298 94 307/02 Untersuchungen zum Stand der Umsetzung des ...

298 94 307/02 Untersuchungen zum Stand der Umsetzung des ... 298 94 307/02 Untersuchungen zum Stand der Umsetzung des ...

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03.12.2012 Aufrufe

J Drying See description under 1 Limed bone process. 6 ACID HIDE PROCESS P Cutting See description under 5 Limed hide process. T Acid treatment See description under 1 Limed bone process. See description under 1 Limed bone process. I Sterilisation See description under 1 Limed bone process. V Alkali treatment Teil 3 Seite 6-23 Hydrochloric acid, or another acid, is added until the pH of the solution is 1 - 3. These conditions are kept for 24 – 48 hours, by adding more acid, if necessary. U Neutralisation The excess acid is removed by washing with water to reach a typical pH of 5.3 – 6.0, but a pH of 2.5 – 4.0 is also possible. E Extraction F Filtration G Ion exchange See description under 1 Limed bone process. H Concentration See description under 1 Limed bone process. See description under 1 Limed bone process. J Drying 7 SODIUM HYDROXIDE HIDE PROCESS P Cutting See description under 5 Limed hide process. NaOH solution is added to the washed hide splits, to a concentration of 0.6 - 1.4 %. The alkaline soak takes a minimum 10 days. During the process, the pH is approximately 12.5 or higher. Finally air is regularly blown through the solution. W Washing and acid treatment When the caustic treatment is finished, the raw material is washed in water until a pH of about 10 is achieved. An acid solution is then added to neutralise the solution. pH’s lower than the extraction pH is aimed for. X Neutralisation

Teil 3 Seite 6-24 The excess acid is removed by washing with water, until a slightly acid, but close to neu- tral pH of about 5.5 – 7.5, is reached. E Extraction See description under 1 Limed bone process. F Filtration See description under 1 Limed bone process. G Ion exchange See description under 1 Limed bone process. H Concentration See description under 1 Limed bone process. I Sterilisation See description under 1 Limed bone process. J Drying See description under 1 Limed bone process. 8 PIG SKIN PROCESS The pig skins, whether they are fresh or frozen, contain a large amount fat. A typical ex- ample of the composition of a batch of pig skins is: water content 56 %, fat 25 %, protein 18 % and minerals 1 %. There are four treatment steps, before gelatine extraction. Y Cutting The pig skins are cut into pieces of about 10 x 10 cm, in a special cutting machine. Z Washing The pig skin pieces are washed in a tank, to remove external fat, before demineralisa- tion/acidulation. A1 Demineralisation/acidulation and rinsing The pig skin pieces are demineralised, in a tank, with dilute sulphuric acid or hydrochlo- ric acid to a pH of about 1.8, for at least 5 hours. The acid solution is then removed and the pig skin pieces are then rinsed. B1 Neutralisation and rinsing The tank is filled with an alkaline solution of e.g., ammonia, to neutralise the pig skin pieces. The solution is then removed and the neutralised pig skin are rinsed, to reach a pH suitable for extraction of the gelatine. The treated pig skins are then transferred to the extraction tanks E Extraction

J Drying<br />

See <strong>des</strong>cription un<strong>der</strong> 1 Limed bone process.<br />

6 ACID HIDE PROCESS<br />

P Cutting<br />

See <strong>des</strong>cription un<strong>der</strong> 5 Limed hide process.<br />

T Acid treatment<br />

See <strong>des</strong>cription un<strong>der</strong> 1 Limed bone process.<br />

See <strong>des</strong>cription un<strong>der</strong> 1 Limed bone process.<br />

I Sterilisation<br />

See <strong>des</strong>cription un<strong>der</strong> 1 Limed bone process.<br />

V Alkali treatment<br />

Teil 3 Seite 6-23<br />

Hydrochloric acid, or another acid, is added until the pH of the solution is 1 - 3. These<br />

conditions are kept for 24 – 48 hours, by adding more acid, if necessary.<br />

U Neutralisation<br />

The excess acid is removed by washing with water to reach a typical pH of 5.3 – 6.0, but<br />

a pH of 2.5 – 4.0 is also possible.<br />

E Extraction<br />

F Filtration<br />

G Ion exchange<br />

See <strong>des</strong>cription un<strong>der</strong> 1 Limed bone process.<br />

H Concentration<br />

See <strong>des</strong>cription un<strong>der</strong> 1 Limed bone process.<br />

See <strong>des</strong>cription un<strong>der</strong> 1 Limed bone process.<br />

J Drying<br />

7 SODIUM HYDROXIDE HIDE PROCESS<br />

P Cutting<br />

See <strong>des</strong>cription un<strong>der</strong> 5 Limed hide process.<br />

NaOH solution is added to the washed hide splits, to a concentration of 0.6 - 1.4 %. The<br />

alkaline soak takes a minimum 10 days. During the process, the pH is approximately 12.5<br />

or higher. Finally air is regularly blown through the solution.<br />

W Washing and acid treatment<br />

When the caustic treatment is finished, the raw material is washed in water until a pH of<br />

about 10 is achieved. An acid solution is then added to neutralise the solution. pH’s lower<br />

than the extraction pH is aimed for.<br />

X Neutralisation

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