08.07.2015 Views

i UNIVERSIDADE ESTADUAL DE CAMPINAS INSTITUTO DE ...

i UNIVERSIDADE ESTADUAL DE CAMPINAS INSTITUTO DE ...

i UNIVERSIDADE ESTADUAL DE CAMPINAS INSTITUTO DE ...

SHOW MORE
SHOW LESS

Create successful ePaper yourself

Turn your PDF publications into a flip-book with our unique Google optimized e-Paper software.

"!¤¢¡£¢£¤¦¥¨§©¤§§¡§¨§(¨¡£) "¤#*¤#¢£$¤%£¡&'JLKNMPOQSRUT*VW+XZY\[]RQSR^_V[a`cbYdK:efRfQVgJLhdYdefY\bS`ci]jkRlmbnM:VoXZbS`QVpG`cbnM:`qM:RcKEOSKA`kbQSRRf^_raM:RsQRftEQSYuM:YwvcRxQVgJLbSVoXZycY\``qMAXZ`$vcrKzQV*35c7A‚5‚57D7FB]ƒ„:


šFICHA CATALOGRÁFICA ELABORADA PELA BIBLIOTECA DO <strong>INSTITUTO</strong> <strong>DE</strong>QUÍMICA DA UNICAMPSa59eSanvido, Cibelle de Souza.Estudo teórico do mecanismo de eliminação internade xantatos usando o método aditivo de energia atravésde ONIOM com pseudopotencial / Cibelle de SouzaSanvido. -- Campinas, SP: [s.n], 2006.Orientador: Nelson Henrique Morgon.Dissertação - Universidade Estadual de Campinas,Instituto de Química.1. Xantatos. 2. Método aditivo de energia. 3. ONIOM.4. Pseudopotencial. I. Morgon, Nelson Henrique.II. Universidade Estadual de Campinas. Instituto deQuímica. III. Título.Título em inglês: Theoretical study of the internal elimination of xanthates usingONIOM additivity and pseudopotentialsPalavras-chaves em inglês: Xanthates, Additivity expression, ONIOM, PseudopotentialÁrea de concentração: Físico-QuímicaTitulação: Mestre em Química na Área de Físico-QuímicaBanca examinadora: Nelson Henrique Morgon (orientador), Rogério Custódio, KalineRabelo CoutinhoData de defesa: 15/08/2006


æ ç §¦ çéèç ¨ ê §?ª¢ß¤ë¥ìí£îïñðòËï$ï$îìôó2ïÍ?·2¸›¸š· Ê ·ãA° ¾ZÌ Ä&ãPÄmº œA šÊ °¼°ÁÕ&·´õkÔÄ=Æ÷Ä Ê ·SÄm¹ Ù2 Õ&·Œº¿Æ%°ZõcøÁùNÚ´øNúÁÚ:û6üÁúÁúöÄ Ù2 °ÁºCÄm¸ šÊ Ä Ê ·mõqýn²ÇÄm¹ ¸š· ²%ÄÄ´Æ ¾ ²%Äm¸ Ê ·ÔÞÄmÕà ºZÄm¹nÝÜãP±â+º Ê ·Œ²%·ŒÈ2°ZõnÒ ¾ ı…· Ê ²¦°ã:ÄmºNÆ ¾ZÙŒÙ2 ÿþ¡ £¢ÔÞÄmÕà ºZÄm¹ÜÝÜãP±·#ÝwÕ&Ä ¸ õ ÙŒ Í?·2¸š¸›·¥¤ š½ Õµ¾ º šÙ ÄmÕ&ÃaµÍZ²¦ © ìôî Þìí© óÞì¢ øÁø´Ý ¢ øÁø À·2¹¦Æ%²ÇÄ Ê °&·ŒÕ× ¾ZØ Õ šÙ Ä­›œ ·2²¦¹ šÊ Ä Ê ·ôâ+¹¦ÆÇÄ ÊZ¾ Äm¸ Ê ·ÔÞÄmÕà ºCÄm¹Û¼º¢ øÁø£ ›Ù ·2º Ù2 Ä=Æ ¾ ²%Ä*·2Õ× ¾ZØ Õ ›Ù Ä­,û8üÁüÁü=Ý›œ ·2²¦¹ šÊ Ä Ê ·ôâ+¹¦ÆÇÄ ÊZ¾ Äm¸ Ê ·ÔÞÄmÕà ºCÄm¹Û¼º¢ ÝÇû6üÁü…· Ù ºZ°Á¸›°ÁÂ Ä Ê ·®¸ Õ&·Œº¿Æ%°Á¹­,û8üÁü›œ ·2²¦¹ šÊ Ä Ê ·ôâ+¹¦ÆÇÄ ÊZ¾ Äm¸ Ê ·ÔÞÄmÕà ºCÄm¹Û¼ºœ: ›


¯tut—T tqpr!sTs% Ò¼â0sÖdÔÜ®7ßã$ËÛ ö-vw% áxË»SâfÖ\+ËâcÒ¼®7 â)ÖdÀÖ\®0sÖ % % áy/‰»¼®/.…®0ËâkãË»â ÄmºNÆÇÎ šÙ Ä Ù2 ›Ê ÎCÄ œ ·kÍ]·Œ·2º º œ ·2¹dÆ ÂNÄ´ÆÇ· ʾ ¹ ºP % ¼Ö % ÀU® ÊZÊZ Æ ›œA Æ4{‰â ÃZ²%·Œ¹%¹ °Áº*Ä´º Ê ±+¹¦· ¾ZÊ °mÃ]°´ÝÄm¸ þ % ¼Ö % À|EÔsÔsã ö 8Z+


¹dÆ÷Ä Ê ·¨0Ä´Í]·Œ¸ÅÄm¹ µµµµµµµµµµôµµµµµµµµµµôµµµµµµµµµµµôµµ AœA š¹dÆ÷Ä Ê ·á  ¾ ²ÇÄm¹¼µôµµµµµµµµµµôµµµµµµµµµµôµµµµµµµµµµµôµµ GP®S¸ Ù °š` ¹/µµµµµµµµµôµµµµµµµµµµôµµµµµµµµµµµôµµ ¢ûÁµûÁµû ` ¹EµµµµµµµµµµôµµµµµµµµµµôµµµµµµµµµµµôµµûÁµûÁµ¢µ¢ ®åCº šÊ Ä Ê ·â+¸›·ŒÆDzœLÁº ›Ù Ä µôµµµµµµµµµµôµµµµµµµµµµµôµµ û¥ûÁµ¢× ¾ZØ Õ ›Ù ÄY…·D`Á² šÙ Ä&µµµµµµµµôµµµµµµµµµµôµµµµµµµµµµµôµµ û ûÁµ_ŒûŠ.ç ¨‹ §o«Œ Ž ¥‘J’”“–•˜—£R’ûÁµû ã ¹¦Æ%·2Õ&Äm¹¼× ¾ZØ Õ šÙ °Á¹sâ+¹¦Æ ¾ZÊ Ä Ê °m¹ µµµµµµµµµµôµµµµµµµµµµµôµµ/‰ÄmºNÆÇÄ´ÆÇ°Á¹µµµµµµµµôµµµµµµµµµµôµµµµµµµµµµµôµµ ùûÁµûÁµ_â+¹¦Æ ¸šÍ?·2ºZ° µµµµµµµôµµµµµµµµµµôµµµµµµµµµµµôµµ û6øûÁµûÁµ›ûÁµ¢ ±+²%°mÃZ² · Ê Ä Ê ·2¹·Œ²%Õ° ÊP º ? Õ šÙ Äm¹GµµµµµµµµµµôµµµµµµµµµµµôµµûÁûûÁµ¢ µû ®åCº šÊ Ä Ê ·Ã?°Á²Ë±+²M`´ÆÇ°Áº µôµµµµµµµµµµôµµµµµµµµµµµôµµûÁûûÁµ_Pµû % Ã]·Œ²ÇÄ Ê °m²»ÄmÕ ¸›Æ%°Áº ÄmºZ° µµµµµµµµµôµµµµµµµµµµµôµµûJ·Œ°Á² Ä Ê °ÔÞÄ´Õ&Ã?°® ¾ Æ%°´Ý Ù °ÁºZ¹ ¹¦Æ%·2ºNÆÇ· µµµôµµµµµµµµµµµôµµ ûûÁµ_Pµ¢ÀÓŒÆ%° Ê ° »á µµµµµµôµµµµµµµµµµôµµµµµµµµµµµôµµ û6üûÁµ_Pµ_ Õ ÆÇ·/»SÄm²dÆDz%·Œ·ÝwáI° Ù [ µôµµµµµµµµµµôµµµµµµµµµµµôµµ ¢ øûÁµ_Pµ›á ¾ ºZÈDCA·2¹ Ê ·ýÞÄ´¹%· µµµôµµµµµµµµµµôµµµµµµµµµµµôµµ ¢ ûûÁµ_PµˆûÁµ› ÀÓÆÇ° Ê °Á¹ÔÜ°Á²¦²%·2¸šÄ Ù2 °ÁºCÄ Ê °Á¹µµµôµµµµµµµµµµôµµµµµµµµµµµôµµ ¢ ü: š ›


ÀÓÆÇ° Ê °® ÊZ Æ ›œ ° Ê ·â+ºZ·Œ²% ÄÄ=ÆDzÇÄ œ Ó2¹ Ê · % Ö % À µôµµµµµµµµµµµôµµ NùPµ_Âi·šº •–¾= Àn“–’«º9·"Ãz¸Zº Ä•˜ºDºDÅX·šº Á”Œ»®åCº šÊ Ä Ê ·Ã?°Á²Ë±+²M`´ÆÇ°Áº µôµµµµµµµµµµôµµµµµµµµµµµôµµ …ZµûÁµ¢â+¹ Ù Ä´¸š°ÁºCÄ´Õ&·Œº¿Æ%° µµµµôµµµµµµµµµµôµµµµµµµµµµµôµµ müZµûÁµ_®Sºn>´¸ ¹¦· Ê °µ·ŒÕ&Ã?° Ê ·±+²%° Ù ·2¹¦¹ÇÄmÕ·2ºNÆ%° ÀÓÆÇ° Ê °¿ÚmýÜÄm¹%· µµµµôµµ ZµûÁµ›ÑkÄm¸ šÊ Ä´È8Ém° Ê °&ÀÓÆÇ° Ê °Uµµµµµôµµµµµµµµµµôµµµµµµµµµµµôµµ úZµ¢ž;Ÿ˜ €¡7¢£S¤ : ›œûÁµ›Zµû ÖwºNÆÇ·2²%ÄmÈ8É´° Ê ·ÔÜ°Áº:åC ¾ ²%ÄmÈ8Ém° µµµµµµµµôµµµµµµµµµµµôµµÁø·Œ°Á² Ä Ê ·±·2²dÆ ¾ ²¦ÍCÄmÈ2Ém° µµµµµµµµµµôµµµµµµµµµµµôµµ PûûÁµ›Zµ¢¥§¦B¨J©«ªm¬M­€¥;ª®¨G¯S°4¬S±—µµµµôµµµµµµµµµµôµµµµµµµµµµµôµµ ¢ûÁµ›Zµ_ûÁµˆ …·2°Á² Ä Ê °á ¾ º ÙŒ °ÁºCÄ´¸ Ê · ö ·2ºP¹ šÊ Ä Ê ·‘µµµµµµµµôµµµµµµµµµµµôµµ% Ö % À µµôµµµµµµµµµµôµµµµµµµµµµôµµµµµµµµµµµôµµ ÁùûÁµ³µ´VD·J¸=¹«’«º »–Œ²¼ ½y·¥’”“ ’ ¾=’¡¿«¸ZÀ» ÁPµû ®¼åCº šÊ Ä Ê ·ôÃ]°m²Ë±c²œ`mÆÇ°mºfµµµµµôµµµµµµµµµµôµµµµµµµµµµµôµµGPµ¢ ÀÓÆÇ° Ê °® ÊZ Æ ›œ ° Ê ·â+ºZ·Œ²% ĵµôµµµµµµµµµµôµµµµµµµµµµµôµµ¿úZµû ÒË·2¹ ¾ ¸›ÆÇÄ Ê °Á¹¼±+²%·Œ¸ Õ ºZÄm²%·Œ¹ µµµôµµµµµµµµµµôµµµµµµµµµµµôµµ:ûâq³Ð· Æ%° Ê °ÀÓŒÆ%° Ê °· Ê °ÔÜ°ÁºBA ¾ ºNÆÇ° Ê ·“ýÞÄ´¹%·ºCÄLâ+ºZ·2²¦Â Ä£â+¸›·ŒÆDzœLÁº ›Ù ÄZµûÁµû°´Æ÷Äm¸¼µµµµµµµµµµôµµµµµµµµµµôµµµµµµµµµµµôµµ:ûµû ÀÓŒÆ%° Ê °&® ÊZ Æ œ ° Ê ·â+ºZ·2²¦Â Ä*µµµµµµµµôµµµµµµµµµµµôµµ úZµ¢µ¢ ÀÓŒÆ%° Ê °® ÊZ Æ ›œ ° Ê ·£â+ºZ·Œ²% ĨĴÆDz%Ä œ Ó2¹ Ê · % Ö % À Ù °mÕ ±+¹%· ¾ZÊ °ÁÃ?°´ÝZµ¢ÆÇ·Œº Ù2 Äm¸—µµµµµµµµµôµµµµµµµµµµôµµµµµµµµµµµôµµúmøZµ¢ µ_Ê Äm¹±+²%°mÃZ² · Ê Ä Ê ·2¹ ®S±·®Sâ Ù °ÁÕ ° Ä ¾ Õ&·Œº¿Æ%° Ê Ä Ù Ä Ê · ÄÒ¼·Œ¸ÅÄmÈ2Ém°Äm²¦Í Lmº šÙ Ä µµµµµµµôµµµµµµµµµµôµµµµµµµµµµµôµµ ú ¢ÙZµ_ â+¹¦Æ ¾ZÊ ° Ê °&À· Ù Ämº ¹¦Õ&° Ê ·ÒË·8ÄmÈ2Ém° Ê ·âc¸ Õ ºCÄ´È8Ém°Öwº¿Æ%·2²¦ºCÄ Ê ·¨/ÄmºNÆ÷Ä´Æ%°Á¹sµµúmù


ž;Ÿ˜ €¡7¢£S¤Aœ:


ÑkÄm¸›°Á²%·Œ¹s· Ã?·2² Õ&·ŒºNÆ÷Ä ¹ Ê ·ôÃ]°ÁºNÆ%°Á¹ Ê ·ô·2Í ¾ ¸ È2Ém°·‰³ ¾ ¹ÇÉm° Ê ·Äm¸›Â ¾ ºZ¹ÞÆ ` ¹ ׈ØMÙ µ&µûÁµ¢â+ºZ·Œ²% Äm¹L·2¸š·ÆDzœLÁº šÙ Äm¹|85·ŒÕ ÎCÄm²dÆDz%·Œ·¥< Ê °Á¹¹ ¹¦ÆÇ·ŒÕ Ä´¹Õ°Á¸›· Ù2¾ ¸ÅÄm²¦·2¹·Œ¹¦Æ ¾PÊ Ä Ê °Á¹ZµûÓ §¬ª¢ £¥¤ Ô ¢ÖÕ ¤ è ¢¡¬ûÁµû ±+²%°mÃZ² · Ê Ä Ê ·2¹s³ Ø ¹ šÙ Ä´¹ Ê ·Äm¸šÂ ¾ ºZ¹ËÄm¸ Ù °$` ¹S׈؜Ùuµéµµµµôµµµµµµµµµµµôµµ°ÁÍ:Æ šÊ Äm¹ Ù °ÁÕ ÊZ ³Ð·Œ²%·2ºNÆ%·2¹ËÕ&ÓÆÇ° Ê °Á¹s· Ù °mºBA ¾ ºNÆÇ°Á¹ Ê ·ôÍCÄm¹¦·mµqµµµµµµµµµôµµÑkÄm¸›°Á²%·Œ¹ Ê ·Ä´åCº ›Ê Ä Ê ·‰Ã?°Á²ËÃZ²œ`mÆÇ°Áº Ù Äm¸ ÙŒ¾ ¸ÅÄ Ê °Á¹Þ·ô· Ã?·2² Õ&·ŒºNÆ÷Ä ¹ þ Ä ¢ üÁù ‰ ·“ûZµ¢· Ê ·2¹ œA °LÄmÍZ¹%°m¸ ¾ Æ%°s85·ŒÕÚ[$bNÚ´Õ°Á¸\


% ° ¾ 㣷 ½ P Ý÷ûô° ¾ ø


ß £àž á@âäã7åäá@â7æå ß â&žG


â+¹¦Æ%² ¾ Æ ¾ ²ÇÄ Ê °Á¹ Ù °ÁÕ&Ã?°Á¹dÆÇ°Á¹Ë·ŒÆÇÄmºZ° þ ·ŒÆ÷Ä´ºZ°Á¸·Ü>m ¾ Ä:µµôµµµµµµµµµµµôµµ ¢ûÁµûÔ ›Ù ¸š° Ê ·ýÜ°m²%º:Ýw»SÄmÍ?·2²sÃCÄ´²ÇÄ Ê ·ŒÆ%·2²¦Õ ºCÄmÈ8É´° Ê Ä&Ä=åCº šÊ Ä Ê ·‰Ã?°Á²sÃZ²M`´ÆÇ°Áºoµaµµôµµ û ¢ûÁµ¢â+¹ ½¿¾ ·ŒÕ Ä % Ö % ÀñÃCÄ´²ÇÄ ¾ Õ ¹ ¹¦Æ%·2Õ&Ä ÊP ›œA šÊZ ›Ê °s·2Õõ85Ä< ÊZ¾ Äm¹$·]85Í¡


ùß £àž á@âäã7åðö£S÷ÍŸ˜¢â&žG: šÑkÄm¸›°Á²%·Œ¹ Ê · Ä=åCº šÊ Ä Ê ··2¸š·ÆDzœLÁº šÙ Ä Ù Äm¸ Ù2¾ ¸šÄ Ê °Á¹ Ù °mÕé°ÕÓŒÆ%° Ê ° % Ö % À ÃZÄm²ÇÄZµˆ¹¦Æ%·2Õ&Äm¹ÔÞ».NB8 ÔÞ».Oe


â+¹¦Æ%² ¾ Æ ¾ ²ÇÄ&À°Á¸›· ÙŒ¾ ¸ÅÄm² Ê ° À·ŒÆ÷Ä´ºZ°Á¸ µµµµµµµµôµµµµµµµµµµµôµµ û6ø£®µâ+¹¦Æ%² ¾ Æ ¾ ²ÇÄ&À°Á¸›· ÙŒ¾ ¸ÅÄm² Ê °Í¼ãV8dûJ< Ê °âqÆ ¸V/‰ÄmºNÆÇÄ´ÆÇ° µµµµµµµµµµµôµµ û6ø®µúâ+¹¦Æ%² ¾ Æ ¾ ²ÇÄ&À°Á¸›· ÙŒ¾ ¸ÅÄm² Ê °Í¼ãV8dûJ< Ê °9/‰Ä´º¿ÆÇÄ´ÆÇ°&±+²%· Ù2¾ ²¦¹%°Á² Ê °&â+¹¦Æ ¸šÍ?·2ºZ° µôµµ û6ø®µùâ+¹¦Æ%² ¾ Æ ¾ ²ÇÄ&À°Á¸›· ÙŒ¾ ¸ÅÄm² Ê °Í¼ãV8 ¢ < Ê °âqÆ ¸V/‰ÄmºNÆÇÄ´ÆÇ° µµµµµµµµµµµôµµ û6øNú®µüß £àž á@âäã7åðö£S÷ÍŸ˜¢â&žš: › š¾ Æ ¾ ²ÇÄ&À°Á¸›· ÙŒ¾ ¸ÅÄm² Ê °Í¼ãV8 ¢ < Ê °9/‰Ä´º¿ÆÇÄ´ÆÇ°&±+²%· Ù2¾ ²¦¹%°Á² Ê °&â+¹¦Æ ¸šÍ?·2ºZ° µôµµ û6øÁù®µû6ø‰â+¹¦Æ%²¾ Æ ¾ ²ÇÄ&À°Á¸›· ÙŒ¾ ¸ÅÄm² Ê °Í¼ãV8< Ê °µò Ù2 ›Ê °µ/ ? ºNÆ ›Ù ° µµµµµµµµµµôµµ ûÁû6ø®µûÁûËâ+¹¦Æ%²®µû ¢ â+¹¦Æ%² ¾ Æ ¾ ²ÇÄ&À°Á¸›· ÙŒ¾ ¸ÅÄm² Ê °µ/ÄmºNÆ÷Ä´Æ%° ±+²¦· Ù2¾ ²%¹%°m² Ê ° â+¹¦Æ ¸›Í]·ŒºZ° µµµµµµôµµ ûÁûÁû


úÿ¡ Dÿ ¢ ó2藍$ò© ì殮¨§©© óÜîï,藍§LíLìí£îï¹ Ù °ÁÕ&Ã?°Á¹dÆÇ°Á¹k°Á²% ? º šÙ °Á¹kÍCÄm¹%·2Ä Ê °Á¹Ü¹%°ÁÕ·2ºNÆÇ··2Õ ¾ Õ&Ä·Œ¹¦ÆDz ¾ Æ ¾ ²ÇÄ Ê ·]>´ÆÇ°ÁÕ°Á¹ Ê · Ù Äm²%Í?°ÁºZ°%›Ê ²%°m£U2º °¹ÇÉm° Ù ÎCÄ´Õ Ä Ê °Á¹ Ê ·ôÎ šÊ ²¦° Ù Äm²%Í?°ÁºZ·ÆÇ°Á¹Œµ+ÛÕ&ÄÂÁ²ÇÄ´º Ê · ½¿¾ ÄmºNÆ ›Ê Ä Ê · Ê · Ù °ÁÕ&Ã?°Á¹dÆÇ°Á¹·‰Îæ ¢Öøwù?ª çéè «û ©ª « £ çýüfþ «? º ›Ù °Á¹ ÊZ ³Ð·Œ²%·Œº¿Æ%·2¹“¹%·£°m²  ºCÄmÕ Ã?·2¸šÄ¨Ä ÊZ È8Ém° Ê ·£° ¾ ÆDz¦°Á¹*·2¸›·2Õ·2ºNÆÇ°m¹ þcÙ °ÁÕ°° : £UŒº ° þ º Ý°Á²¦Â°° ¾ ·2º °m³Ð²¦· þ à Ù Ä Ê · Ä Ê ·2¹dÆÇ·Œ¹/Î šÊ ²%° Ù Äm²¦Í]°ÁºP·ŒÆÇ°m¹2µs®S¹ÃZ²%°mÃZ² · Ê Ä Ê ·2¹³ Ø ¹ ›Ù Äm¹Ë· ½¿¾ZØ Õ ÝÆ%²%°Á£UŒºÄm¹ Ê ·2¹dÆÇ·2¹ Ù °mÕ&Ã?°Á¹¦Æ%°Á¹¹ÇÉ´°—Ä=ÆDz Í ¾ZØ›Ê Äm¹Ä Ù ·Œ²¦Æ%°Á¹j>=ÆÇ°ÁÕ°Á¹*° ¾ ÂÁ² ¾ Ã?°Á¹ Ê ·W>´ÆÇ°ÁÕ°Á¹*ÃP²%·2¹¦·2ºNÆÇ·Œ¹ÙÙ2¾ ¸ÅÄm¹ þkÙ ÎZÄmÕ Ä Ê °Á¹ Ê · ¿«‘B• È0’4•˜Ž–ĸ=’ Ž Àn¾ µ‘ÔÞÄ Ê ÄFÂm² ¾ Ã?°F³ ¾ º Ù2 °ÁºCÄm¸Þ¹¦°m³Ð²%·²%·2ÄmÈDCA·2¹ºCÄ´¹Õ°Á¸›ÓÕ ›Ù Äm¹ Ù Äm²ÇÄ Ù ÆÇ·Œ² Ø ¹¦Æ ›Ù Äm¹ þZ º Ê ·2Ã?·2º Ê ·2ºNÆÇ· Ê °Æ÷ÄmÕ&ÄmºZÎP°· Ê Ä Ù °ÁÕ&ÃP¸š· : ›Ê Ä Ê · Ê ÄÕ°Á¸šÓ Ù2¾ ¸šÄPµ½¿¾Zع Àn¾ZÄ£’¤«¸Zº ¹%Ém° Ù °mÕ&Ã?°Á¹¦Æ%°Á¹ Ù2¾ A%Äm¹&Õ&°m¸šÓ ÙŒ¾ ¸ÅÄ´¹*ÆHU2Õ ¾ Õ ÂÁ² ¾ Ã?° Î ›Ê ²%° : ¸šÄF¸ ÂNÄ Ê °—Ä ¾ Õ%Ê · Ù Äm²¦Í]°mºZ°Ë¹ÇÄ´Æ ¾ ²ÇÄ Ê ° þ Ã]°Á¹¦¹ ¾Z º Ê °Ë°ËÂÁ² ¾ Ã]°s³ ¾ º ÙŒ °ÁºZÄm¸ ÂS³ µ¥b£>˺P°Á¹ J¸ ¸Zº þ °Ë° : £UŒº °>´Æ%°ÁÕ°¾ ÍZ¹dÆ Æ ¾ZØšÊ ° Ã]·Œ¸š°—·2º °m³Ð²¦· þ ²%·2ÃP²%·2¹¦·2ºNÆ÷Ä´º Ê °z° ÂÁ² ¾ Ã]° ³ ¾ º Ù2 °ÁºCÄm¸  µ % ¹£Äm¸ Ù °š` ¹“·¨°Á¹Ó¨¹` ¹/¹ÇÉm° Ù °mÕ&Ã?°Á¹¦Æ%°Á¹ôÄmºn>´¸š°ÁÂÁ°m¹ þ Ã?° ¹‰°° P £U2º °£·“°·Œº °m³Ð²%·Ã?·2²¦Æ%·2º Ù ·2Õ àLÕ&·Œ¹%Õ&Ä ³5ÄmÕ Ø ¸ ÄÆÄÆ÷ÄmÍ?·2¸šÄÃ]·Œ² ` ÊZ ›Ù Ä þ ÄmÃZ²¦·2¹%·ŒºNÆ÷Ämº Ê °FÃP²%°ÁÃZ² · Ê Ä Ê ·Œ¹ ½¿¾ZØ Õ šÙ Äm¹¹ Õ ¸šÄm²%·Œ¹jEûDK µ % ¹ ÀnŽ ¥À$¥’«ºÊÙ °ÁÕ&Ã?°Á¹dÆÇ°Á¹¼°Á²%ÂÁÄmºZ°Á¹¦¹ ¾ ¸³ ¾ ²ÇÄ Ê °Á¹ þ?½¿¾ ·Ã?°Á¹%¹ ¾ ·2ÕÂÁ² ¾ Ã]°m¹¼³ ¾ º Ù2 °mºCÄ ¹¼¹%·ŒÕ&·Œ¸šÎCÄ´ºPÆÇ·Œ¹SÄm°m¹ Ê °Á¹¹%Ém°Ù °š` ¹n·‰Æ ` ¹2µ0®SÃZ²¦·2¹%·ŒºNÆ÷ÄmÕ ³=`Á²¦Õ ¾ ¸šÄ*ÂÁ·2²%Äm¸ ÂS³iÆ! "#M þ °Áº Ê ·ÒgÓ ¾ Õ ÂÁ² ¾ Ã?°Äm¸ ½¿¾Z ¸ÿµÄm¸û


¾ Æ ¾ ²ÇÄ*¹ Õ ¸ÅÄ´²nà Ê Ä9>´Â ¾ Ä þ ° ? ºZ ¾ ¸›° Ê ·87:9=?A@ Ê Ä*¸ ÂÁÄmÈ8Ém°»ËÝ % Ýw»gÄ ¾ Õ·2ºNÆÇÄ*ÃCÄm²ÇÄÆMU2ÕxÄ“·Œ¹¦Æ%²ÂÁÄmÈ8Ém°*ÒsÝ % Ýw» E¢ Kÿõ7:9AB,@sºCĸ ¾ ²%ÄûÁµ›ûmõcâc¹dÆDz ¾ Æ ¾ ²%Ä Ê °Á¹ Ù °ÁÕÃ]°m¹¦ÆÇ°m¹s·ŒÆ÷Ä´ºZ° þ ·ŒÆÇÄmºZ°Á¸a·>´Â ¾ ÄPµáÊ ·ŒÕ ¹%·2² Ù ¸šÄm¹%¹ å Ù Ä Ê °Á¹·2Õ ÆDzœU2¹0Âm² ¾ Ã?°Á¹ þmÊ ·ÞÄ Ù °Á² Ê ° Ù °mÕß°SÂÁ²ÇÄ ¾Ê ·Ü¹ ¾ ÍZ¹dÆ Æ ¾Z È2Ém° Ê °â+¸š·Œ¹0Ã?°Ù ÎCÄmÕ&Ä Ê ÄºP°ÁÕ&·Œº Ù ¸šÄ´Æ ¾ ²ÇĹ ¾ ÍZ¹dÆ Æ ¾ Æ œ Ä Ê ÄÖ\Û±]®¼ÔxE_BK;8IHJn°4¬S±J#K°ILQ¦MJ#KªONJPLQ¦MJ"¦.QSR-¨š±H¬SÄþ °“ºZ°ÁÕ· Ê · ¾ Õ >m¸ Ù °A°Á¸aÓ Ê Ä Ê ° Ê Ä“¹¦·2 ¾P ºNÆÇ·ôÕ&ÄmºZ· ²ÇÄPõKAJ«­UT-©©«ªVLQ¬M­3¥!Wn¬X8Lm¯S°Z±Y@


¹£Äm¸ Ù °š` ¹¹ Õ&ÃZ¸›·2¹&¹ÇÉm° Ù °ÁºZÎZ· Ù2 šÊ °Á¹£Ã]·Œ¸ÅÄ ºP°ÁÕ&·Œº Ù ¸šÄ´Æ ¾ ²ÇÄ ²%Ä ÊZ šÙ °m³ ¾ º ÙŒ °ÁºZÄ ¹ þÞ½¿¾ ·¨Æ÷ÄmÕÝ%œ Ä Ê ÄÃ]·Œ¸ÅÄ“Ö\ÛS±?®¼ÔSµo±°m²· ·ŒÕ&ÃP¸š°Zõ6>´¸ Ù °A°Á¸oÃP²%°ÁÃ Ø ¸ ›Ù ° þ >´¸ Ù °A°Á¸ ¹%°ÁÍ ¾ Æ Ø ¸ šÙ °·>m¸ Ù °A°Á¸Í?Ó2Õ.ÓÄmÃZ²%°Âm² ¾ Ã?°‰³ ¾ º Ù2 °ÁºCÄm¸¿Ý % »‘Ã?° Ê ·Þ³Ð°m²%Õ&Äm²q¸ ÂNÄmÈC:·Œ¹ Ê ·ËÎ ›Ê ²%°ÁÂU2º ° þÁ½¿¾ ·¼Ä ¾ Õ·2ºNÆ÷Ä´ÕfÄm¹q³Ð°Á²¦È8Äm¹%ÙŒ¾ ¸ÅÄm²¦·2¹c· Ù °ÁºZ¹¦· ½[Z ·2ºNÆ%·2Õ·2ºNÆÇ·Ä´³Ð·Æ÷ÄmÕUÄm¹nÃZ²%°mÃZ² · Ê Ä Ê ·2¹n³ Ø ¹ ›Ù Äm¹k²%·Œ¸ÅÄ ÙŒ °ÁºCÄ Ê Äm¹ þ¿Ù °ÁÕ&°º¿Æ%·2²¦Õ&°Á¸›·$â&%('Dá]Ÿ ß ¤*),+f£.-9ᘢ&¤6ãŸ0/21ܤ¾ ¸›å °h¦Bªµ ¹¾ Õ·2²ÇÄ´²‰·2¹¦ÆÇÄ Ù Ä Ê · Ä Ê · Ù Äm²¦Í]°ÁºP°Á¹ þ ¹%·Œº Ê ° ½¿¾ ·°LÕ&·ŒºZ°Á²ôºGíZÕ·2²%°¹%·Œ²H> Ê Ä Ê °ÃCÄm²%Ä°­äÊ · Ù Äm²¦Í]°ÁºP°¸ ÂÁÄ Ê °Äm°ÂÁ² ¾ Ã]°*Î šÊ ²¦° : ¸ÅÄPµ0Û¹ÇÄ´²Þ·2¹dÆ÷Ä*º ¾ Õ·2²ÇÄ´È8Ém°ÃCÄ´²ÇÄ º ÊZ šÙ Äm²ÞÄ>=ÆÇ°ÁÕ°È8É´° Ê °&Âm² ¾ Ã?°“Î šÊ ²¦° P ¸ÅÄ· Ê ·ô° ¾ ÆDz%°m¹s¹ ¾ ÍZ¹dÆ Æ ¾Z º¿Æ%·2¹ þ?Ù °ÁÕ°ÃZ²%·å °ZµÃ?°Á¹Ø ¸ šÙ °Zµ ºZ·Œ°ÁÃ?·2ºNÆ· œ: ›Ê °à“ÂÁ²%Ämº Ê ·Ã]°m¸ÅÄm² šÊ Ä Ê · Ê Ä&¸ ÂNÄ´È8Ém° % Ý\» þ °Á¹Äm¸ Ù °$` ¹sÄmÃZ²¦·2¹¦·2ºNÆ÷ÄmÕÂÁ²%Ämº Ê ·¹%°m¸ ¾ Í ¸ ÝöÄ Ê ··2Õý>´Â ¾ Ä£·¹%°Á¸œ ·Œº¿Æ%·2¹Ã]°m¸ÅÄm²¦·2¹2µ % ¹Äm¸ Ù °š` ¹Õ&·Æ Ø ¸ šÙ ° þ ·ŒÆ Ø ¸ ›Ù ° þ ÃZ²%°ÁÃ Ø ¸ ›Ù °· ¹%°ÁÃZ²¦°ÁÃ Ø ¸ šÙ °Ê¹ Ù2Øœ · ¹s·2Õ >´Â ¾ ÄPµnÔÜ°ÁºNÆ ¾PÊ ° þ ° Ä ¾ Õ&·ŒºNÆÇ° Ê Ä Ù Ä Ê · Ä Ù Ä´²%Í«LÁº šÙ Ä ÊZ Õ º ¾Z Ĺ%Ém°Æ%°mÆ÷Ä´¸šÕ·2ºNÆÇ·/Õ¾ Í ¸ ›Ê Ä Ê ··2ÕÚ>m ¾ Ä:µÖw¹dÆÇ°Ä Ù °mº¿Æ%· Ù ·Ã?°Á² ½A¾ ·“ÄÃCÄm²¦Æ%·“ÄmÃ?°Á¸ÅÄm² Ê ÄÕ°Á¸šÓ Ù2¾ ¸šÄ"85ÂÁ² ¾ Ã?°£Î šÊ ²¦°´Ý¹¦°Á¸Äm²%Í?°ÁºZ·ÆÇ°Gm ¾ Ä£=_^ àBcbd=_? eâqÆ Ø ¸ šÙ ° bAfg=_h `¡7,7";>=i7 e±+²%°ÁÃ Ø ¸ ›Ù ° Bcbd=j `¡7kj=l; eÖw¹%°mÃZ²%°ÁÃ Ø ¸ ›Ù ° fcjd=_h àfcbd=GB eý ¾ Æ Ø ¸ šÙ ° 7A7kbd=b àf,fg=G^ fg=_hÖw¹%°mÍ ¾ Æ Ø ¸ ›Ù ° 7"9cbd=_B `¡7:9,fg=G9 7"9g=_9¯¥¬_F#ÝwÍ ¾ Æ Ø ¸ šÙ ° B,Bg=? àf,fg=_? j


¹sÄm¸ Ù °š` ¹n¹ÇÉm° Ù °ÁÕ&Ã?°Á¹dÆÇ°Á¹Þ°m²% ? º šÙ °m¹ÜÕ ¾Z ÆÇ° œ ·2²¦¹H>´Æ%· ¹ þ Ã?° Ê ·Œº Ê °¹¦·2²ÞÆDz%ÄmºZ¹d³Ð°Á²%Õ&Ä Ê °Á¹Ü·2Õ%Äm¹¦·Æ%° Ê Ä´¹ Äm¹ Ê ·ŒÕ Ä ¹ Ù ¸ÅÄ´¹%¹%·Œ¹ Ê · Ù °ÁÕÃ?°Á¹¦Æ%°Á¹Äm¸ ³Z>´Æ ›Ù °Á¹Œµó…° Ê °Á¹&°m¹Äm¸ Ù °š` ¹¸ ¹¦ÆÇÄ Ê °Á¹ºZĽ¿¾’«¾ ½y·¥ÀnŽ¾Z Æ%°ÆÇ·2ÕÃ?° þ °LÕ&·Æ÷ÄmºZ°m¸0³Ð° ÃZ²¦° ÊP¾ZÌ2 ›Ê °LÃ]·Œ¸ÅÄ ½¿¾ · Õ Ä Ê Ä£Õ&Ä Ê · ²ÇÄPµ*áI° qÊ · œA ›Ê °Ä±°m²ÕÕ&·Æ÷ÄmºP°Á¸¿Ó ºd~IÄmÕk> œ ·2¸A·ÞÄm¸Æ÷ÄmÕ·2ºNÆ%·kÆM` : ›Ù ° þ Ä ºZÂm·2¹¦ÆÇÉm° Ê ·ÜÃ?· ½¿¾ ·2ºZÄm¹ ½¿¾ ÄmºNÆ ›Ê Ä Ê ·Œ¹0Ã?° Ê ·%Ä ¾ ¹ÇÄ´² Ù ·ŒÂ ¾ · ²ÇÄ&·*ÂÁ²ÇÄ´º Ê ·2¹ ½A¾ ÄmºNÆ šÊ Ä Ê ·2¹S¸š· œ ÄmÕà&Õ&°Á²dÆÇ·´µ % ·2º œ ·ŒºZ·2ºZÄmÕ&·ŒºNÆÇ°LÃ]°m²SÕ·ŒÆ÷Ä´ºZ°Á¸Ù$â&%('Dá]Ÿ ß ¤*),+f£.-9ᘢ&¤6ãŸ0/21ܤÂÁ²ÇÄ´º Ê ·²¦·2¸›· œ…? º ÙŒ Ä Ù °ÁÕ·2² ÙŒ Äm¸ þ ºZ°·Œº¿ÆÇÄmºNÆÇ° þ ° ·ŒÆÇÄmºZ°Á¸…Ó*°j>m¸ Ù °:°Á¸ Ê ·ÄmÍ?·2¸ÅÄûÁµû*ÄmÃZ²¦·2¹¦·2ºNÆ÷ÄmÕ°m² ÕÃ]°Á²dÆ ? º Ù2 Ä*· Ù °Áº@LÁÕ ›Ù ÄPµÜ®¡¹%·ŒÂ ¾Z ²¹¦·2²ÇÉ´°ÄmÃZ²¦·2¹¦·2ºNÆ÷Ä Ê Äm¹‰Äm¸›Â ¾ Õ&Äm¹ Ù Äm²%Ä Ù Æ%·2² Ø ¹¦Æ šÙ Ä´¹ Ê °Õ&ÄÕ·ŒÆÇÄmºZ°Á¸)8 ÔÞ».N % »]m¸ Ù °:°m¸ Ê Ä‰Õ&Ä Ê · ²ÇÄdm›µ…®¼Ý·Œ¹¦ÆÇ·sÃP²%°¾ Äm¸šÕ·2º:ÆÇ· þ °‰Õ&·Æ÷ÄmºZ°m¸ZÓsÃZ²%·ŒÃCÄm²%Ä Ê °ôÃ]·Œ¸ÅÄ/Î ›Ê ²%°mÂÁ·2ºCÄ´È8Ém° Ù Ä´Æ÷Ä´¸ Ø Æ šÙ Ä Ê ·ËÕ°ÁºR` : šÊ ° Ê · Ù Äm²%Í?°ÁºZ°Æ85â ½ µ:ûÁµ›û¥< þ ²¦·8ÄmÈ2Ém° Ù °mº ÊZ¾ZÌŒ šÊ ĉà/Ä´¸›Æ÷ļÃZ²%·Œ¹%¹%Ém°k8 ¢ øÁøHÝIÁøÁøÄ´ÆÇÕj


ÀnŽ–’«¾ Ë·Æ÷ÄmºZ°m¸qÓ“°3>m¸ Ù °A°Á¸ ¾ Æ ¸ šÌ Ä Ê °·ŒÕ¥Í]·ŒÍ šÊ Äm¹Äm¸ Ù °$`Á¸ šÙ Äm¹S·“Ã?° Ê ·“¹¦·2²ôÃZ²%° ÊZ¾ZÌŒ šÊ °LÃ?·2¸šÄ£³Ð·Œ²dÝ%n c_rjçZO o c( €E‚ƒ€I„†…xØl‡`}| j n r9N n r9O o r p j n¡o O 8dûÁµ¢ m ¾ Ä··Æ÷ÄmºZ°m¸…³Ð°Á²¦Õ Ä ¾ Õ&Ä&Õ ¹dÆ ¾ ²%Ä&Ä Ì ·2°´ÆDzM`mà šÙ ÄPµ %·Æ÷ÄmºZ°m¸Ä´º¾ ²%°z8а ¾ >m¸ Ù °:°m¸]Ä´ÍZ¹%°Á¸ ¾ ÆÇ°


· œ: ›Ê ° àÃ?· ½¿¾ ·ŒºCÄ ÊZ ³Ð·Œ²%·ŒºZÈ8Ä Ê · ·2¸š·ÆDz¦°ÁºZ·2ÂÁÄ´Æ œ: ›Ê Ä Ê ·“·Œº¿Æ%²%·£°¨·Œº °m³Ð²%· ·°¨Î ›Ê ²%°ÁÂU2º ° þö` ¹s³Ð°Á²¦Õ ÄmÕ.¸ ÂNÄ´ÈDCA·2¹ Ê ·*Î ›Ê ²%°m£U2º °³Ð²%Ä Ù Ä´¹ þ Ä´ÃZ²%·Œ¹%·2ºNÆÇÄmº Ê °LÍCÄ ° Ã?°ÁºNÆÇ° Ê ··2Í ¾ ¸ È2Ém° ·°Á¹¼Æ¹Ü¹ ÕÃZ¸›·2¹2µ Õ&ÄõqÑkÄm¸š°m²%·2¹s· Ã]·Œ² Õ·2ºNÆÇÄ ¹ Ê ·ôÃ?°ÁºNÆÇ°Á¹ Ê ·ô·ŒÍ ¾ ¸ È8Ém°·‰³ ¾ ¹%Ém° Ê ·Äm¸šÂ ¾ ºZ¹ÞÆ ` ¹e×^ØœÙuµ0ÄmÍ?·2¸šÄûÁµ¢›Ê °Á¹ËÄ£ûÄ´ÆÇÕµ×]\=Ù0ÑkÄm¸›°Á²%·Œ¹s°ÁÍPƹSÆ ` ¹ Ê ·ÍCÄ † °&Ã]·Œ¹%°£Õ°Á¸š· Ù2¾ ¸šÄm²Ë¹ÇÉm° Ù °ÁÕÃ]°Á¹dÆÇ°Á¹ œ °Á¸m>´ÆÇ· ¹·²%·Œ¹%Ã?°ÁºZ¹M> œ · ¹Ã?°Á²¼Õ ¾Z ÆÇ°Á¹%$â&%('Dá]Ÿ ß ¤*),+f£.-9ᘢ&¤6ãŸ0/21ܤTY\WkY\K3(45364z¹Æ ` ¹o¹%Ém°ºP°Á²%Õ&Äm¸šÕ·2ºNÆ%· Ù ÎCÄmÕ&Ä Ê °Á¹ Ê ·kÕ·2² Ù ÄmÃ:Æ÷ÄmºZ°m¹2µ % Ù °ÁÕÃ?°Á¹¦Æ%°¼Õ&Ä ¹o¹ Õ&ÃZ¸›·2¹ Ê ·Œ¹¦ÆÇÄ%¾ ºPÈ8Ém° ½¿¾ZØ Õ ›Ù ÄôÓS°Õ&·Æ÷ÄmºZ°´Æ °mÇ° ¾ Õ·ŒÆ ÇÕ&·Œ² Ù ÄmÃPÆ÷Ä´ºZ°z8ÿÔÞ»+NãP»7< ½¿¾ · þ:Ù °ÁÕ°°Á¹n° ¾ Æ%²%°Á¹kÆ ` ¹³·ôÍCÄ † °Ã]·Œ¹%°Õ&°m¸š· ÙŒ¾ ¸ÅÄ´² þ Ã?°Á¹¦¹ ¾Z ° Ê °Á²Þ³Ð°Á²dÆÇ·‰· Ê ·Œ¹ÇÄmÂÁ²%Ä Ê > œ ·Œ¸ÿµÊ>´ÆÇ°mÕ&° Ê ··Œº °m³Ð²%·*ÓÕ Ä °Á²s·*Õ&Ä ¹¼Ã?°Á¸ÅÄm² šÌ > œ ·2¸ ½¿¾ ·*°>=ÆÇ°ÁÕ° Ê ·*° P £U2º °Zµ±°Á² ¹¦¹%° þ%°ÁÕ&Ã?°Á¹dÆÇ°Á¹ Ù °ÁºNÆÇ·Œº Ê °°Âm² ¾ Ã?°ÝdãP»f¹%Ém°W> Ù2 ›Ê °Á¹/Õ&Ä ¹³Ð°Á²¦Æ%·2¹ ½¿¾ ·¹%· ¾ ¹ Ù °ÁÕÃ]°Á¹dÆÇ°Á¹ôÄ´ºn>m¸š°mÂÁ°Á¹Ù·° : ÂU2º °Zµ±°Á²‰· ·ŒÕ&ÃP¸š° þ ° Ø °ÁºFÔÞ».N÷ÔÞ».Oã ì Ó ¾ Õ º ¾PÙ ¸š·`måC¸›°£Õ Ä ¹³Ð°Á²dÆÇ· þo½¿¾ Ämº Ê °L²¦·8ÄmÂÁ·Ê°ÁÕ ¾ Õ >=ÆÇ°ÁÕ° Ê · Ù Äm²¦Í]°mºZ° þZ½¿¾ ·ô° Ø °ÁºÔÞ»+NÔÞ».O % ì µÙ¾Z٠Ĺ%°Á¸ ¾ Í ¸ šÊ Ä Ê ··2Õ >m ¾ Ä· ° ¾ ÆDz¦°Á¹¹¦°Á¸ œ ·2ºNÆÇ·Œ¹Ã]°Á¸šÄm²%·Œ¹ þ ¹%· Ù °ÁÕ&ÃZÄm²ÇÄ Ê °Á¹Ä´°Á¹*Äm¸ Ù °š` ¹ Ê ·Ã?°ÙŒ¾ ¸ÅÄ´²2µ+®x0Ä´Í]·Œ¸ÅÄ£ûÁµ¢ ÄmÃP²%·2¹¦·2ºNÆ÷Ä°Á¹¼Ã]°ÁºNÆ%°Á¹ Ê ··ŒÍ ¾ ¸ È8É´°·‰³ ¾ ¹%Ém° Ê °Á¹ËÆ ` ¹Õ·2¹¦Õ&°“Ã?·2¹%°&Õ&°m¸š· °Á¸±°ÁºNÆÇ° Ê ·â+Í ¾ ¸ È8É´°$× \=Ù ±…°ÁºNÆÇ° Ê ·á ¾ ¹ÇÉm°8I@#Ô6


úÊ · œA šÊ °£àÃZ²%·Œ¹%·ŒºZÈ8Ä Ê ·Æ ` ¹Ë·2Õ¹ ¾ Ä Ù °ÁÕ&Ã?°Á¹ È8É´°Zµ % ¾ ÆDz¦° · ·ŒÕ&ÃZ¸›° Ù °ÁºZÎZ· Ù2 šÊ ° Ê ·Æ °Á¸Ó¹%Ém°¹&Æ ` ¹ÆÇÄmÕ*Í?Ó2Õ_ÆHUŒÕ Âm²ÇÄmº Ê · ÕÃ?°Á²¦Æ ? º Ù2 ÄF·ŒÕ ¹ ¹dÆÇ·ŒÕ Äm¹&Í °m¸m`Á ›Ù °Á¹ þÜÙ °ÁÕ&°—° ÂÁ² ¾ Ã]°%¾ º Ù2 °mºCÄm¸ Ê °Ämº Õ&°> Ù2 šÊ ° Ù2 ¹dÆÇ· Ø ºCÄPµ&®xÃP²%°mÆ%· Ø ºZÄ·Œ¹¦ÆDz ¾ Æ ¾ ²ÇÄm¸ ½¿¾ ·2²%Ä´Æ ºCÄÓ² ›Ù ÄL·2Õ鲦·2¹ Ø›ÊZ¾ °Á¹³$â&%('Dá]Ÿ ß ¤*),+f£.-9ᘢ&¤6ãŸ0/21ܤ٠°ÁÕ&Ã?°Á¹dÆÇ°9=ÝuÕ&·Æ ¸Ý÷ûÝwÍ ¾ Æ%·2ºZ°´Æ °m¸ þmÙ °ÁºZ¹dÆ Æ ¾Z ºNÆ%· Ê °²%·ŒÃ ¾ ÂÁºZÄmºNÆÇ·‰¸ Ø›½¿¾Z šÊ ° Ê · Ê ·³Ð·2¹ÇÄ· Ã?·2¸ šÊ °°Ã?·2¸›°Á¹sÂNÄmÕ*ÍR>m¹¨EùBKÿµ›Ù ÄmÈ2Ém°Õ ¾Z ÆÇ° ÕÃ?°Á²¦ÆÇÄmºNÆÇ· Ê °Á¹ËÆ ` ¹sÓ¹%· ¾¨¾ ¹¦° ·2Õ.²¦·ŒåCºZÄm² Äm¹ Ê ·Ã?·ŒÆ%²M`Á¸›·2°ZµÜ±°Á²ÛÕ&ÄÄmÃZ¸œ °Á¹ Ê ·&¹¦·2 ¾ ²%ÄmºZÈ2Ä þ ° Ù °mÕ&Ã?°Á¹¦Æ%°L·ŒÆ÷Ä´ºZ°mÆ °Á¸qÓ&Ä ÊZ ›Ù2 °mºCÄ Ê °LÄm°35¨…±ï8Q5¨>m¹Ü ›½[Z ·Œ³Ð· ÆÇ° Ê ·Õ°mƺCÄ=Æ ¾ ²%Äm¸šÕ·2ºNÆÇ· ºZ° Ê °Á²¦° þ °·ŒÆÇÄmºZ°mÆ °ÁçÃZ²¦° ÊP¾ZÌ ¾ Õ ° Ê °Á² Ù Äm²%Ä Ù Ý±…·ŒÆDzœ`Á¸š·Œ°Gm¹2µÆ%·2²· ÙŒ ¹dÆÇ· Ø ºCÄ þZ½¿¾ ·‰³Ð°Á²¦Õ Ä´ÕxÃ?°ÁºNÆÇ·Œ¹ ÊZ ¹%¹ ¾ ¸›³Ð·ÆÇ°W8 Ý\ã¿ÝdãNÝà·ŒÍZ²ÇÄ Ê Äm¹‰Ã]°m²/²%· ÊZ¾ È8É´° Ù °ÁÕ Õ·2² Ù ÄmÃ:Æ÷ÄmºZ°m¹2µ®¹ ½¿¾ ·2²%Ä´Æ ºCÄm¹/¹%Ém° Ù ¸ÅÄ´¹%¹ å Ù Ä Ê Äm¹ Ù °ÁÕ&° ÊP¾ ²ÇÄm¹½¿¾¾ Õ°Á¸›·2¹*¹¦·£Ã]°Á¹¦¹ ¾ZØ ²%·ŒÕ Äm¸ÆÇ°¨° ¾ ÍZÄ † °¨ÆÇ·Œ°Á² Ê ·£·Œº °m³Ð²%·´µ ®¹ ½¿¾ ·Œ²ÇÄ´Æ ºCÄ´¹ ÊZ¾ ²%Äm¹ þcÙ °mÕ&° Äm¹°° Ù Ä´Í]·Œ¸š° · Ê Äm¹ ¾ ºZÎCÄm¹ þ ¹ÇÉ´° Õ·2ºZ°Á¹8~C· :Ø›œ · ¹ Ê ° ½A¾ ·¨Äm¹ ½¿¾ ·2²%Ä´Æ ºCÄm¹“Õ°Á¸š·Œ¹ þkÙ °ÁÕ° Ä´¹ Ê ÄÊÊ °m¹ Ù Äm¸š°Á¹ þ ²¦·2¹ ¹¦Æ º Ê °—à Ê ·Œ³Ð°Á²¦Õ Ä´È8Ém° Ê · œ: ›Ê ° à´¹Ã?°ÁºNÆÇ·Œ¹ ÊZ ¹%¹ ¾ ¸›³Ð·ÆÇ°Zµ¯±°Á²· ·ŒÕ&ÃZ¸›° þÃ?·2¸›··Ê · Ù ÄmÍ?·2¸›°Ã?° Ê ·&¹¦·2²*Ä´¸ ¹%Ä Ê °L° ¾ ·ŒºZ²%°m¸ÅÄ Ê °Ã?·2¸š°¹%·ŒÂ ¾Z º¿Æ%· ÃZ²¦° Ù ·2¹¦¹%°ZõÆDz%Ä´Æ÷Ä´Õ&·Œº¿Æ%° Ù °ÁÕ°åC°Ù ÄmÃPÆÇÄmºZ°Á¹ þ:½¿¾ · ½A¾ ·2ÍZ²%ÄmÕ Ä´¹ÜÃ?°ÁºNÆÇ·2¹ ÊZ ¹¦¹ ¾ ¸³Ð·ŒÆ%°*·/ÄmÃP¸ šÙ ÄmÈ8É´° Ê · ¾ ÕñÄmÂÁ·Œº¿Æ%·/° : šÊ ÄmºNÆ%· þA½A¾ ·Õ·2²Ù ·Ä´¹¼Ã?°ÁºNÆÇ·Œ¹ ÊZ ¹¦¹ ¾ ¸³Ð·ŒÆÇ°“·ŒÕ ¾ Õ&Ä“ºP° œ Ä Ù °Áº:åC ¾ ²%ÄmÈ8Ém°WEü…K µ²¦·2·2¹dÆ÷ÄmÍ?·2¸›·Ù ¸šÄ´Æ ¾ ²%ÄS°må ÙŒ Äm¸ Ê Ä/Ö\ÛS±?®¼Ô}ÃZÄm²ÇÄ/°Á¹qÆ ` ¹¹¦·2 ¾ ·Ä´¹qÕ&·Œ¹%Õ&Äm¹q²¦·2ÂÁ²%Äm¹q·2¹dÆ÷ÄmÍ?·2¸›· ÙŒ šÊ Äm¹®‘ºZ°mÕ&·ŒºÙ °$` ¹ þ6Ù °ÁÕg· :Ù ·2È8É´° Ê · ½¿¾ ·n°¼ºZ°ÁÕ· Ê °Äm¸ Ù ÄmºZ° Ù °Á²¦²%·Œ¹%Ã?°Áº Ê ·Œº¿Æ%·ÜÓcÕ&ÄmºNÆ šÊ ° þ ¹%·2 ¾Z šÊ °ÃCÄ´²ÇÄs°Á¹Äm¸°ÃP²%·Œå °r°ELQ¦BªµF°·2ºNÆÇÄmºNÆÇ° þ ºCĨºZ°mÕ&·Œº Ù ¸šÄ´Æ ¾ ²%Ä ¾ ¹ ¾ Äm¸ þ °ºP°ÁÕ&· Ê · ¾ Õ Æ °mņÓ Ê Ä Ê °Ã?·2¸š°Ê²%Ä ÊZ šÙ Äm¸oÄ´¸ ½¿¾Z ¸ Ù °Á²¦²%·2¹¦Ã]°mº Ê ·2ºNÆ%· þ ¹%·ŒÂ ¾Z šÊ ° Ê ÄÃCÄ´¸ÅÄ œ ²ÇÄ‘Xj¬S±GFlKS©«° KAJCµ


pG`cbnM:`qM:RkK¹ ÄmºNÆ÷Ä´Æ%°Á¹¹ÇÉm°¹%Ä ¹° ¾ Ó2¹¦Æ%·2²¦·2¹ Ê ·2² ›œ Ä Ê °m¹ Ê °T> Ù2 ›Ê ° @? ºNÆ ›Ù ° ·£ÄmÃP²%·2¹¦·2ºNÆ÷Ä´Õ ³=`Á²%Õ ¾ ¸ÅÄ%n r9N n r9O“ n•” ‰–“(— on r9NO| r9O n ‰ n r9O p˜n r9N on” ‰š“(—l“›r 8dûÁµ›G Ù2 ›Ê ° @? ºNÆ ›Ù ° ³Ð°m²%Õ&Ä Ê ° ºP·2¹¦ÆÇÄ ²%·2ÄmÈ8Ém° þ ¹¦· Ê · Ù °ÁÕà CA··ŒÕ Õ·ŒÆÇÄmºZ°Á¸¼· ÊZ ¹%¹ ¾ ¸›³Ð·ÆÇ° Ê ·%Äm²%Í?°ÁºZ° þP¾ Õ ¸ Ø›½¿¾Z šÊ °ÆH` : šÙ ° Ê · Ù °Á¸š°Á²%ÄmÈ8É´°“ÄmÕ Ä´²%·2¸›° Ù ¸šÄm²%°W85â ½ µ$ûÁµˆ£m¹ ›Ù ° þ ³Ð°Á²%Õ&Ämº Ê ° ¾ Õ Ä¹¦°Á¸ ¾ È2Ém° Äm¸šÄm²ÇÄmºJA%Ä Ê Ä þ+Ù ÎCÄ´Õ Ä Ê Ä Ê · Ù ·2¸ ¾ ¸š°Á¹¦· ÄmºNÆ÷Ä´Æ%°F° ¾·ŒÕ¥ 8dûÁµ


ü$â&%('Dá]Ÿ ß ¤*),+f£.-9ᘢ&¤6ãŸ0/21ܤon•” ‰–“(—l“ ì ¦¨§ u­ž :¡«¢}¡£


¾ Õ Ã?°Á¸ Ø Õ&·Œ²%° Ù °ÁºBA ¾ ÂNÄ Ê ° Ù °ÁÕ ÃP²%°ÁÃZ² · Ê Ä Ê ·Œ¹ Ê ··2¸›·ŒÆDz¦°Á¸ ¾ Õ º ¹ Ù U2º Ù2 Ä þ?Ê · œA šÊ °LàÃP²%·2¹¦·2ºZÈ2ÄÓ··2¸›ÓŒÆ%²%°ÁºZ¹6l Ê ·2¸›° Ù Äm¸ ›Ì Ä Ê °m¹&Eû8ù…KÿµÞâc¹dÆÇ·Œ¹SÃ?°Á¸ Ø Õ&·Œ²%°Á¹ þZÙ ¸šÄm¹%¹ å Ù Ä Ê °Á¹ Ù °mÕ&° % ±($â ö 8¹±IºcKAJPLzFÊþ ·Œ¹¦Æ÷É´°¹%·Œº Ê ° ¾ ¹ÇÄ Ê °Á¹ºZ°Á¹ôºZ° œ °Á¹Õ&°mº Æ%°Á²%·Œ¹ Ê ·ÍÞÑx·R¦BªVYMXj¬S±LzF»2L¼ºMWš°E½z¾OX8L\°°EL«J¿ºÀ¬Á:LzFo¬o¯J


ÿ¡ G à §0îð§0óòËíLìí£òËïÅÄ—ò§;© îí£óªÆÇÜ© óÞìïtÊÉSbSY\QS`cQSVg€R+Xz~¨XZWqM:RkbÙ ·ŒºNÆÇ·2Õ·2ºNÆ%· þ Õ ¾Z Æ%°Á¹+ÆDzÇÄ´ÍCÄm¸šÎP°Á¹c¹%°ÁÍZ²¦· Ù >m¸ ÙŒ¾ ¸š°m¹cÆ%·D`Á² šÙ °Á¹ Ê ·SÄ=åCº šÊ Ä Ê ·ËÃ]°m²kÃP²M`mÆ%°Áº&ÆMU2ÕÒË·ÊZ ›Ê Ä Ê Ä£ÍCÄm¹ ›Ù2›Ê Ä Ê · º¿Æ%² Ø ºZ¹%· Ù Ä Ê · ¾ Õ&Ä·2¹%Ã?Ó ÙŒ ·“ÓÄ£¹ ¾ Ä ÀgÌŽ˜¸Z“–ÀR“–·ÞÈ0’¡‘®Õ·2¸šÎP°Á²/Õ·’ Ž 85®/±(


ÝÞOß©ã äEå:æ è}é í êìÕV×kÙ ÔÖÕØ×:Ù(ÚœÛîíÊ Ä®S± ¹ÇÉm°Põ+»S±kÀ¨ãh8 õÑL¼ºMW¿½zR§±H¬oō¯S¨š±o¬Sö÷KBō¯µø£©n¬_FS°±H¦MXj¬S°Z±Y$< þ ãAÖ\áä8.øX¬Sªm¬_FS°4¬M­A½EH¥¦MJù0ªm¦MúºCÄ´È8Ém°¨>üS¬¥< þ áÖdÀ¨ã|8 ù)ª¼KAXj¬½EH¥¦MJ‘ö÷KBō¯ýø£©n¬_FS°±H¦¥¯Xj¬S°Z±Y$


JLh\VaMAX¡ cbSY\[]`tÊÉSbSY\QS`cQSVÄ Ê °°¹¦·2 ¾P ºNÆÇ·· ½¿¾Z ¸ Ø ÍZ² ° ½¿¾ZØ Õ ›Ù ° þ Ä ÀgÌ;Ž–¸Z“–Àn“ ·z·š¾Z·¥‘£¢«Ž˜¸ZÄ£À 85®Sâ§< Ê Ä·Œ¹%Ã?Ó ÙŒ ·¼® þ ·2ÕöÏ$â&%('Dá]Ÿ ß ¤*),+f£.-9ᘢ&¤6ãŸ0/21ܤû¥3(4zÈ4zþ Ó Ê ·ŒåCº ›Ê Ä Ù °ÁÕ°Ä ÊZ ³Ð·2²%·ŒºZÈ8Ä Ê ··2ºZ·Œ²% ÄLÆ%°mÆ÷Ä´¸ Ê °·Œ¹¦ÆÇÄ Ê °L³ ¾ º Ê ÄmÕ·2ºNÆÇÄmç· Ê °³5Äm¹¦·“ÂNÄm¹%°m¹Çĺ °Áºoõ ?Ï × ÎœÙp ì |‰–Ó× ÎM٠ϥ¤ì¤8dûÁµü´ÆÇ°ÁÕ°Á¹Þ·®Ù2¾ ¸šÄm¹ þ…½¿¾ ··Œº œ °Á¸ œ ·°·Œ¹¦Æ ¾ZÊ ° Ê · ? º °mºZ¹·&²ÇÄ ÊZ ›Ù Ä ¹2µL® ·Œ¹¦ÆÇÄmÍ ¸ šÊ Ä Ê · Ê ·2¹dÆÇ·2¹¹ ¹dÆÇ·2Õ&Äm¹Õ°Á¸šÓÊ · Âm²ÇÄmº Ê · Õ&Ã?°Á²¦Æ ? º ÙŒ ĺCÄ Ê ·ŒÆ%·2²%Õ ºZÄmÈ8Ém° Ê ·Õ&· Ù Ämº ¹%Õ°Á¹ôÍ ° ½¿¾ZØ Õ ›Ù °Á¹ þÙ °ÁÕ°Æ%²ÇÄmºP¹¦³Ð·ÝÓÙŒ Ä Ê ·S·2¸›ÓŒÆ%²%°ÁºZ¹ þ ³Ð°´ÆÇ°Á¹¦¹ Ø ºNÆ%·2¹%· þ ³Ð°Á¹d³Ð°Á² ¸ÅÄmÈ2Ém°‰° : šÊ Ä´Æ ›œ Ä þ ·ŒÆ Ù µcâ+¹¦Æ%·2¹Þ· ·2ÕÃZ¸š°Á¹ Ê ·ŒÕ&°ÁºP¹¦ÆDz%ÄmÕ²œU2ºÕÃ?°Á²¦Æ ? º Ù2 Ä Ê Ä Ê ·ŒÆ%·2²¦Õ ºCÄmÈ8É´° Ê ÄF®Sâ þ ÆÇÄmºNÆÇ°FÃ]°Á²ÕÓŒÆ%° Ê °Á¹“· Ã]·Œ² Õ&·Œº¿ÆÇÄ ¹ þnÙ °ÁÕ°FÃ?°Á²Ä>m¸ ÙŒ¾ ¸š°Á¹nÆÇ·D`m² šÙ °Á¹¨E¢ BK µ ÙÄ´ºZ· ²ÇÄsÕ Ä ¹·Œ³Ð·Æ œ ÄsÃCÄ´²ÇÄ Ê ·ŒÆ%·2²%Õ ºZÄmÈ8Ém° Ê ÄÄ´åCº ›Ê Ä Ê ·c·Œ¸š·ŒÆ%²MLÁº šÙ ÄsÓcÍCÄm¹¦·8Ä Ê ÄºZ°¼·Œ³Ð· ÆÇ°®}Õ›Ù ° þaÊ ·2¹ Ù °ÁÍ?·2²dÆÇ°·ŒÕ_û6ùÁùNú þ Ã]°Á²»¼· ºP² šÙ Η»·Œ²¦Æ Ì E¢ K µ&ýÞÄm¹%·2Ä Ê ÄºZ·2¹dÆÇ·ÃZ² º Ù2Ø Ã ° þ ijаmÆ%°:·Œ¸šÓÆDz٠Æ%²%°Á¹ Ù °Áà Ä&³Ð°mÆ%°:·Œ¸šÓÆDz ›Ù ĵ % áy8 û L«Xj¬•¹³Qýù)ªVL¼ºMWš°œm¸šÙ Ä´¹2µ % ¹ËÕ&·Œ¸šÎZ°m²%·2¹Ü²%·2¹ ¾ ¸›ÆÇÄ Ê °Á¹s¹%Ém°“°ÁÍPÆ šÊ °Á¹ Ù °ÁÕ ° ¾ ¹¦° Ê ·ôÕ&ÓÆÇ° Ê °Á¹Þ¹¦°måC¹¦Æ šÙ Ä Ê °Á¹ þCÙ °´Ý·Œ¸š·ŒÆ%²MLÁº¾ ³ ¾ º Ù2 °mºCÄm¸ Ê · Ê ·ŒºZ¹ ›Ê Ä Ê ·· Ù °ÁºBA ¾ ºNÆÇ°m¹ Ê ·ÍZÄm¹%·Œ¹ Ù °ÁÕÃZ¸›· °Á¹ þsÙ °ÁÕÕ°qFo¦B¨¥©«ªm¬M­˜FSª®¨G¯S°4¬S±F°Ä Ê Äm¹Ü³ ¾ ºZÈC:·Œ¹ ÊZ ³ ¾ ¹%Äm¹Ë· Ê ·ôÃ]°Á¸šÄm² ›Ì ÄmÈ2Ém°E¢ ü þ ÁøBKÿµÄmÃP²%°ÁÃZ²


ÿ¡ ©¨ ¥¨§©© óÞì Ä—òܧóÞ칉Õ&° Ê ·Œ¸š°Á¹¼ÆÇ·D`m² šÙ °Á¹ ½¿¾ · Ê ·Œ¹ Ù ²¦· œ ·2Õé°Á¹‰¹ ¹¦Æ%·2Õ&Äm¹/Õ&Ä Ù ²¦°Á¹ Ù `Áà ›Ù °Á¹/·Õ šÙ ²%°Á¹ Ù `Áà šÙ °m¹S¹ÇÉ´°%³Ð·2²¦·2ºNÆÇ·Œ¹2µsâ+º ½¿¾ ÄmºNÆ%°°Á¹¼¹ ¹dÆÇ·ŒÕ Äm¹ËÕ&Ä Ù ²¦°Á¹ Ù `Áà ›Ù °Á¹Ë¹ÇÉ´° Í?·2Õ Ê ·Œ¹ Ù ² Æ%°Á¹Ã?·2¸šÄÕ&· Ù ? º ›Ù Ä Ù ¸m>m¹dÝÊZ¹LÃ]°Á¹dÆ ¾ ¸šÄ Ê °Á¹ Ê ÄzÕ· ÙD? º šÙ Ä ½A¾R? ºNÆ šÙ Ä Ù °ÁºZ¹ šÊ ·Œ²ÇÄmÕ ½A¾ · ½¿¾ Äm¸ ½¿¾ ·2²L¹ ¹¦Æ%·2Õ&Ä}Ã?° Ê · ¹%·2²%°ÁÕ&ÃP¸š·ŒÆÇÄmÕ·2ºNÆÇ· Ê ·Œ¹ Ù ² Æ%°ËÃ]°Á² ¾ Õ&ÄÞ³ ¾ ºZÈ2Ém° Ê ·k°mº Ê Ä8¨


€VoXZ`cQSR+XEU"`kefY\huMPRcbYd`cbR{°mÃ]·Œ²ÇÄ Ê °m²Ë»SÄmÕ ¸ÆÇ°Áº ÄmºZ°ÃCÄm²%Ä ¾ Õ Ê Ä Ê °&¹ ¹¦Æ%·2Õ&Ä*·2¸›·ŒÆDzœLÁº ›Ù °Ó Ê ·2¹ Ù ² ÆÇ° Ù °ÁÕ&°“Ŧ°ÁÕ Ä%°mÃ]·Œ²ÇÄ Ê °m²»ÄmÕ ¸›Æ%°Áº ÄmºZ° ½A¾ · Ê ·Œ¹ Ù ²%· œ · ¾ Õ ¹ ¹dÆÇ·ŒÕ Ä£Õ°Á¸š· Ù2¾ ¸šÄm² Ù °mÕ¥º ·2¸šÓÆDz¦°ÁºZ¹ô·&À%Ù ¸š·2°m¹·ŒºZÂÁ¸›°ÁÍCÄ Ù2 º Ù ° Ù °ÁºNÆ%² Í ¾Z ÈC:·Œ¹ÃZÄm²ÇÄÄ·ŒºZ·2²¦Â Ä Ê ·Œ¹¦Æ%· ¹ ¹¦Æ%·2Õ&ÄPõô°Á¹‰ÆÇ·2²¦Õ&°m¹ ÙŒ ºZÓÆ ›Ù °Á¹ºGíXëZ Oj[ Y :`Z `Oj[ Y\`O`Xë:``pXë:X: b9cëpX ^c ô`d``ôaZ ÓÄ Ù °ÁºP¹¦Æ÷Ä´º¿Æ%· Ê ·ÓŦ·2ÃCÄm²%ÄmÈ8É´° º¿Æ%·2²¦º ¾PÙ ¸š·2Äm²¨E› ¢ K µô²¦·2¹¦°Á¸ ¾ È2Ém° Ê Ä â ½A¾ ÄmÈ8Ém° Ê ·ã Ù ÎZ²©T ÊP ºZÂÁ·Œ² þs¾ Æ ¸ šÌ Ä´º Ê °F° °ÁÃ?·2²%Ä Ê °Á² »SÄmÕ ¸ÆÇ°Áº ÄmºZ° Ê Ä®`Yô\O Ó$â&%('Dá]Ÿ ß ¤*),+f£.-9ᘢ&¤6ãŸ0/21ܤûJ½ µ/ûÁµûÁûÓ Ä · ½¿¾ Ä´È8Ém°E³ ¾ º Ê ÄmÕ&·ŒºNÆ÷Äm¸ Ê Ä Õ&· Ù ? º Ù2 Ä ½A¾R? ºNÆ šÙ ÄE·¨Ó Ù °ÁºPÎZ· ÙŒ šÊ Ä Ù °ÁÕ&°®é⽿¾ ÄmÈ2Ém° Ê ·ã Ù ÎZ²=T ÊZ ºPÂÁ·2²Œµk® ¹¦°Á¸ ¾ È2Ém°“· Ä´ÆÇÄ Ê Ä· ½A¾ ÄmÈ8Ém° Ê ·ã Ù ÎZ²©T ÊZ ºZÂÁ·Œ² º Ê ·ŒÃ]·Œº Ê ·Œº¿Æ%· Ê °âÙ ·°·Œ¹¦Æ÷Ä Ê °·2¹dÆ÷Ä ÙŒ °Áºn>´² ° Ê ·Õ·2ºZ°Á²·2ºZ·Œ²%Â Ä þ+½¿¾ ·£Ó Ù °ÁºZÎZ· Ù2 šÊ ° Ù °ÁÕ°¨·2¹dÆ÷Ä Ê °Æ%·2ÕÃ]°³Ð°m²%ºZ·¾ º Ê ÄmÕ·2ºNÆ÷Äm¸ Ê °&¹ ¹dÆÇ·2Õ&ÄE¢ K µ³3(4E’µ453Ê Ä´¹ Ù °ÁºNÆDz Í ¾Z ÈDCA·2¹ ÙŒ ºZÓÆ šÙ Ä*·ôÃ]°mÆ%·2º ÙŒ Äm¸ Ê ·2¹dÆÇ·¹ ¹dÆÇ·ŒÕ ÄPõrʼn V p W 8dûÁµû ¢


ûÄ´Õ&·Œº¿ÆÇÄ Ê Ä*ºCÄÂÁ²%Ämº Ê · ÊP ³Ð·2²¦·2ºZÈ2Ä Ê ·‰Õ Ä´¹%¹ÇÄ·Œº¿Æ%²%·‰°“ºGí Ù ¸›·2°Ä´ÆMLÁÕ ›Ù °*·‰°“·Œ¸šÓŒÆ%²%°Áº þPÙ °mºZ¹ ›Ê ·2²%ÄÊ€z´Æ šÙ Ä· Ä´Æ÷Ä ÃCÄm²%ÄF¹ ¹dÆÇ·2Õ&Äm¹®âóòpXça``$â&%('Dá]Ÿ ß ¤*),+f£.-9ᘢ&¤6ãŸ0/21ܤ·Ä ÊZ ¹dÆDz Í ¾Z È8Ém°·2¸š·ÆDzœLÁº šÙ Ä Ê · ¾ Õ&Ä*Õ&°Á¸›Ó ÙŒ¾ ¸ÅÄÃ?° Ê ·‰¹%·Œ²¼ÍZÄm¹%·2Ä Ê Ä“·2Õ ¾ Õ&Ä*·2¹dÆDz ¾ Æ ¾ ²%ĺ ¾ ݽ¿¾¸š·8Ä´²*å ÄPµGã:·Œº Ê ° Äm¹%¹ Õ þ °F°ÁÃ?·2²%Ä Ê °Á²»SÄ´Õ ¸›ÆÇ°mº ÄmºP°Ã?° Ê ·L¹¦·2²¹%·2ÃZÄm²ÇÄ Ê °—·ŒÕ ¾ Õ ÄÃCÄ´²¦ÆÇ·ÙšÙ Äz8 r ·Œ¸š·ŒÆ%²MLÁºrji§¨° »SÄ´Õ ¸›ÆÇ°mº ÄmºP°º ¾ZÙ ¸š·2Äm²*Ó Ù °mÕ&Ã?°Á¹¦Æ%°¨Ã?·2¸ÅÄÙ°ÁºNÆDz Í ¾Z È8Ém° Ê · ²¦·2à ¾ ¸›¹ÇÉm°º ¾PÙ ¸š·2Äm²2µ® º Ê ÄÃ?° Ê ·Ýw¹¦· Ê ·åCº ²°¨°ÁÃ?·2²%Ä Ê °Á²»SÄmÕ ¸ÆÇ°Áº ÄmºZ° Ê ·ÙÕ ·2¸šÓÆDz¦°Áº 8 Z :=< þ ÃCÄ´²ÇÄ ¾ Õ ¹ ¹¦Æ%·2Õ&Ä Ê ·À ºGí Ù ¸š·2°m¹ þÜÙ °ÁÕÃ]°Á¹dÆÇ°¹¦°ÁÕ&·ŒºNÆÇ·Ã]·Œ¸š°Á¹*Æ%·2²%Õ°Á¹ Ê ·¾·ŒºZ·2²¦Â Ä Ù2 ºZÓŒÆ šÙ Ä Ê °&·Œ¸šÓÆDz%°mº·Ä´Æ%²ÇÄmÈ2Ém°º ¾ZÙ ¸›·8Äm² þCÊ ·2¹ Ù ² ÆÇ°·2Õ ¾ º šÊ Ä Ê ·2¹¼Ä´ÆMLÁÕ šÙ Ä´¹ þPÙ °ÁÕ°Zõ`¡k8dûÁµûJ£´Æ%°ÁÕ° Ê ·LÎ šÊ ²%°Á£UŒº °ñE_£BKÿµ ö · œA šÊ °—Ä´° Æ%·2²¦Õ&° Ê ·Õ¾ ¸›¹ÇÉm° ·Œ¸š·ŒÆ%²MLÁº šÙ Ä þ ºZÉm°—ÓLÃ?°Á¹%¹ Ø›œ ·2¸Ë²%·Œ¹%°Á¸œ UÝu¸ÅĨÃCÄ´²ÇÄ ¹ ¹dÆÇ·ŒÕ Äm¹Õ ¾ ¸›Æ Ýw·Œ¸š·ÆDzMLmº šÙ °Á¹·L¹%·£³5Ä Ì²¦·2ÃÙ ·Œ¹%¹H>´² °° ¾ ¹%° Ê ·ô° ¾ Æ%²ÇÄm¹¼ÄmÃP²%° : Õ&ÄmÈDCA·2¹ þ Äm¸›Ó2Õ Ê Ä Ê ·ý % µºZ·Õ&° Ê ·2¸›° Õ&Ä´ÆÇ·ŒÕj>=Æ šÙ ° ÃZ²¦°ÁÃ?°Á¹¦Æ%°£Ã]°Á² ö ° ¾ ÂÁ¸šÄm¹‰»Äm²¦Æ%²%·2· þ ·2Õ û6ü ¢ ù þ Ó ¾ Õ&Ä Ê Äm¹‰Ä´ÃZ²%° : Ý%Ä ¹ Õ&Ã?°Á²¦ÆÇÄmºNÆÇ·Œ¹2µ ö ·Ä Ù °Á² Ê ° Ù °ÁÕx·2¹¦Æ%·ôÕ&° Ê ·2¸›° þ °Á¹s·2¸›ÓŒÆDz¦°ÁºZ¹ Ê · ¾ Õ Ê ·ÆÇ·2²¦Õ ºCÄ Ê °Õ&ÄmÈDCA·2¹ÜÕ¹¦Æ%·2Õ&Ä&Õ° œ ·2ÕÝw¹¦· º Ê ·2Ã?·2º Ê ·2ºNÆÇ·ŒÕ&·ŒºNÆÇ· ¾ ºZ¹ Ê °Á¹/° ¾ ÆDz%°m¹2µ‰ãA·2º Ê °LÄ´¹%¹ Õ þ Ä&³ ¾ ºPÈ8Ém° Ê ·°Áº Ê Ä¹Æ%°mÆ÷Äm¸+8'òØ < Ê · ¾ Õé¹ ¹dÆÇ·ŒÕ ÄLÕ ¾ ¸Æ ·Œ¸š·ÆDzMLmº šÙ °£Ã]° Ê ·“¹%·Œ²²%·ŒÃZ²%·Œ¹%·Œº¿ÆÇÄ Ê ÄÃ?·2¸›°ÃP²%° ÊZ¾ ÆÇ° Ê ·¨J³ ¾ ºPÈDCA·2¹Ë°Á²%Í Æ÷Ä ¹ÞÕ°ÁºZ°A·2¸›·ŒÆDzœLÁº ›Ù Äm¹78n¡:\


óòòØ ‰onXç©n«O%p p p=n¡ë 8dûÁµû


tŒ8‰ q(çDq˜O9qN%yzyzy©q4i2‡ 8dûÁµû6ù ÕÃZ¸ ØšÙ2 ÆÇ°Zµ°Áº¾ ¹%° Ê ° Ê ·ŒÆ%·2²¦Õ ºCÄmºNÆÇ· Ê ·ã:¸šÄ´ÆÇ·Œ² ÂNÄm²%ÄmºNÆÇ·ÄEÄmºNÆ Ýu¹ Õ&·ÆDz Ä Ê Ä—³ ¾ ºZÈ2Ém° Ê ·°Áº Ê Ä þËÊ ·%Ê · ¾ Õ¹ ¹¦Æ%·2Õ&ÄÕ ¾ ¸›Æ ·2¸›·ŒÆDzœLÁº ›Ù ° þ ¹%Ém° Ù ÎZÄmÕ Ä Ê Äm¹ Ê · 4•–Ž–—£ÅX·šºi“–·s´–ÀnºD· µ % Õ&ÓÆÇ° Ê °&ÓÆ%°mÆ÷Äm¸°ÁºZÎZ· Ù2 šÊ ° Ù °ÁÕ° Ù °ÁÕ*Í ºCÄmÈ2Ém°Þ¸ ºZ·2Äm² Ê °m¹°Á²%Í Æ÷Ä ¹oÄ´ÆMLÁÕ šÙ °m¹)8†»!L«JV¬lK±¥§¦MXüiL«J#K°ELQ¦MJͦ.Q!T]°4¦MX8LzFÙþ …ÔÜ® %


º¿Æ%²%° ÊZ¾ZÌŸš¾ ° ö ·ÆÇ·Œ²%Õ Ÿ ºCÄmºNÆ%· Ê ·ã:¸šÄ´ÆÇ·Œ²ôÃCÄm²ÇÄÄ Ù °ÁºZ¹dÆDz ¾ È8Ém° Ê Ä³ ¾ ºPÈ8Ém° Ê ·&°mº Ê Ä Ÿ º Ÿ›Ù/Ÿ Ä´¸q·&°ŸÄ´¸ Ÿ ¹¦Õ&°Õ Ä´Æ%·2Õk>´Æ Ÿ›Ù ° Ê ·Œ¹%·2º œ °Á¸ œ ŸšÊ °Ã]°m²ÒË°A°mÆÇÎCÄmÄmº þ ³Ð°Á²ÇÄ´Õ ²%· Ê ·ŒåCº ŸšÊ Äm¹SÄm¹â ½¿¾ Ä´ÈDCA·2¹ Ê ·³Ð°Á²¦Õ7j\OXça`û6ü$â&%('Dá]Ÿ ß ¤*),+f£.-9ᘢ&¤6ãŸ0/21ܤ3(4E’µ4E’^_raM:RsQSRœUžÄmÃZ²¦° Ÿ Õ ÄmÈ2Ém°/³ ¾ º Ê ÄmÕ&·ŒºNÆ÷Äm¸ Ê Ä‰ÆÇ·Œ°Á² Ÿ Äô»Sá Ó ½¿¾ · Ù Ä Ê Ä·Œ¸šÓÆDz%°mº&¹¦·Õ° œ ·Ë·2Õ ¾ Õ Ù ÄmÕÃ]°®Ÿ›Ù °¨·Œ¹¦Æo>=Æ ŸšÙ ° þcÙ ² Ÿ Ä Ê °Ã?°Á²*Æ%° Ê °m¹*°Á¹° ¾ Æ%²%°Á¹·Œ¸šÓÆDz%°mºZ¹2µ—®Së`Á¹Ä¨¹ ¾ ÂÁ·Œ¹¦ÆÇÉm° Ê ·LáI° Ù [ þc½A¾ ··Œ¸šÓŒÆ%²»Äm²¦Æ%²%·2·#Ý\áC° Ù [ þP½A¾ ·ºCÄ*³Ð°Á²¦Õ ÄåZºCÄm¸Ã?° Ê ·ŒÕ ¹%·Œ²Ë·2¹ Ù ² ŸÆ÷Äm¹ Ù °mÕ&°Zõ¡ :¢q˜:³‰¤£œ:¥q–: 8dûÁµ¢ øm¹%¹ ŸšÙ ÄWE›NúBK µ¨ ‰ b« b ” j,—5q b ” j,— Kªq¯BçZO´]¬ O 8dûÁµ¢£¢


Ù °ÁÍZ² Ÿ Õ·2ºNÆÇ°L·Œº¿Æ%²%· Äm¹‰³ ¾ ºZÈDCA·2¹ Ê ·ÍCÄm¹¦·h8 ãš: b P·²‰”:¸µ¹‰ b ‡H


¤ÕÓŒÆ%° Ê °»áÆÇ·2Õ ¾ ÕgÃCÄmÃ?·2ŅÕ ¾¡Ÿ Æ%° Ÿ ÕÃ]°Á²dÆ÷ÄmºNÆ%·qºCÄ ½¿¾ZØ Õ ŸšÙ Ä ½A¾¡Ê ºNÆ ŸšÙ Ä þ ºCÉm°¼¹%°ÁÕ·2ºNÆ%·kÃ?°Á²%¾ ¹s²¦·2¹ ¾ ¸›Æ÷Ä Ê °Á¹ þ Õ Ä´¹ÞÃ]°m²Ü¹%·Œ²s°³ ¾ º Ê ÄmÕ&·ŒºNÆÇ°ÃCÄm²%Ä*Ã]°m¹¦ÆÇ·Œ² Ÿ °Á²%·Œ¹sÄmÃZ²¦° Ÿ Õ ÄmÈC:·Œ¹ þA½¿¾ · Ÿ º Ù ¸ ¾ ·ŒÕ¹¦·ÙŸ °ÁºZÄm¸a²¦·2¸ÅÄ=Æ ŸÇÆ ÄmÕ·2ºNÆ%·S³Z> Ù · Ÿ ¹Œµ¤`$â&%('Dá]Ÿ ß ¤*),+f£.-9ᘢ&¤6ãŸ0/21ܤû ¢¾ Õ&·Œº¿Æ%° Ê Ä ½A¾ Äm¸ Ÿ›Ê Ä Ê · Ê Äm¹o³ ¾ ºZÈC:·Œ¹ Ê ·kÍZÄm¹%·qÆ%°Á²%ºCÄ´Õ"°Á¹$²%·Œ¹ ¾ ¸Æ÷Ä Ê °Á¹ Ù Ä Ê Ä Æ ·/ÈcÕ&Ä Ÿ ¹oÃP²%· ÙŸ ¹¦°Á¹ þ°ËĽ¿¾ ·&¹%· Ä´Æ Ÿ ºBA%Ä° ¾¸ZÌñ¸\¥·¸€ÀR‘¥¥‘J·G·,oÑ”’”Ä£ˆ µ±·Œ¸š°ÃP² Ÿ º Ù2Ø Ã Ÿ ° Æ Äm² Ÿ Ä Ù/Ÿ °ÁºCÄm¸ þ ÃCÄm²ÇÄ ¾ Õ Ê Ä Ê °Ä´Æ%ÓŸ ¹¦Æ%·2Õ&Ä þ Ä·ŒºZ·2²¦Â Ÿ ĺZ°“¸ Ÿ Õ ŸÆÇ·»Sá 8 â Š§


B æC$#ºæ4ô¹ß]æ=æ©ø¡â/ðû Yo©n¬¹±ªüiL\°zK⯠þ 5¨ % ¹o


B‰i ÜX kbÆ é‚ï Ÿ é½á¡â g é gëß]àíìèïèéE¢áSé½â¸à¡ß]ï©ðäéò¢ð¦â/àíìèâø È Ÿ à¡éRíé`€ iEb â ~ â ú ï=âR 0 ìèâm)é‚ïDìfâ ß]ô­ò¢â`€ gb ÷Aß]ïèé‚ð…ß]æô­ï Ÿ ð¦â Ÿ ï=ß]æ é½â/æDìèø¡á¡é‚ïø¡ðñéîæ=ûï Ÿ â~Ÿ àSé‚á¡â¦ ø¡é‚ó¡ â/æ ô¹ß]ï Ÿ æ=æ=ß\ %÷Aß‚ïèé‚ð_ë/ï Ÿ é‚áSé‚æº÷Aø­à¡ó¡ â/æ|¦Nø¡âjá¡â¡à¡â/ð|á¡ø¡é‚æ÷Aø¡à¡ó¡ â/æ á¡â¢Séæ=â¦ôSé‚ïèéeb$â&%('DáGF ßH ),+JI.-KML HON F0/21 H PRQ¢¡ï Ÿ ð¦â/àíìè߸âàNì=ï=âhá¡øSé‚æS$#ºæ ûïèéô Ÿ áSéðñâàNì=âfë/ß]ð¦ô¡ø­ìèé‚áSéâ/ð…ë%ò¢ë/ø­ò¢ß]æ?á¡ââ/æDìèï©ø­ìèø¡ï=é§âò¢âì=ïT&]à Ÿ ¤ë/é ÜVU %¦é‚æW!"$#æfìXðY]ïèéà¡á¡â÷1é‚ë Ÿ ò Ÿ áSé‚á¡âºá­â Ÿ ðñô­ò¢â/ð¦â/àíìèé‚ózç‚߃ëß]ð¦ô¡ø­ì9éë Ÿ ß‚àSé‚ò>â¸ô¹â/ï=ð Ÿ ì=â/ð³éߣ¢ìèâ/à­ózç‚ßjá¡â¸ï=âæ=ø¡òBì9é‚á­ß]æfá¡â¸ô¡ï=ß]ô­ï Ÿ âáSé‚á¡âæéìX&]ð Ÿ ë/é‚æ)â¸ð¦ß]ò¢âë/ø¡ò¢é‚ï=âæV¢Sé‚æDì9é‚àíìèâ¸ô¡ï©â/ë Ÿ æ=ß‚æ Ü éïèéºæ=â)é‚ô¡ï=ß Æ â Ÿ ìèé‚ï?é‚æmðñâò ú ß]ï©â/æëzé‚ï=é‚ëì=â/ïTÇæ©ì Ÿ ëzéæ4áSé‚æm÷Aø­à¡ó¡ â/æZ


ŸžG Z¡KGF5¢ H¤£¥ I§¦KML HON FS¨Ÿ© H P B æâSé‚æ©â/æ)á¡âGÄ¥ø¡à¡à\´¢à½âhë/ß]ò¢éR¢¹ß]ïèé‚á­ß]ï=âæ æ=ç‚ßîâ âðñô­ò¢ß]æ á¡â¥ëß]àíìèïèéózç‚ß½á­âh÷Aø¡à¡óâæ2á¡âG¢Sé‚æ=âÆ é‚òŒ/à¡ë´Šé½æ=ç‚ßjï=â/ô­ï=â/æ©â/àíì9éá¡ß]æ¥ô¹ß]ï)÷Aø¡à­ó¡ â/æ|u’“‡•”*Š‹m«Î³ Üá¡âæ=âà Æ ß]ò Æ Ÿ áSé‚æsé‚æ÷Aø¡à¡ó¡ â/æS†ª”*Š—‡wq«ª¬¥­RŠ‹mˆ¯®°‹ Ü ãhâæ©ìèâ)ì Ÿ ô¹ß¥á¡â ÷Aø¡à¡ózçßá¡âV¢Sé‚æ©âR íß]æß]ïT¢ Ÿ ì9é Ÿ æ Ÿ àíìèâï=à¡ß]ææ=ç‚ßäï©â/ô¡ï©â/æ=âàíì9é‚á¡ß‚æºô


QB ô¡ï ƒ ´¢ðñé âìèé‚ôSéÒôSé‚ï=é ð¦â/ò ú ß]ï=éáSé6á¡â/æ©ë/ïT´Çózç‚ß áSé‚æõ÷Aø¡à­ó¡ â/æöá¡âÔ¢Sé‚æ©âÓûÓé6é‚á´Çózç‚ß6á¡âŸžG Z¡KGF5¢ H¤£¥ I§¦KML HON FS¨Ÿ© H P£Ð6>85)M/£9:4


ŸžG Z¡KGF5¢ H¤£¥ I§¦KML HON FS¨Ÿ© H P ·à¡ß‚ï=ðñé‚ò¢ð¦â/àíìèâëß]à¡æDì9é‚àíìèâæ¥â¸ìèâà¡á¡â/ðé¦æ=â ëzé‚à­ë/â/ò¢é‚ï Ü þ ß]àíìèø¡á­ß 85)M/£9:4


Æ ß á­â¦ë/é‚ï=ß ó/ß fÀå,æ ‹°®mq‡w¬R‹ÁçÃŽ¥’X‹(è$Ž¥ª‹mˆ¯®m‡q­RŠ— þ j ß‚øÓô­æ=â/ø­á¡ß]ô¹ß‚ìèâà¡ë¡´¢é‚ò?ôSé‚ï=é ï=â/ô­ï=â/æ©â/àíì9éï§ß]æB ëß]à¡æ©ì=ï=ø¡ó/ç‚ßá¡ßô¹ß‚ìèâà¡ë¡´¢é‚ò â÷AâìT´ Æ ßôSé‚ïèéhø¡ðªß]Çìèé‚òNá¡â Æ é‚òŒ/à¡ë´Šé¥ëß]ð ð¦ß]ð¦â/àíìèߺé‚à]ø¡ò¢é‚ïøùhúû â öø ¨ ùhúû ï©â/ô¡ï©â/æ©â/àíì9é¦ø¡ðäéƒð¦ßá\´ŒSë/é‚ózç‚߃âðöêó àíôïøý¡þ É ß]æ¸ß]ô¹â/ï=é‚á¡ß]ï©â/æ á¡â þ ß]ø¡ò¢ß‚ð¢öàóí ôïá­â/ïT´ Æ é‚á¡ßºá¡â ÿô­æ=â/ø­á¡ßß]ïT¢\´Çì9éòøùúhû Sá¡â Æ ´¢á­ßñéߦô¹ß‚ì=â/à¡ë´Šé‚ò>â!÷AâìT´ Æ ß ÜögjŸžG Z¡KGF5¢ H¤£¥ I§¦KML HON FS¨Ÿ© H P£äÑ(;¡4' r '0+.4


ŸžG Z¡KGF5¢ H¤£¥ I§¦KML HON FS¨Ÿ© H Pàóí ôïàêëûùhúû c ÿ ùhúhûc ûà ý¡þ É ÿÉ ý¡þc ûfhg Ü Q£Qkjðäé â È ë/ß]à úûâ/ë¡´Çá¡ß]æ¸ßöô¡æ=âø¡á¡ßùß]ïT¢´Bì9é‚ò Û cj âƒß é‚ø­ì=ß Æ éò¢ß]ï û Æ c j áSé ¦ Ü g Ü QkP 0ßöô¹ß‚ìèâà¡ë¡´¢é‚òf¢ fâ!÷AâìX´ Æ ßjô¹ßá¡â¸æ©â/ïfá¡â/æ©ë/ï´Çìèßjëß]ðñߧ`€ ä¥b ]øûùhúhû c õ ¨øûc à ¢ ¤§¦êë ô ó ñ¥¤§¦ìífhg Ü Q jìoõî ïûc


Eb Ü ð¦â/àíì9éE´¢æ|`€Bþ %‚òÇë/ø¡òÇß]æ ~ ÏÜ]â/ï=é‚ð{ï=âæ=ø¡òBì9é‚á­ß]æñëß]ð{ô¡ï©â/ë¡´Çæèç‚ßÓáSéÓß]ï=á¡âð{á¡âTSUSWV âþ ß]à0]ø¡ï=é‚ózç‚ß\ âß]ïT´¢éƒá¡â â/ïDìèø¡ï¢Sé‚ó/ç‚ßñâ§çÃŽ¥.”*Š‹T‘çCŠ—k†m§‹m’“ Sá¡âæ=ë/ï´Çì=ß]æéjæ©â¡]ø\´¢ï ÜŸžG Z¡KGF5¢ H¤£¥ I§¦KML HON FS¨Ÿ© H PRa "!$#%!'&)(*!©+,+.-0/21'3542!'671'#%!'&%‚òÇë/ø¡òÇß]æ¸á¡âäâæ©ìèï©ø­ìèø­ïèéêâò¢âì=ïT&]à\´¢ëzéöá¡â¦ô¡ï=ß‚ô¡ïT´Çâ/áSé‚á­â/æ½é3ìX&]ð}´¢ë/é‚æâäð¦ß]ò¢âë/ø¡ò¢é‚ï=âæ"¢Sé‚æ©âzé‚á¡ß‚æþàSé ¦NøSé‚ózçßñá¡â‚ë ú ï98á\´¢à]âïfæèç‚ߦë ú é‚ðñé‚á¡ß]æfá¡â¸ë¡%‚ò¢ëø¡ò¢ß]æð¦â/ë;:‚à´Çë/ßE¤À¦ ø


B~ ~ A B ħ Á‡Å {Žw‘vxwŒ† |´BA ~2‚Uz\†CŠ;vÆ‚U£~;‚‹{ ~ ´{2z\†C{;©}‰w œa€hz{7µ |{;9‚UB€


~ — Ï ‚Žv$Š2†C‚‹}


Ø { ´z ´zhçU{ |D‹mµ­RŠEûÃ` Ðgý òý òb |{2~;‚Uv${;zh}‰wv³‚Ë€


!"!#!’}ö ‚Uˆž{ |w}


ŸžG Z¡KGF5¢ H¤£¥ I§¦KML HON FS¨Ÿ© H Q öãöööïöŠbˆ¡‚U9PÌ= {;¡ˆ‰w |w' ´9†P{;vxw– ´v$ˆ


9É-0!+L421 :


ŸžG Z¡KQP5¢SR £¥UT ¦WV¡XYRZ[PS¨Ÿ©\R ] ·K


ŸžG Z¡#VQP5¢SR £¥UT ¦WV¡XYRZ[PS¨Ÿ©\RP{2çU€ P„‚$wˆ |{;P{2z\†›w}çU€


ŸžG Z¡#VQP5¢SR £¥UT ¦WV¡XYRZ[PS¨Ÿ©\RŸ¡ 3ž £¢¤Ÿê´ Ž ­k²l‡wˆ0‡wq‡ w = wzhƒ;‚U0~2‚Uvxĥ€h†›w~ ´‚Uz


ŸžG Z¡#VQP5¢SR £¥UT ¦WV¡XYRZ[PS¨Ÿ©\Rv { Û w |{;ˆ |{;P{2z\†›wƒ;„‚Ý}


ŸžG £¥UT ¦WV¡XYRZ[PS¨Ÿ©\R ¹ “Z¡#VQP5¢SRà Á wy{2z


Ü ÝßÞáàâÀãåähæ çè é½ê


ŸžG Z¡#VQP5¢SRùø ¥ RúDûüQV T~ý Rkþ ¹šlÍ´}


ŸžG ¥ RúDûüQV T~ý Rkþ ¹ ]Z¡#VQP5¢SRùø9†P{;"{;N†C€


ŸžG Z¡#VQP5¢SRùø ¥ RúDûüQV T~ý Rkþ ¹J¹


Ü ÝßÞáàâÀãåähæ ë,âÀæ æ ähæ ì ÝT6%42#Ë1#%-!©+ +©"!y6x;‚Uv$‚Ñvx‚UN† |w0w à » — a — ’ wÑw


T5 ·45!6©7#VQP98SR;:=ªüºV2RZWR@8SRBA ¹wŒ†P€ | w —©Í ‚ |†›wz\†C‚ ’ w à » — |´†›w‡~2‚Uvx‚Àm· ] —a ˆž‚‹}


45!6©7#VQP98SR;:=ªüºV2RZWR@8SRBA T5´}|'|{;P€h>†›wŒ}~;€‚U©ˆ |{2~ ´P‚U‡wȆ | w = Š; }


45!6©7#VQP98SR;:=ªüºV2RZWR@8SRBA T5 "!$#%! â#%4˜"4'Uy! #%-V6%- +W4;1 1£Ï+.1kU Ñ&â#7- Ÿ¡ ᢠŸê‚‡{29†P€


T5 ¹545!6©7#VQP98SR;:=ªüºV2RZWR@8SRBA“£C„Œ‚'~2‚Uzñ9€


45!6©7#VQP98SR;:=ªüºV2RZWR@8SRBA T5 ƒ “


Ü ÝßÞáàâÀãåähæ „… ëNï[ãåäâªÝ† æðï ë ‡ ì ’ãåï[ï‹Š ë ï|‚ç | wvxw { d‘ ±{;~2€‚Uz‰wjr>¸¼‰w |v ø zerB~…wŒ£{x‚Ë~>~;€‚%}‰w{;z{2† |9ø zxr>~…w‚Ë~>~;€‚%}‰w©œ|{2»=Shú;z


v P{2çU€xr>}‰w ’ ‚UŸ


45!6©7#VQP98SR;À=


üSþóPÁ8 Vx5QZWRkþªü Z TþE4YPþqþÂküSþ ƒ¹45!6©7#VQP98SR;À=?2B6!h7ž/7,=)!/"W+;3 #&% r+µ #-hTi&+X/ƒ) r >?2B,¨#-,1P^+;,=%0/1,02!34'5#-)!+-,*+ C ' r )!+-,6B+–6!j¯ /73· ²\H ˜B‰¾¡ † )YP²"³ŠU# r 6!)$#“6$i-+N,0i-+±,0#&' r ,(>ˆ#&'0”;% r +;,7P-/7F C +;%¨#“E$#ñ #X2!Fa#“%0/1)!2!hTi&+±, r 8;6 r V < #\' ŕ¯ #)B+‚¯=r +±F l ) r + †ˆ´ ®^­¤µ-“° y^· FG+;3·Š¤bJ¥L2M,(/ñ#BPž+}F l '0+^)!+± ‚ 6$i-+±)!/7, < %(/ ¯ /N#&)!/7@2$#-)!#-Fa/16’'¨//1,('¨#)!/1,"!%(+;"!% r /7)!#-)!/-P³FG/7,(Fa+gFG/73<strong>DE</strong>B+;%¨#-6B)!+G# C #-,(/±2^' r 3r+µ #-)$#BP r 6!) r9< #-6!)B+a#G6!/ < /7,(, r )!#-)!/})!# r 6 < 392!,¨i-+)$# < +;%0%(/73 #&hTi-+g/739/1'0%0:;6 r9< #Bb' r 3r+µ #&6!)!+a#M'¨/7+-% r #G)!/{"W/7%('02!% C #-hTi-+Ÿ)B/–,0/18;2!6!)$#Ÿ+;%()!/7F¸)!/g¹[º;3D39/7% H cJ3D/7,(,0/f' † ¹]c=-ŠfPY+;,%(/7,02B39'5#&)!+;,M)B/_#&V$6 r )$#-)B/]"W+;%M"B%0”-'0+;6Ž#-"B%0/7,(/76’'5#&F 2!Fa#»FG/739E!+;%¨#¼, r 8;6 r V < #&' ŕ¯ #Bb¢½+ª6!j¯ /73· ²\H ˜B‰¾¡Q+;,O%0/1,02!34'5#-)B+;,# r 6!)!#–,¨i-+G%02 r 6!,7P < +;F¿)!/1, ¯=r +gF l ) r +g)!/ µ ´ ­5¯ ´ ° y^· FG+;3Àb½ƒ+g/76 H¹`c< +-FÁ#XF–2B)$#-6!h7#±"$#-%0#X2BFM# C #-,(/ƒFa# r ,J/¤ež'¨/76B,¨# H²\H ˜B‰¾¡ † )YP²"³ŠfP’+ C ' l F H ,(/O%0/7,(2!39'¨#-)!+;,'¨#-6’'¨+!P


45!6©77ÂÃ98Ä;À=?2!6


45!6©77ÂÃ98Ä;À=


ƒ ºOQPSRUT7ÂÃVÄ;ÀXWÆÅYFZRÃDVmÂ[PÇ{Ä\ZYŽÇƒÈ¡Z]O“ÃQZ[ZÂ\YFZCWl F "$#-%0#M+;,'7^D”8^9,/1,('02!)$#-)!+-,7Pm+•6!j¯ /13U)!/±'¨/7+-%7^ #a ‚ · ²\H ˜B‰¾¡ 6$i-+Ÿ#-"B%0/7,(/76’'¨+-2 C +;6!,U#-F%(/7,02B39'5#&)!+;, † )B/7, ¯ ^9+ÆF l )[^9+ ®-ÎB­5¯-ª°`_ · Fa+;3 Šfb ›6’'0%0/1'¨#-6’'¨+!PFa/13<strong>DE</strong>!+;%0#-6!)!+ H ,0/`+ < +;6 a(2!6’'0+Æ)!/#&,0/ H”²‹H ˜B‰¾¡ † )YP²"³Š¤PR+;,–%(/7,02B39'5#&)!+;,–FG+;,('0%¨# ¯ #-F H ,0/a"!%0”Te^DFG+;,}#-+;, ¯ #-39+;%0/1,–/fe^"W/7%7^9Fa/16’'5#-^9,7bCC '/^D)B+;,7Pƒ)!/7,'5# < #-F H ,0/Ø+;, Ä 6[^9+;6!,k)!+;,Ÿ'/^9”8^D,MFM#-^9,Ÿ,7^9Fa"!39/7,1PFG/1'5#&6!+-'/^9+;3/½+;,k%0/7,(2!39'¨#-)!+;,k+/f'5#-6!+&'/^D+-3P < +;FÉ)!/1, ¯ ^D+-,{# C ,(+;3D2B'0+;,X)!/ŸÏ ­5-Î[°_ · FG+;3/ Ë ­¤µ-«k°_ · FG+;3PU%0/1,0"W/ < '7^¯ #-FG/76’'¨/&b]ŒC ,0/7% ¯ #-hTi-+G#-6’'0/7%7^9+;% ļ ¯&S 3b^D)$#}"!#-%¨#{+;,Ð+;2^'¨%0+-,.'/^D”-^D,7P^"n+-^D,.FG/7,(Fa+g#-"B%0/7,(/76’'5#&6!)!+G)!/7, ¯ ^9+;,# C^H+l7< 2!3 #-,1P,(+;3D2B'0+;,KFa#-^9+;%0/1,7P;/1,('¨/1,#-^D6B)$#,¨i&+XFG/76B+;%0/1,R@2!/Ð+“/7%(%0+“/fe^"W/7%c^DFG/76’'5#-3ÀbRcU#-%¨#L/1,('5#&,JFa+;3+ ?/1%0/16'0/7FG/76’'¨/)$# C #-,(/ ²‹H ˜B‰¾¡ † )YP²"³Š¤P’@ž2B/L#-"!%(/7,(/76’'5#X%0/7,(2!39'¨#-)!+;, < +ž/7%(/76’'¨/1, < +;F +;, ¯ #&3D+;%(/7,/fe^"W/7%7^9Fa/16’'5#-^9,7b›J,('0/7,Ÿ%(/7,02B39'5#&)!+;,ŸFG+;,('0%¨#-F@2!/-Pe^D8;2!#-3DFG/76’'¨/["$#-%0#ª+;,Ÿ#-3 < +ž”8^D,a/7,'¨2!)$#&)!+;,7Pƒ#f^D6 < 3D2B,¨i-+ª)!#+;%0%(/73 #&hTi-+k/739/1'0%0:;6[^ < #Ÿ6$i-+ l ,02BV < ^D/16’'¨/-PU,0/16!)!+`6B/ < /1,0, S %7^9+`+]#-2!FG/76’'¨+[)$#Ÿ>?2!6!hTi&+])!/ C #&,0/-b


çT÷1øÀù;úfû ü/\ý;ÿ¤üfþ ¢-ÿ¡¢õ=öçT÷1øÀù;ú¤£Ðû¦¥ 樧© ü/ ¢-ÿ¤ü/ ;ÿ¡¾ýõ=öq¤kX ãaì‹çT÷1øÀù;úfû ü/&þ -ÿ¡¢ ü/ ¾ý$ªü¾ü ¢-ÿ%(õçT÷1øÀù;úfû ü/ ‹þ&ÿ" ;ÿ¡¢õ=öçT÷1øÀù;ú¤£Ðû¦¥ 樧© ü/ ¢-ÿ¡‹þ üTÿ¡‹þõ=öq õ$# kX ãaì‹çT÷1øÀù;úfû ü/\ý¾ý-ÿ¤ü ü/ ¢$)-ÿ¡ ;üTÿ¡;üõçT÷1øÀù;úfû ü/ !’ÿ(þ¾þ ‹þ&ÿ¡ ¢õ=öçT÷1øÀù;ú¤£Ðû¦¥ 樧© ü/ ‹þ&ÿ¡¾ý -ÿ¡¾ýõ=öq õ$# õ# kX ãaì‹çT÷1øÀù;úfû ü/\ý¢ -ÿ"¢ ü/ ¢ $)-ÿ¡ ü-ÿ¡¾ýõçT÷1øÀù;úfû ü/ ¾ý-ÿ¡¢ ¢ -ÿý¢õ=öçT÷1øÀù;ú¤£Ðû¦¥ 樧© ü/ ‹þ&ÿ%¢ -ÿ%¢õ=öçT÷1øÀù;ú¤£Ðû¦¥ 樧© ü/ ¢-ÿý¢ -ÿý¢õ=öq õ$# õ# õ$# k ãaì‹çT÷1øÀù;úfû ü/ ¢-ÿ¡¢ ü/ 0)-ÿ¡ ;ÿ¤üãaì‹çT÷1øÀù;ú¤£Ðû¥ 樧© ü/ ¢-ÿ¡! -ÿ¡!õõ=ö çT÷1øÀù;úfû ü/ ;üTÿ¡ ¢õ=ö çT÷1øÀù;ú¤£Ðû¦¥ 樧©r î um2 ê5â"354 åéTæ’á¾âJê768©!ê/9Ôà;:Nê¨ß\åé7àIâá[?@+-ú7AB> rtô?u C ê5â%E&àIáLër í uqp é!4Iá9ê768©Bê/9Ôà;:Nê¨ß&åé!4WßXrTáNæ;àIâ"©!áTß5s;E‹ê/4t>ƒ ¹OQPSRUT7ÂÃVÄ;ÀXWÆÅYFZRÃDVmÂ[PÇ{Ä\ZYŽÇƒÈ¡Z]O“ÃQZ[ZÂ\YFZC /73 # ‡ bx˜BÚ}Û#-39+;%0/1,±)B/•#&V$6`^D)$#-)B/a"W+;%X"!%0”-'0+;6 < #-3 < 2!3 #&)!+;,N/M/¤eB"W/7%c^DFG/76’'5#,^D,7PK#_-Ü ¹`Ý /`‰U#/)!/1, ¯ ^D+–# C ,0+-3D2B'0+ † /1F °`_ · Fa+;3 ŠR"$#-%¨#X+;, Ä 6[^D+;6B, < +;%0%(/7,0"W+;6!)B/76’'¨/1,O#-+;,'/^D”-^D,/7,'¨2!)$#&)!+;,7b#&'0Fãaä¨åá-æ’á\ç7èJéTâê ë*ìzí?î(ï²í ë=ìdðˆñò r î u ó}rtô?uÞß’àIáTßâãaì‹çT÷1øÀù;ú¤£Ðû¥ 樧© ü( -ÿ¡¢ ý-ÿ¡¢èRù ÐìUçT÷1øÀù;úfû ü/ ¾ý-ÿ¡¢ -ÿ%(èRù ÐìUçT÷1øÀù;ú¤£Ðû¦¥ 樧© ü/ ¾ý-ÿ¡¢-ÿý¢ãaì‹çT÷1øÀù;ú¤£Ðû¥ 樧© ü/ ¢-ÿ¡¢ üTÿ¡¢èRù ÐìUçT÷1øÀù;úfû ü/ ;ÿ¤üfþ þ&ÿ¡¢èRù ÐìUçT÷1øÀù;ú¤£Ðû¦¥ 樧© ü/&þTý-ÿ¡¢ü¾üTÿ¤üfþãaì‹çT÷1øÀù;ú¤£Ðû¥ 樧© ü/ ‹þ&ÿ%( -ÿ%\þèRù ÐìUçT÷1øÀù;úfû ü/&þTý-ÿ(þ -ÿ¡ ;üèRù ÐìUçT÷1øÀù;ú¤£Ðû¦¥ 樧© ü/&þ-ÿ¡ ¢ý-ÿ(þ õ q # õ k ãaì‹çT÷1øÀù;úfû ü/\ý¢-ÿ¡ ‹þ ü/&þ$)-ÿ¡ ü-ÿ(þãaì‹çT÷1øÀù;ú¤£Ðû¥ 樧© ü/ ¢-ÿ¡ ‹þ ’ÿ¡ ‹þ¥èRù ÐìUçT÷1øÀù;úfû ü/&þ¾þ&ÿ¡¢ üTÿ"&þèRù ÐìUçT÷1øÀù;ú¤£Ðû¦¥ 樧© ü/&þ -ÿ¡ý-ÿ¤ü1õ=ö çT÷1øÀù;úfû ü/ !’ÿ%( ¢-ÿ¡;üèRù ÐìUçT÷1øÀù;úfû ü/&þ -ÿ¡;ü þ&ÿ¤üèRù ÐìUçT÷1øÀù;ú¤£Ðû¦¥ 樧© ü/&þ-ÿý;üý-ÿ¡¢ü/ ¢-ÿ"\ý õ q õ$# ¥ k õ õ q ãaì‹çT÷1øÀù;úfû ü/ ¾ý-ÿ¡¾ý l r í uãaì‹çT÷1øÀù;ú¤£Ðû¥ 樧©ü/&þ¾þ&ÿ%èRù ÐìUçT÷1øÀù;úfûü/&þ!;ÿ%‹ýÐìUçT÷1øÀù;ú¤£Ðû¦¥ 樧© ü/\ý‹þ&ÿ¡‹þèRùçT÷1øÀù;úfû ü/ ¢-ÿ¡! ü-ÿý¾ýõ=öçT÷1øÀù;ú¤£Ðû¦¥ 樧© ü/ !’ÿ¡¢ -ÿ¡¢õ=ö¥ õ q q k ãaì‹çT÷1øÀù;úfû ü/\ý;ÿ¡! ü/&þ$)-ÿ¡ ü/’ÿ%‹ýãaì‹çT÷1øÀù;ú¤£Ðû¥ 樧© ü/&þ¾þ&ÿ¤ü -ÿ¤üèRù ÐìUçT÷1øÀù;ú¤£Ðû¦¥ 樧© ü/&þ!;ÿý¢ÐìUçT÷1øÀù;úfû ü/&þ-ÿ(þ ;ÿ¡¢’ÿ¡;üèRù


+;6 H ?/7%0/16!hT#ª/16’'¨%0/¼+;,#-39+;%0/1, < #&3 < 2B3 #-)!+X/L%(/T#-3 l %0/13 #&'7^¯ #-FG/76’'¨/O2!6[^4>?+;%0FG/-Pž"W+;%$^9,0,0+BPB+;,>ˆ#&'¨+;%(/7,.)B/L/7, < #-39+;6$#-FG/76’'¨+¯< +-Fa"W/76!,0#-%Ð/7,'¨/1,ƒ/1%0%0+-,,c^9'0/7F S '/^ < +;,¦º ‚Àb,0i-+g2!,¨#-)B+;,ƒ"!#-%¨#ƒFa#`+;2^'¨%¨# ¯ #&6'¨#-8;/1F l @ž2B/Ÿ+;,}>ˆ#&'0+;%0/1,})!/•/1, < #-3D+;6!#-Fa/16’'¨+_"W+^)B/7F ,0/7%})!/1'0/7%0Fi^D6!#-)!+;,< /1%('¨+Ÿ8-%02!"W+Ÿ)!/–FG+;3 l1< 2!3D#-,/{,0/7%(/7Fš#-"!3h^ < #-)B+;,/1F ,c^D,('0/7Fa#-,“#-6 S 3D+;8-+;,Fa#-^D, < +-F H"$#&%¨#M2!F< #&3D+;6$#&Fa/16'0+–#-"B%0+;"!%c^ #-)B+;,J'¨/7FÁ%(/ < / C ^D)B+"!39/fe^+;,1bJcU+;%^D,'¨+!Pž#±)B/1'¨/1%0Fi^D6$#&hTi-+X)!/ƒ>ˆ#\'¨+;%(/7,)!//1,˜BP º ‡ ‚Àb8;%0#-6!)!/N#\'¨/76BhTi-+G6$#{3h^4'¨/7%0#&'¨2B%¨#ƒº< #-%U/7,('0/.%0/ < 2!%(,0+!P;>?+-^^%(/T#-3b^µ #&)!+ƒ2BFÙ/1,('¨2B)!+“"$#-%0#)!/1'0/7%(F„^96$#-hTi&+L)!+LFG/739E!+;%cK#&%¨#/¤eB/1Fa"B3h^9V< #-3D+-6$#-FG/76’'¨+{"$#&%¨#}+ ?+8^ƒ%0/T#&3h^µ #-)!+»6!+¨6!j¯ /73ƒ)!/_'¨/1+;%7^D#ª¹`c · ²‹H ˜B‰¾¡ † )YP²"³Š¤PÐ@ž2B/)!+-^D,#-"B%0/7,(/76’'¨+-2[+-,*FG/73<strong>DE</strong>B+;%0/1,*%0/1,02!34'5#-)B+;,7PB'¨#-6’'¨+–"!#-%¨#}+-,Ð#-3 < +^”-^D,@ž2!#-6’'¨+{"$#-%0#}+;,*'7^D”8^9,7bR¥€#¢a(2!,('0/)!+[>ˆ#&'¨+-%})!/a/7, < #-3D+-6$#-FG/76’'¨+[>?+8^>?/'^9'0+_#&'0%¨# ¯;l ,–)!/M2BF…^96 < %(/7FG/76’'¨+`)!/x†BP‡†5ˆ]62!Fa#[>ˆ#,^4eB#])!/†g#Ÿ‰;Px˜8†Bb †BPºU# C /73D# ‡ b ‡ FG+;,('0%¨#G+;, ¯ #-39+;%0/1,)!/±ŒLc < #-3 < 2!3D#-)!+;,/},(/72!,%0/7,("n/ < '7^¯ +-,“)!/7, ¯ ^9+;,/1F %(/ HŒ3D#-hTi-+ƒ#-+ ¯ #-39+;%d/fe^"n/1%7^9Fa/16'¨#-3ž/7FÊ>?2!6!h7i-+“)!+>ˆ#&'0+;%d)!/*/1, < #&3D+;6$#&Fa/16'0+!bR›J,'¨/7,J)!#-)!+;,UFa+;,'¨%0#-F@2!/Ð# ¯ #&%7^ #&hTi-+ƒ)!+L>ˆ#&'¨+-%K)!/./1, < #-3D+;6!#-Fa/16’'¨+>?+;%(6!/ < / ¯ #-3D+-%0/7,U)!/.ŒcØF–2`^9'¨+ƒ,¨#&'7^D,>ˆ#&'¨”;%c^D+;,1P < +;F


² †OQPSRUT7ÂÃVÄ;ÀXWÆÅYFZRÃDVmÂ[PÇ{Ä\ZYŽÇƒÈ¡Z]O“ÃQZ[ZÂ\YFZ¯ ^D+kFG/76!+-%“@ž2B/[‰ °_ · FG+;3Pn'5#-6’'¨+k"$#&%¨#k#-3 < +^”-^D,@2$#&6'0+]"!#-%¨#•'/^9”8^D,1b}cd+^)B/G,(/7%X#-6$#&3h^D,0#-)!+)!/1,d q ¥ d q¤d # ¥ d q¤‹ d qd # ‹ ‰W#\'¨+;%í?î(ï²í Œ /7, ¯ ^9+ ŒLc í?î(ï²í Œ /7, ¯ ^D+ ŒLc í?îïxí Œ /1, ¯ ^D+ Œc í?îïxí Œ /1, ¯ ^D+ŒLc­¤« Ï Ë Î Ë ®ž­5;¬ Ë Î^­5;¬ Ë µ-¯-ÎB­5;¯ Ë ¬B­5;¯ Ë µ Ë Ï ­¤« Ï ËT´ ­¤« Ï Ë7´ ¯’«^­¤« ´ ¯B­¤« ´Ï­¤«;µ Ë Î Ë Ï ­5 ´ ËT´ ­5 ´ Ë µ-¯ ´ ­5¯’® Ë-Ë ­5¯’® Ë µ Ï ¯B­ ´!Ë Ë ¬B­ ´!Ë Ë7´ ¯;ÎB­ ´ µ B­ ´ µÏ­5 Ï Ë Î Ï ^­5’µ Ë ®ž­5’µ Ë µ-¯;®^­5¯ ´ ¯^­5¯ ´ Ë µ Ï B­ Ë;Ë Ë ®^­ Ë;Ë Ë7´ ¯’µ^­ Ë µ «^­ Ë µÏ­5’µ Ë Î Ï Î^­5’µ Ë Ï ­5’µ Ë µ-¯ Ï ­5¯ ´ «ž­5¯;Î Ë µ Ï ÎB­5 Ï Ë Ï ­5 Ï Ë7´ ¯;¬B­5;µ µ^­5’µÏ­5¯ Ï Ë Î Ï ´ ­5’µ ^­5’µ Ë µ--B­5¯’« µž­5¯’« Ë µ Ï µ^­ ´ ¯ ¯B­ ´ ¯ Ë7´ ¯’®^­¤µ ´ ´ ­¤µ ´Ï­5¯’µ Ë Î Ï ®ž­5 ´ Î^­5 ´ Ë µ--ÎB­5¯; ¬^­5¯; Ë µ Ï ´ ­ Ë « B­ Ë « Ë7´ ¯ Ë ­¤®&¬ ¬B­¤®-¬Ï­ Ï;Ï Ë Î Ï;Ï ­5;¬ ´ ­5;¬ Ë µ- ´ ­5¯;¯ Ë ­5¯;¯ Ë µ Ï ®^­5’µ ÎB­5’µ Ë7´ ;¯B­5¯;® Ë ­5¯’®Ë­ Ï µ Ë µ-¯;^­5 Ë ®ž­5 Ë Ë µ-;®^­5¯;¯ Ï ­ Ï Ë Ë µ Ï Ë ­¤µ;® µ^­¤µ;® Ë7´ ;B­5Î Ï Ï ­5Î ÏË­ Ë Ï Ë µ-¯;Î^­¤«-¯ Ï ­¤«-¯ Ë µ- Ï ­5¯;¯ ®ž­ Ï Ë ËT´ ¯;¯B­ Ë ¯ ¬B­ Ë ¯ Ë7´ ’«^­¤®& Ï ­¤«;®Ë­ Ë µ Ë µ-¯ ´ ­¤«;« Ë ­¤®-¬ Ë µ;«&B­5¯;¯ ´ ­ Ï Ë ËT´ ¯;B­5;Î ®^­5;Î Ë7´ ’µ^­5¯-Î ®^­ Ï ´Ë­¤® Ï Ë µ-¯’®ž­¤« ´ ¬^­¤®-Î Ë µ;«-Î`x¯;¯ Î^­ Ï Ë ËT´ ¯’«^­¤µ;® Ë ­¤µ;® Ë7´ ´ ­5Î ´ ¬B­5¬;ÎË­¤®;µ Ë µ-¯ Ï ­¤« Ë µž­¤®-¯ Ë µ;« ´ ­5¯; ^­ Ï ® ËT´ ¯;ÎB­ Ë Ï ­ Ë Ë7´ ;¬B­5¬;® ´ ­5Î;Ë­5¬ Ï Ë µ-;^­5Î; «ž­5¬’® Ë µ;«-®^­5¯; Ë Ï ­ Ï ® ËT´ ¯ ´ ­5 ´ Ë ­ Ë Î Ë7´ Ë ­5¯-¯ ÎB­ Ï ËË8;%0#&V < #-Fa/16’'¨/-PU6$#Š‰Q^98;2!%0# ‡ b4‰;PK# ¯ #-%7^D#-hTi&+])!+])!/7, ¯ ^D+_/1FÉ>?2B6!hTi-+`)$# ¯ #-%7^D#-hTi&+])!+[>ˆ#&'¨+-%±)!//1, < #&3D+;6$#&Fa/16'0+!b×¥ C ,(/7% ¯ # H ,0/M@ž2B/•+_FG/73<strong>DE</strong>B+;%X>ˆ#\'¨+;%±)!/M/1, < #&3D+;6$#&Fa/16'0+_/76 < +;6’'¨%0#-)!+×"$#&%¨#`+;,#-3 < +ž”8^D,>?+8^R‰;P4‰¢†{/N"$#-%0#g+-,O'7^D”8^9,L‰;P4‰(ˆ^bC /73 # ‡ b ‡ ÚÛ#-3D+-%0/7,ƒ)!/g#&V$6`^D)$#-)B/{"n+;%"!%0”-'0+;6×+ C '7^D)!+-,L6!+k6!j¯ /73¹]c= · ²\H ˜^‰¾¡ † )YPx"$ŠfP < +;FU##-%c^ #-h7i-+–)!+g>ˆ#&'¨+-%.)!/N/7, < #-39+;6$#-FG/76’'¨+g)!/†^Pº †g#Ÿ‰;Px˜8† † †BP‡†5ˆ;Š/X)B/7, ¯ ^9+;,# C ,0+-3D2B'0+;, † °_ · FG+;3·Š¤b¯


20.0OQPSRUT7ÂÃVÄ;ÀXWÆÅYFZRÃDVmÂ[PÇ{Ä\ZYŽÇƒÈ¡Z]O“ÃQZ[ZÂ\YFZ ² ‰15.0CH 3O −CH 3CH 2O −CH 3S −CH 3CH 2S −Desvio da AP (kJ/mol)10.05.00.00.6 0.7 0.8 0.9 1.0 1.1 1.2 1.3 1.4Escalonamento‡ b9‰;ÚUÛ#-%7^D#-hTi-+X)!+±)!/7, ¯ ^9+{# C ,(+;3D2^'¨+X)$#–#&V$6`^D)$#-)B/ƒ"W+;%"!%0”-'0+;6M/1FÁ%0/73D#-hTi&+}#-+X>ˆ#&'¨+-%=)!/‰Q^98;2!%0#< #&3D+;6$#&Fa/16'0+g"$#-%¨#{+;, Ä 6`^D+;6!,Ð)B/±#&3 < +ž”8^9,*/“'/^9”8^D,.)B/±#\' l )!+8^9, < #-% C +-6!+;,7b/1,


²OQPSRUT7ÂÃVÄ;ÀXWÆÅYFZRÃDVmÂ[PÇ{Ä\ZYŽÇƒÈ¡Z]O“ÃQZ[ZÂ\YFZ¯ /1%7^9V < #-%d#Ð/1V < ^ A 6 < ^D#O)B+2B,0+O)!/J>ˆ#&'¨+-%0/7,m)B//1, < #-3D+;6!#-Fa/16’'¨+!P‹+.>ˆ#&'0+;%J‰;P4‰¢†*>?+8^’#-"B3h^ < #-)!+cK#&%¨#C /73 # ‡ bŽˆ^ÚdÛ#-3D+-%0/7,K)!/#&V$6[^9)$#-)!/Ð"W+;%J"!%(”-'¨+;6g+ C '/^D)B+;,J6!+N6!j¯ /73W¹`c · ²\H ˜B‰¾¡ † )YPx"$ŠfP;2B'7^D3b^µ #&6 HU#< #-3D+-6$#-FG/76’'¨+a‰;P9‰†X"$#&%¨#±+-,*#-3 < +ž”8^D,J/±‰;P4‰(ˆN"!#-%¨#X+;,'7^D”8^9,J/)!/1, ¯ ^D+-,.# C ,(+;3D2^'¨+;,)!+±+X>ˆ#\'¨+;%)!//7,‰ ‡ ¹ ˜BP‡†5ˆ ‰;P‡†5ˆ‰ ‡ º ˜BP4‰(ˆ ‰;P¹ ˆ‚6!+-,R#-3 < +ž”8^D,zFa#-^D, < +-Fa"!39/fe^+;,1P’#-,0,c^DF+-Fa+ƒ+ƒ>ˆ#&'0+;%=‰-P9‰(Ô>?+8^ž#-"!3h^ < #-)B+ƒ6!+-,K'/^9”8^D,1bK¥L,U%0/7,(2!39'¨#-)!+;,ˆ#&'0+;%O)!/}/1, < #&3D+;6$#&Fa/16'0+!P#G2B'/^93h^µ¯ ^D+kF l )[^9+•)[^9F„^96ž2`^D2`"!#-%¨# ®^­5¯;µa°_ · Fa+-3bXcK#-%0#Ÿ+;,L'/^9”8^D,1PY#•%0/1)!2!h7i-+k)!+k)!/7, ¯ ^9+kF l )[^D++Ÿ)!/1,6!/1,('0/}6!j¯ /73d)!/N'¨/1+;%7^D#BP$>?+8^ ´ ­ Ë;Ë °_ · Fa+-3b _ SG< +;F>?+8^U#-^96!)$#aFa#-^9,ƒ,c^D8;6[^4V < #\'/^¯ #BP$,(/ < +;FG"$#-%0#-)$# < +;F+;,“#&3 < +ž”8^9,7P³)[^DFi^D62[^96!)!+G)!/ ¬B­¨¯;¬a°_ · FG+;3"$#&%¨#Ë ­ ´ μ°_ · Fa+-3bŽcd/7% < / C / H ,0/_@2!/]+»2B,0+ª)!+Ø>ˆ#&'¨+-%G)B/]/1, < #&3D+;6$#&Fa/16'0+»"W/7%(F„^4'¨/k%0/fV$6$#-%+’#Ÿ"!%0/ < ^D,0i-+!b Cl F )!/ ¯ / H ,(/_+ C ,(/7% ¯ #&%•#¼"n/1@ž2B/76$#ª#&Fa+;,'¨%0#-8;/7F < +;6!,c^D)!/1%¨#-)!#Bb Œ3 l F )[^9,0,0+BP*+;,g>ˆ#&'¨+-%0/7,cd+;%%(/7,02B39'5#&)!+;,N)!/g"!%0+-"!%7^9/7)$#-)B/7,N/739/1'¨%(:;6[^ < #-,1P < +;FG+[#&V$6[^9)$#-)!/g"W+;%“"!%0”&'¨+;6YP < +;F


¥e” ¨§¢=£Ê!­–•p£qv 1­£!£ a¦x­ ¬ £ ¢=¢= v £ ¥ ©e­˜—š œ©¤­Ð!­0Qš¡ ©¢=£?S 3b^D,(/7,X%0/T#&3h^µ #-)$#-,X#-6’'0/7%7^9+;%0FG/76’'0/ C #&,0/!^D#-F H ,0/g,(+;Fa/16’'¨/M6!#`@2$#-3h^9)$#-)!/g)!+


C /73 # ