BVT-Merkblatt zu Abwasser- und Abgasbehandlung
BVT-Merkblatt zu Abwasser- und Abgasbehandlung BVT-Merkblatt zu Abwasser- und Abgasbehandlung
Annexes Emission limits for the production of several organic substances Substance Emission standard [mg/l] [g/tonne installed production capacity] 1. Ethylbenzene, cumene 1.0 20 2. Acetaldehyde, vinyl acetate 1.0 30 3. Vinyl chloride (VC) 1.0 2 4. Trichlorophenols (TCP, all isomers) 1.0 20 5. Trichlorobenzenes 0.2 2 (TCB, all isomers) 6. Tetrachloromethane 1.5 3 7. Hexachlorobutadiene (HCBD) 1.5 2 8. Ethane-1,2-dichloride (EDC) 1.0 2 9. Trichloroethene (TRI) 1.0 3 10. Perchloroethene (PER) 1.0 3 11. Halogenated organic solvents ex- 1.0 10 cept: 1,2,4-trichlorobenzene and items 6 – 11 To meet the emission limits, four out of five successively measured values have to be lower than the emission limit value and only one measured value may exceed the emission limit (maximum 50 % of the emission limit). The majority of the parameters have to be determined with mass proportional homogeneous daily average samples. The parameters temperature, TSS, pH, cyanide, sulphide, POX and sum of volatile aromatics (BTXE) are determined with random samples. For the production of acetylene with calcium carbide as raw material emission limits are set in the ordinance “Verordnung über die Begrenzung von Abwasseremissionen aus der Herstellung von technischen Gasen” (BGBl. 1996/670). All acetylene plants in Austria use calcium carbide processes for acetylene production Emission standards for the production of acetylene from calcium carbide General parameters Standards for the discharge in Standards for the discharge in the surface water public sewerage system Temperature 35 °C 40 °C TL 4 No impairment of the public waste water treatment plant TF 2 No impairment of the public waste water treatment plant TSS 50 mg/l No impairment of the operation of the public sewage system or wastewater treatment plant pH 6.5 – 9 6.5 – 10 Inorganic parameters Standards for the discharge in Standards for the discharge in the running waters public sewerage system Iron (calculated as Fe) 2 mg/l Limited with the standard for TSS Ammonium (calculated as N) 10 mg/l - Cyanide (easy to release and calculated as CN) 0.1 mg/l 0.1 mg/l Total phosphorus (calculated as P) 1 mg/l - Sulphate (calculated as SO4) - 200 mg/l Sulphide (calculated as S) 0.1 mg/l 1 mg/l Sulphite (calculated as SO3) 1 mg/l 10 mg/l Organic parameters Standards for the discharge in Standards for the discharge in the running waters public sewerage system COD (calculated as O2) 50 mg/l - Sum of hydrocarbons 10 mg/l 20 mg/l Phenolindex (calculated as phenol) 0.1 mg/l 10 mg/l To meet the emission limits, four out of five successively measured values have to be lower than the emission limit value and only one measured value may exceed the emission limit (maximum 50 % of the emission limit). The majority of the parameters have to be determined with mass proportional homogeneous daily average samples. The parameters temperature, TSS, pH, cyanide, sulphide are determined with random samples. 356 Waste Water and Waste Gas Treatment
Annexes The ordinance “Verordnung über die Begrenzung von Abwasseremissionen aus der Herstellung von anorganischen Düngemitteln sowie von Phosphorsäure und deren Salzen “ (BGBl. 1996/669) regulates the emission standards for the discharge of waste water from melamine and urea production. Emission standards for waste water from urea and melamine production General parameters Standards for the discharge into Standards for the discharge into surface water the public sewerage system Temperature 30 °C 35 °C TF 4 No impairment of the public waste water treatment plant TSS 30 mg/l 150 mg/l pH 6.5–8.5 6.5–9.5 Inorganic parameters Standards for the discharge into Standards for the discharge into surface water the public sewerage system Ammonium (calculated as N) 0.5 kg/t 0.5 kg/t Nitrate (calculated as N) 0.5 kg/t 0.5 kg/t Nitrite (calculated as N) 0.02 kg/t 0.02 kg/t Organic parameters Standards for the discharge into Standards for the discharge into surface water the public sewerage system COD (calculated as O2) 0.5 kg/t - The emission standards are related to the installed production capacity of the plant (related to the tonne nitrogen in the final product). To meet the emission limits, four out of five successively measured values have to be lower than the emission limit and only one measured value may exceed the emission limit (maximum 50 % of the emission limit). Most of the parameters have to be determined with mass proportional homogeneous daily average samples. The parameters temperature, filter out matter, pH and nitrite have to be determined with random samples. 