5(3) O(4)-C(37)-O(5) 125.0(3) O(4)-C(37)-C(36) 125.7(3) O(5)-C(37)-C(36) 109.3(3) O(6)-C(39)-N(2) 121.6(3) O(6)-C(39)-C(8) 121.5(3) N(2)-C(39)-C(8) 116.8(3) N(2)-C(40)-C(41) 113.0(3) O(7)-C(41)-O(8) 123.9(3) O(7)-C(41)-C(40) 125.7(3) O(8)-C(41)-C(40) 110.4(3) 351
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- Seite 315 und 316: Experimenteller Teil 305 Probe δob
- Seite 317 und 318: Experimenteller Teil 4.3.2 1 H-NMR-
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- Seite 327 und 328: Experimenteller Teil Rezeptor: OH O
- Seite 329 und 330: Experimenteller Teil Δδ obs [ppm]
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- Seite 343 und 344: Experimenteller Teil 4.3.2.2 Rezept
- Seite 345 und 346: Experimenteller Teil 4.3.2.3 Rezept
- Seite 347 und 348: Experimenteller Teil 4.3.2.4 Titrat
- Seite 349 und 350: Experimenteller Teil Rezeptor: - O2
- Seite 351 und 352: Experimenteller Teil Rezeptor: + Li
- Seite 353 und 354: Experimenteller Teil 4.3.2.5 Titrat
- Seite 355 und 356: Experimenteller Teil Rezeptor: + Li
- Seite 357 und 358: Experimenteller Teil 4.4. Kristalls
- Seite 359: Experimenteller Teil Tabelle 4.4.1.
- Seite 363 und 364: Experimenteller Teil Tabelle 4.4.1.
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- Seite 369 und 370: Experimenteller Teil Tabelle 4.4.1.
- Seite 371 und 372: Literaturverzeichnis [20] P. J. Smi
- Seite 373 und 374: Literaturverzeichnis [63] F.-G. Kl
- Seite 375 und 376: Herrn Prof. Dr. F.-G. Klärner dank
Experimenteller Teil<br />
Tabelle 4.4.1.2-4: Bildungswinkel [°] <strong>von</strong> 31c.<br />
C(1)-O(1)-C(31) 112.1(2)<br />
C(32)-O(2)-C(16) 118.3(3)<br />
C(37)-O(5)-C(38) 115.7(3)<br />
C(41)-O(8)-C(42) 116.3(3)<br />
C(35)-N(1)-C(36) 122.0(3)<br />
C(2)-C(1)-C(30) 117.9(3)<br />
C(2)-C(1)-O(1) 120.6(3)<br />
C(30)-C(1)-O(1) 121.5(3)<br />
C(39)-N(2)-C(40) 123.6(3)<br />
C(1)-C(2)-C(15) 121.6(3)<br />
C(1)-C(2)-C(3) 130.6(3)<br />
C(15)-C(2)-C(3) 107.1(3)<br />
C(4)-C(3)-C(2) 102.9(3)<br />
C(4)-C(3)-C(33) 99.9(3)<br />
C(2)-C(3)-C(33) 100.2(3)<br />
C(5)-C(4)-C(13) 121.2(3)<br />
C(5)-C(4)-C(3) 132.1(3)<br />
C(13)-C(4)-C(3) 105.9(3)<br />
C(4)-C(5)-C(6) 119.8(3)<br />
C(7)-C(6)-C(5) 121.6(3)<br />
C(7)-C(6)-C(11) 118.8(3)<br />
C(5)-C(6)-C(11) 119.1(3)<br />
C(8)-C(7)-C(6) 122.5(3)<br />
C(7)-C(8)-C(9) 118.0(3)<br />
C(7)-C(8)-C(39) 118.2(3)<br />
C(9)-C(8)-C(39) 123.6(3)<br />
C(10)-C(9)-C(8) 121.1(3)<br />
C(9)-C(10)-C(11) 121.6(3)<br />
C(10)-C(11)-C(6) 117.6(3)<br />
C(10)-C(11)-C(12) 122.0(3)<br />
C(6)-C(11)-C(12) 120.0(3)<br />
C(13)-C(12)-C(11) 118.8(3)<br />
C(12)-C(13)-C(4) 121.0(3)<br />
C(12)-C(13)-C(14) 132.5(3)<br />
C(4)-C(13)-C(14) 106.1(3)<br />
C(13)-C(14)-C(15) 103.1(3)<br />
C(13)-C(14)-C(33) 99.3(3)<br />
C(15)-C(14)-C(33) 100.4(3)<br />
C(16)-C(15)-C(2) 120.7(3)<br />
C(16)-C(15)-C(14) 133.0(3)<br />
C(2)-C(15)-C(14) 106.0(3)<br />
O(2)-C(16)-C(15) 123.6(3)<br />
O(2)-C(16)-C(17) 118.9(3)<br />
C(15)-C(16)-C(17) 117.4(3)<br />
C(16)-C(17)-C(30) 121.6(3)<br />
C(16)-C(17)-C(18) 130.9(3)<br />
C(30)-C(17)-C(18) 107.2(3)<br />
C(17)-C(18)-C(19) 104.3(3)<br />
C(17)-C(18)-C(34) 99.3(3)<br />
C(19)-C(18)-C(34) 98.9(3)<br />
C(20)-C(19)-C(28) 121.4(3)<br />
C(20)-C(19)-C(18) 132.0(3)<br />
C(28)-C(19)-C(18) 106.4(3)<br />
C(19)-C(20)-C(21) 119.8(3)<br />
C(22)-C(21)-C(20) 122.3(3)<br />
C(22)-C(21)-C(26) 118.3(3)<br />
C(20)-C(21)-C(26) 119.3(3)<br />
C(23)-C(22)-C(21) 121.5(3)<br />
C(22)-C(23)-C(24) 120.6(3)<br />
C(25)-C(24)-C(23) 119.0(3)<br />
C(25)-C(24)-C(35) 117.8(3)<br />
C(23)-C(24)-C(35) 123.2(3)<br />
C(24)-C(25)-C(26) 122.4(3)<br />
C(25)-C(26)-C(21) 118.2(3)<br />
C(25)-C(26)-C(27) 122.5(3)<br />
C(21)-C(26)-C(27) 119.3(3)<br />
C(28)-C(27)-C(26) 119.3(3)<br />
C(27)-C(28)-C(19) 120.7(3)<br />
C(27)-C(28)-C(29) 133.4(3)<br />
C(19)-C(28)-C(29) 105.8(3)<br />
C(30)-C(29)-C(28) 105.6(3)<br />
C(30)-C(29)-C(34) 98.8(3)<br />
C(28)-C(29)-C(34) 98.5(3)<br />
C(1)-C(30)-C(17) 120.6(3)<br />
C(1)-C(30)-C(29) 133.1(3)<br />
C(17)-C(30)-C(29) 106.3(3)<br />
C(3)-C(33)-C(14) 94.3(3)<br />
C(29)-C(34)-C(18) 95.1(2)<br />
O(3)-C(35)-N(1) 121.2(3)<br />
O(3)-C(35)-C(24) 121.2(3)<br />
N(1)-C(35)-C(24) 117.6(3)<br />
N(1)-C(36)-C(37) 113.5(3)<br />
O(4)-C(37)-O(5) 125.0(3)<br />
O(4)-C(37)-C(36) 125.7(3)<br />
O(5)-C(37)-C(36) 109.3(3)<br />
O(6)-C(39)-N(2) 121.6(3)<br />
O(6)-C(39)-C(8) 121.5(3)<br />
N(2)-C(39)-C(8) 116.8(3)<br />
N(2)-C(40)-C(41) 113.0(3)<br />
O(7)-C(41)-O(8) 123.9(3)<br />
O(7)-C(41)-C(40) 125.7(3)<br />
O(8)-C(41)-C(40) 110.4(3)<br />
351