relevant information - Gelest Inc.

Gelest, Inc.
Acrylatesilanes
in dental
restorative
composites.
Silane Coupling Agents for Thermosets
Selection Chart
Coupling Agent Class
Suggestions for Primary Screening
O
Acrylate, UV cure
C OCH 3
Acrylate SIA0200.0 SIM6487.4
CH 2 C
Vinyl/Olefin
SIS6964.0
H
(COOCCH 2 CH CH 2 ) 2
n
Diallylphthalate Amine SIA0591.0 SIA0610.0
Vinyl/Olefin
SIS6964.0
Epoxy Amine SIA0591.0 SIT8398.0
OH
O
CH 3
CH 3
O Anhydride
SIT8192.6
H 2 CCHCH 2 O C
O CH 2 CH CH 2 O
CH 2 O CH 2 CH CH 2
CH 3
n CH 3 Epoxy
SIG5840.0
O
Epoxy, UV Cure Amine SIA0591.0 SIT8398.0
C O CH 2
O
O
Epoxy SIE4668.0 SIE4670.0
O
O
Polyimide Amine SIA0599.2 SIA0591.0
N
N R
Halogen SIC2295.5 SIC2296.2
O
O
Dipodal
SIB1833.0
n
Furan Amine SIA0611.0 SIA0599.0
CH 2 O
O
Epoxy
SIG5840.0
n
CH
Melamine 3 OCH 2 NH N NHCH 2 OCH 3
Amine SIA0611.0 SIA0599.0
N N
Hydroxyl
SIB1140.0
Dipodal SIB1833.0 SIT8717.0
NHCH 2 OCH 3
Parylene Halogen SIC2295.5
CH 2 CH 2 Vinyl/Olefinic SIS6990.0 SIM6487.4
n
Dipodal SIB1832.0 VMM-010
OH
Phenol-formaldehyde CH 2 OH Amine SIA0611.0 SIT8187.5
Epoxy SIE4670.0 SIG5840.0
O
Methylmethacrylate, cast C OCH 3 Acrylate SIM6487.4 SIA0200.0
CH 2 C
Amine
SIB1828.0
CH 3
n
Polyester, unsaturated
O
Acrylate SIM6487.4
COCH CHCOCH 2 CH 2 OCH 2 CH 2 O
n Vinyl/Olefin SIS6994.0 SIV9112.0
Urea-formaldehyde O O Amine SIA0610.0 SIU9055.0
HOCH 2 NHCNHCH 2 NHCNHCH 2 OH
Hydroxyl
SIB1140.0
Urethane Amine SIA0610.0 SIM6500.0
CH 3
H 3 C
Isocyanate
SII6455.0
O
Sulfur
SIM6476.0
CH 2
CH 3
N
C
O
CH 3
CH 2 CHO(CH 2 CHO) n CH 2 CH
n
(215) 547-1015 FAX: (215) 547-2484 www.gelest.com
21
© 2006 Gelest, Inc.

Gelest, Inc.
Diamine-silanes
couple
polycarbonate
in CDs
Silane Coupling Agents for Thermoplastics
Selection Chart
Coupling Agent Class
Suggestions for Primary Screening
Polyacetal CH 2 O
Vinyl/Olefin SIS6994.0
O
C OCH 3
n
Polyacrylate CH 2 C
Amine SIU9058.0 SIA0610.0
H
n
Polyamide O
Amine SIA0610.0 SIA0614.0
NH(CH 2 ) m C
Dipodal SIB1834.1 SSP-060
n
Water-borne
WSA-7011
O
O
Polyamide-imide Amine SIA0610.0
N
N R
H
Halogen
SIC2295.5
O
n
Polybutylene terephthalate Amine SIA0610.0
C
CO(CH 2 ) m O
O
O
n Isocyanate
SII6455.0
CH 3
O
C
O C
Polycarbonate Amine SIA0591.0 SIA0610.0
CH 3
O
O
Polyether ketone Amine SIA0591.0
O
C
Dipodal
SIT8717.0
n
n
Polyethylene Amine SIA0591.0 SIT8398.0
CH 2 CH 2 n Vinyl/Olefin SSP-055 SIV9112.0
Polyphenylene sulfide Amine SIA0605.0
S
Halogen
SIC2295.5
n
Sulfur
SIM6476.0
Polypropylene CH 3
Acrylate SIM6487.4
CH
Azide
SIA0780.0
2 CH
n Vinyl/Olefin VEE-005 SSP-055
Polystyrene
CH 2 CH
Acrylate SIM6487.4
Dipodal
SIB1831.0
CH 3
n
C
O
S
Polysulfone Amine SIA0591.0 SIU9055.0
CH 3
O
O
n
© 2006 Gelest, Inc.
CH 2 CH 2
O O
Polyvinyl butyral Amine SIA0611.0 SIU9058.0
CH 2 CH 2 CH 3 n
Cl
Polyvinyl chloride Amine SIA0605.0
CH 2 CH
Sulfur SIM6474.0 SIB1825.0
n
(215) 547-1015 FAX: (215) 547-2484 www.gelest.com
22

Gelest, Inc.
Water-borne aminosilanes
increase bonding
of acrylic
latex
sealants
Silane Coupling Agents for Sealants & Elastomers
Selection Chart
Coupling Agent Class
Suggestions for Primary Screening
O
Acrylic latex
C OCH 3
Acrylate SIM6487.4
CH 2 C Vinyl/Olefin SIV9210.0 SIV9218.0
Water-borne WSA-7021 WSA-6511
CH 3
Butyl Acrylate SIM6487.4
CH 2 CH CHCH 2 n
Sulfur SIB1825.0 SIM6476.0
Vinyl/Olefin SSP-055 VEE-005
Epichlorohydrin OCH 2 CH
Amine SIA0605.0
CH 2 Cl n
Sulfur
SIM6474.0
Fluorocarbon (CF Amine SIB1834.1
2 CF 2 ) m (CH 2 CF 2 ) n
Dipodal
SIT8717.0
CH 3
Isoprene Sulfur SIM6474.0 SIM6476.0
CH 2 C CHCH 2
Vinyl/Olefin SSP-055 VEE-005
Cl
n
Neoprene Sulfur SIM6474.0 SIM6476.0
CH 2 C CHCH 2
Vinyl/Olefin SSP-055 VEE-005
CN
n
Nitrile Epoxy SIG5840.0
CH 2 CH
Sulfur
SIB1825.0
CH 2 CH CH
n
n
Polysulfide Epoxy SIG5840.0
CH 2 CH 2 S n
Sulfur SIB1825.0 SIM6476.0
CH 2 CH CH 2 CH CH
n
SBR Amine SIA0605.0
Sulfur SIB1825.0 SIM6486.0
CH
Silicone 3 CH 3 CH 3
Amine SIA0605.0 SIA0589.0
HO Si O Si O Si OH
(hydroxyl terminated) Vinyl/Olefin SIV9098.0 VMM-010
CH 3 CH 3 n CH 3
Dipodal
SIB1824.0
CH 3
CH 3
CH 3
Silicone Acrylate SIM6487.4
H 2 C CH Si
(vinyl terminated) Vinyl/Olefin SIA0540.0 VMM-010
O Si O Si CH CH 2
CH 3 CH 3 n CH 3
(215) 547-1015 FAX: (215) 547-2484 www.gelest.com
23
© 2006 Gelest, Inc.

Gelest, Inc.
aldehyde-,
amino-, and
hydroxylsilanes
couple
DNA in array
technology
Silane Coupling Agents for Biomaterials
Selection Chart
Suggestions
Site/Type Coupling Class Co-reactant for Screening
Oligonucleotides hydroxyl SIB1140.0
diamine cobalt ethylenediamine SIA0591.0
G. McGall et al, J. Am. Chem. Soc., 119, 5081, 1997. F. Chow, in
“Silylated Surfaces” D. Leyden ed., Gordon & Breach, 1978, p.301.
DNA terminal favored vinyl/olefin SIO6708.0 SIU9049.0
pendant amine aldehyde SIT8194.0
pendant amine diamine SIA0594.0 SID3543.0
pendant amine epoxy SIE4675.0 SIG5838.0
A. Bensimon, Science, 265, 2096, 1994. J. Grobe et al, J. Chem.
Soc. Chem. Commun, 2323, 1995. C. Kneuer et al, Int'l J.
Pharmaceutics, 196(2), 257, 2000.
mitochondria
on silica bead
Protein lysine aldehyde SIT8194.0
lysine amine glutaraldehyde SIA0611.0 SIA0595.0
lysine amine thiophosgene SIA0611.0
cysteine sulfur dithionite SIM6476.0
tyrosine nitrobenzamide NaNO2/HCl SIT8191.0 SIA0599.0
heparinated amine/quat SSP-060 SIT8415.0
immunoglobin pyridyl-thio SIP6926.4
antibody cyano SIC2456.0
Cell-Organelle
J. Grobe et al, J. Chem. Soc. Chem. Commun, 2323, 1995. H. Weetall, US Pat. 3,652,761. G.
Royer, CHEMTECH, 4, 699, 1974. S. Bhatia et al, Anal. Biochem., 178, 408, 1989. J. Venter
et al, Proc. Nat. Acad. Soc., 69(5), 1141, 1972. R. Merker et al, Proc. Artificial Heart Prog.
Conf., June 9-13, 1969 HEWNIH, p29. S. Falipou, Fundamental & Applied Aspects of
Chemically Modified Surfaces, p389, 1999.
chloroplast alkyl SIO6645.0
mitochondria alkyl SIO6645.0
B. Arkles et al, in “Silylated Surfaces” D. Leyden ed., Gordon & Breach,
1978, p363. B. Arkles et al, J. Biol. Chem., 250, 8856, 1975.
Whole Cell
erythrocytes short alkyl SIE4901.4
erythrocytes on
glass wall
B. Arkles et al, in "Silylated Surfaces" D. Leyden ed., Gordon & Breach,
1978, p363.
© 2006 Gelest, Inc.
Whole Cell procaryotic alkyl-quat SIO6620.0
(causing lysis)
SID3392.0
W. White et al in "Silanes, Surfaces & Interfaces"
ed. D. Leyden, Gordon & Breach, 1986, p. 107.
Tissue histological samples SIA0611.0 SIA0610.0
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