2. BELGIUM Flemish Legislation on Waste Water and Waste Gas in the Chemical Sector In the Flemish environmental legislation, VLAREM, the chemical sector is classified under different subsections: � classification number 7 ‘Chemicals’ (see Annex 1) � classification number 17 ‘Hazardous Substances’ (see Annex 2) � classification number 20.4 ‘Chemical Industry, Industrial activities subject to 84/360/EEG’ (see Annex 3) Chemical plants are subject to some sector-specific legislation that may differ from the general environmental legislation specified in VLAREM: � Vlarem II, Hoofdstuk 5.7 ‘Chemicals’ (classification number 7) (see Annex 4) � Vlarem II, Hoofdstuk 5.17 ‘Hazardous Substances’ (classification number 17) (see Annex 5) � Vlarem II, Hoofdstuk 5.20 ‘Industrial activities that can give rise to air pollution’ (classification number 20) (see Annex 6) Waste Water and Waste Gas Treatment 357
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Annexes<br />
The ordinance “Verordnung über die Begren<strong>zu</strong>ng von <strong>Abwasser</strong>emissionen aus der Herstellung<br />
von anorganischen Düngemitteln sowie von Phosphorsäure <strong>und</strong> deren Salzen “ (BGBl.<br />
1996/669) regulates the emission standards for the discharge of waste water from melamine and<br />
urea production.<br />
Emission standards for waste water from urea and melamine production<br />
General parameters Standards for the discharge into Standards for the discharge into<br />
surface water<br />
the public sewerage system<br />
Temperature 30 °C 35 °C<br />
TF 4 No impairment of the public waste<br />
water treatment plant<br />
TSS 30 mg/l 150 mg/l<br />
pH 6.5–8.5 6.5–9.5<br />
Inorganic parameters Standards for the discharge into Standards for the discharge into<br />
surface water<br />
the public sewerage system<br />
Ammonium (calculated<br />
as N)<br />
0.5 kg/t 0.5 kg/t<br />
Nitrate (calculated as N) 0.5 kg/t 0.5 kg/t<br />
Nitrite (calculated as N) 0.02 kg/t 0.02 kg/t<br />
Organic parameters Standards for the discharge into Standards for the discharge into<br />
surface water<br />
the public sewerage system<br />
COD (calculated as O2) 0.5 kg/t -<br />
The emission standards are related to the installed production capacity of the plant (related to the tonne nitrogen in the<br />
final product).<br />
To meet the emission limits, four out of five successively measured values have to be lower than the emission limit and<br />
only one measured value may exceed the emission limit (maximum 50 % of the emission limit). Most of the parameters<br />
have to be determined with mass proportional homogeneous daily average samples. The parameters temperature, filter<br />
out matter, pH and nitrite have to be determined with random samples.<br />
2. BELGIUM<br />
Flemish Legislation on Waste Water and Waste Gas in the Chemical Sector<br />
In the Flemish environmental legislation, VLAREM, the chemical sector is classified <strong>und</strong>er<br />
different subsections:<br />
� classification number 7 ‘Chemicals’<br />
(see Annex 1)<br />
� classification number 17 ‘Hazardous Substances’<br />
(see Annex 2)<br />
� classification number 20.4 ‘Chemical Industry, Industrial activities subject to 84/360/EEG’<br />
(see Annex 3)<br />
Chemical plants are subject to some sector-specific legislation that may differ from the general<br />
environmental legislation specified in VLAREM:<br />
� Vlarem II, Hoofdstuk 5.7 ‘Chemicals’ (classification number 7)<br />
(see Annex 4)<br />
� Vlarem II, Hoofdstuk 5.17 ‘Hazardous Substances’ (classification number 17)<br />
(see Annex 5)<br />
� Vlarem II, Hoofdstuk 5.20 ‘Industrial activities that can give rise to air pollution’ (classification<br />
number 20)<br />
(see Annex 6)<br />
Waste Water and Waste Gas Treatment 357