BVT-Merkblatt zu Abwasser- und Abgasbehandlung
BVT-Merkblatt zu Abwasser- und Abgasbehandlung BVT-Merkblatt zu Abwasser- und Abgasbehandlung
Annexes Annex 6 CHAPTER 5.20: INDUSTRIAL ESTABLISHMENTS WHICH CAN CAUSE AIR POLLUTION Section 5.20.1 General provisions Art. 5.20.1.1 § 1. The provisions of this chapter are applicable to the establishments specified in section 20 of the classification list. § 2. As a derogation from the general emission limit values mentioned in chapter 4.4. the emission limit values specified in other chapters of this order for specific categories of establishments also apply for the categories of establishments covered by the specified sections in § 1 with the same industrial activity. This particularly concerns the emission limit values mentioned in chapters 5.7. "Chemicals" and 5.29. "Metal" which respectively apply for the establishments as referred to in subsections 20.4 and 20.2. Section 5.20.2 Oil refineries. Art. 5.20.2.1 Scope The provisions of this section are applicable to the establishments as referred to in subsections 1.1 and 20.1.2. of the classification list. Art. 5.20.2.2 § 1. As a derogation from the provisions of the articles 5.7.6.1, chapters 5.31 and 5.43 and the general emission limit values specified in chapter 4.4., for oil refinery installations [ ¼ ] the following emission limit values apply concerning the sum of the emissions originating from heating installations, including STEG installations and processing installations: 1. from 1 January 1994: a) for sulphur dioxide: - until 31 December 1997: 2000 mg/Nm 3 - from 1 January 1998: 1300 mg/Nm 3 b) for nitrogen oxides: - until 31 December 1997: 900 mg/Nm 3 - from 1 January 1998: 450 mg/Nm 3 c) for suspended particulates: - until 31 December 1997: 300 mg/Nm 3 - from 1 January 1998: 150 mg/Nm 3 2. from 1 January 1997: for CO: - until 31 December 1997: 250 mg/Nm 3 - from 1 January 1998: 150 mg/Nm 3 3. from 1 January 1999: - for Ni and its compounds: 2 mg/Nm³ expressed in Ni - for V and its compounds: 7 mg/Nm³ expressed in V. At processing installations referred to in the first subsection include, among others: - sulphur recovery units - catalytic cracking and converting installations - incinerators - torches as well as asphalt oxidisers and all other processing units with SO 2-, NO x, CO and dust emissions. 402 Waste Water and Waste Gas Treatment
Annexes For new, large heating installations the provisions of section 5.43.2 apply, except for the emission limit values included in the section. These are replaced by the emission limit values included in appendix 5.20.2. As a derogation from article 3.2.1.2, § 3, a), for existing establishments the more stringent emission limit values apply as referred to in the third subsection, as of 1 January 2005. § 2. From 1 January 1994 the operating conditions in the operating licences for oil refineries with respect to SO 2-, NO x-, CO and dust are replaced by the provisions of § 1. § 3. For the application of the provisions of § 1 of this article, the following specifications must be respected: 1. for the definitions of flue gases and emission limit values, for new and existing heating installations and for steam and gas turbine installations (STEG) the definitions of article 1.1.2 apply, in particular concerning industrial establishments which can cause air pollution. For processing installations the actual flow rates in m 3 /hour must be converted at the normal temperature (273 °K) and pressure (101.3 kPa), but on a dry basis as specified in article 4.4.3.1. with the actual quantity of excess oxygen 2. measuring strategy for suspended particulates, SO2 , NOx , CO, Ni and V: - for heating installations, including machines with internal incineration the provisions of article 5.43.2.3. apply, §§ 1 and 2 - for processing installations, residual gas measurements are constantly conducted or the emissions are calculated on the basis of constant or periodically measured relevant parameters according to codes of good practice as in article 5.43.2.3., §§ 1 and 2 3. assessment of measuring results: for the assessment of the measuring results the following applies: - for SO2: the provisions of article 5.43.2.4 with continuous measurement or article 4.4.4.5 with discontinuous measurement - for NO x and CO: the provisions of article 5.43.5.1, § 4 with continuous measurement or article 4.4.4.5 with discontinuous measurement - for suspended particulates: the provisions in article 5.43.5.1, § 4 with continuous measurement or article 4.4.4.5 with discontinuous measurement - for Ni and V: the provisions as mentioned for NO x, in article 5.43.5.1, § 4 with continuous measurement or article 4.4.4.5 with discontinuous measurement. § 4. Gaseous effluents discontinuously released by a processing such as gaseous effluents resulting from the regeneration of catalytic agents and with inspection and cleaning activities must be transported to a combustion facility or a torch, or equivalent measures must be taken to ensure emission reduction. Gaseous effluents released with the starting up or stoppage of an installation must, to the extent possible, be transported to a collection system for gaseous effluent or incinerated in process heating installations. When this not possible, the gases must be led to a torch, in which for organic substances an emission level of 1 % with respect to the total carbon content may not be exceeded. Gaseous effluents from desulphurisation installations or other sources with a volume level of hydrogen sulphide of over 0.4 % and a mass flow of hydrogen sulphide of over 2 tonnes/day must be further processed. Gaseous effluents which are not further processed must be transported to an incinerator. As a derogation from the provisions of chapter 4.4, the emissions of hydrogen sulphide in the discharged gaseous effluent may not exceed 10 mg/Nm 3 . Hydrogen sulphide-containing water may only be processed in such a way that the release of gaseous effluent into the atmosphere is avoided. With the transfer of base, intermediary and finished products the emissions of organic substances with a vapour pressure of over 13.3 kPa at a temperature of 35 °C must be reduced by means of appropriate measures, such as by gas pendulum, extraction and transfer to an effluent gas purification installation. Waste Water and Waste Gas Treatment 403
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Annexes<br />
For new, large heating installations the provisions of section 5.43.2 apply, except for the emission<br />
limit values included in the section. These are replaced by the emission limit values included<br />
in appendix 5.20.2.<br />
As a derogation from article 3.2.1.2, § 3, a), for existing establishments the more stringent<br />
emission limit values apply as referred to in the third subsection, as of 1 January 2005.<br />
§ 2. From 1 January 1994 the operating conditions in the operating licences for oil refineries<br />
with respect to SO 2-, NO x-, CO and dust are replaced by the provisions of § 1.<br />
§ 3. For the application of the provisions of § 1 of this article, the following specifications must<br />
be respected:<br />
1. for the definitions of flue gases and emission limit values, for new and existing heating installations<br />
and for steam and gas turbine installations (STEG) the definitions of article 1.1.2<br />
apply, in particular concerning industrial establishments which can cause air pollution.<br />
For processing installations the actual flow rates in m 3 /hour must be converted at the normal<br />
temperature (273 °K) and pressure (101.3 kPa), but on a dry basis as specified in article<br />
4.4.3.1. with the actual quantity of excess oxygen<br />
2. measuring strategy for suspended particulates, SO2 , NOx , CO, Ni and V:<br />
- for heating installations, including machines with internal incineration the provisions of<br />
article 5.43.2.3. apply, §§ 1 and 2<br />
- for processing installations, residual gas measurements are constantly conducted or the<br />
emissions are calculated on the basis of constant or periodically measured relevant parameters<br />
according to codes of good practice as in article 5.43.2.3., §§ 1 and 2<br />
3. assessment of measuring results:<br />
for the assessment of the measuring results the following applies:<br />
- for SO2: the provisions of article 5.43.2.4 with continuous measurement or article 4.4.4.5<br />
with discontinuous measurement<br />
- for NO x and CO: the provisions of article 5.43.5.1, § 4 with continuous measurement or<br />
article 4.4.4.5 with discontinuous measurement<br />
- for suspended particulates: the provisions in article 5.43.5.1, § 4 with continuous measurement<br />
or article 4.4.4.5 with discontinuous measurement<br />
- for Ni and V: the provisions as mentioned for NO x, in article 5.43.5.1, § 4 with continuous<br />
measurement or article 4.4.4.5 with discontinuous measurement.<br />
§ 4. Gaseous effluents discontinuously released by a processing such as gaseous effluents resulting<br />
from the regeneration of catalytic agents and with inspection and cleaning activities<br />
must be transported to a combustion facility or a torch, or equivalent measures must be taken to<br />
ensure emission reduction.<br />
Gaseous effluents released with the starting up or stoppage of an installation must, to the extent<br />
possible, be transported to a collection system for gaseous effluent or incinerated in process<br />
heating installations. When this not possible, the gases must be led to a torch, in which for organic<br />
substances an emission level of 1 % with respect to the total carbon content may not be<br />
exceeded.<br />
Gaseous effluents from desulphurisation installations or other sources with a volume level of<br />
hydrogen sulphide of over 0.4 % and a mass flow of hydrogen sulphide of over 2 tonnes/day<br />
must be further processed.<br />
Gaseous effluents which are not further processed must be transported to an incinerator.<br />
As a derogation from the provisions of chapter 4.4, the emissions of hydrogen sulphide in the<br />
discharged gaseous effluent may not exceed 10 mg/Nm 3 .<br />
Hydrogen sulphide-containing water may only be processed in such a way that the release of<br />
gaseous effluent into the atmosphere is avoided.<br />
With the transfer of base, intermediary and finished products the emissions of organic substances<br />
with a vapour pressure of over 13.3 kPa at a temperature of 35 °C must be reduced by<br />
means of appropriate measures, such as by gas pendulum, extraction and transfer to an effluent<br />
gas purification installation.<br />
Waste Water and Waste Gas Treatment 403