03.12.2012 Aufrufe

298 94 307/02 Untersuchungen zum Stand der Umsetzung des ...

298 94 307/02 Untersuchungen zum Stand der Umsetzung des ...

298 94 307/02 Untersuchungen zum Stand der Umsetzung des ...

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Teil 3 Seite 10-2<br />

costs for the cooling lubricant on the basis of saturated fatty acids, since approx. 16 kg of<br />

rape seed oil needs to be prepared for the manufacture of one kilogram of this fraction.<br />

In preliminary trials at the Institute for Energy and Environmental Technology of the Food<br />

Industry (LEU) at the Munich-Weihenstephan TU, a methyl ester was manufactured on<br />

the basis of animal fats. The saturated fatty acid content (C14:0 – C18:0) is approx. 54%<br />

in animal fat. Rape seed oil exhibits a substantially higher content of unsaturated fatty<br />

acids, which on the basis of double bonding oxidise far more easily, and therefore do not<br />

exhibit as long a utilisable life-span, since they deteriorate very quickly. The subsequent<br />

transesterification process does not change the percentage distribution of the fatty acid<br />

components.<br />

Achieved environmental benefits<br />

Cross media effects<br />

A full and problem free substitution of the exhaustible resource represented by cooling<br />

lubricant manufactured from mineral oil is possible through the sustainable raw material<br />

represented by animal fat, since approx. 300.000 t of animal fat is currently produced in<br />

animal carcass disposal plants in Germany per annum. In this regard, primarily slaughter-<br />

ing waste from slaughtering houses (2,6 million t), as well as animal carcasses (150.000 t)<br />

are processed.<br />

On the basis of these 3000.000 t of animal fat, the outlined process allows approx.<br />

150.000 t of saturated fatty acids to be separated and to be processed into cooling lubri-<br />

cants. In comparison, the annual demand for cooling lubricants in Germany is approx.<br />

75.000 t. Demand can therefore be met fully on the basis of animal fats.<br />

However, markets can also be created for the remnant of saturated fatty acids not utilis-<br />

able as cooling lubricants (75.000 t) and the entire volume of unsaturated fatty acids<br />

(150.000 t). In this regard, for example, the annual total demand for lubricants is approx.<br />

1,2 million t. Cooling lubricants here only have a small market share at 75.000 t. Larger<br />

volumes are consumed in the motor oil (385.000 t), hydraulic oil (150.000 t), processed oil<br />

(144.000 t), gear lubricant oil (95.000 t), as well as the base oil (83.000 t) sector. The total<br />

volume of animal fats or animal fat ester can therefore easily be integrated into the Ger-<br />

man lubricant market.<br />

Operational data Applicability<br />

Within the framework of research conducted with the co-operation of various project<br />

partners, non-water miscible cooling lubricants are to be manufactured. For the first time,<br />

animal fats from animal carcass conversion plants and used nutrient fats are to be used<br />

as a source of raw materials. These fats are purified and subjected to a transesterification<br />

process, and the fatty acid ester is then subsequently fractionated. The technique of water<br />

vapour distillation is to be adapted to the necessary requirements within this context and<br />

optimised for the purification of raw materials. This is necessary to eliminate unpleasant<br />

odorous substances, e.g. short-wrap fatty acids, aldehy<strong>des</strong> or ketones. If required, treat-<br />

ment with active charcoal can subsequently be carried out in or<strong>der</strong> to enhance purification<br />

performance further.

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