Substitution von molekularen Klammern an den Naphthalin ...

Experimenteller Teil
13 C-NMR (126 MHz, CDCl3): δ [ppm] = 20.85 (q, C-22, C-24), 47.99 (d, C-8, C-15),
48.05 (d, C-6), 48.20 (d, C-17), 52.00 (q, C-26), 64.86, 64.94 (t, C-19, C-20),
120.02, 120.06, 120.10 (d, C-5, C-9, C-14), 121.26 (d, C-18), 124.88 (d, C-3),
125.29 (d, C-11, C-12), 126.66 (s, C-2), 127.62, 127.65, 127.78 (d, C-4, C-10, C-
13), 130.64 (d, C-1), 131.33 (s, C-4a), 132.09/ 132.10 (s, C-9a, C-13a), 134.74 (s,
C-18a), 137.26 (s, C-7, C-16), 140.21, 140.43, 140.89, 140.95 (s, C-6a, C-7a, C-
15a, C-16a), 145.69 (s, C-9a, C-13a), 146.73 (s, C-5a), 148.71 (C-17a), 167.39 (s,
C-25), 168.59, 168.61 (s, C-21, C-23).
8.0
Enantiomer 2:
7.0
6.0
5.0
1 H-NMR (500 MHz, CDCl3): δ [ppm] = 2.41, 2.43 (dt, 2H, 2 J(19i-H, 19a-H)= 8 Hz,
3
J (19i-H, 6-H)= 1.5 Hz, 19i-H, 20i-H), 2.46, 2.47 (s, 6H, H-22, H-24), 2.64, 2.66 (dt,
2H, 19a-H, 20a-H), 3.87 (s, 3H, 26-H), 4.29 (s, 4H, 6-H, 8-H, 15-H, 17-H ), 7.24 (m,
11-H, 12-H), 7.50 (s, 2H, 9-H, 14-H), 7.54 (s, 2H, 5-H, 18-H), 7.56 (m, 2H, 10-H,
13-H), 7.58 (d, 2H, 4-H, 10-H), 7.83 (dd, 2H, 3-H, 11-H), 8.32, 8.33 (s, 1H, 1-H).
4.0
3.0
2.0
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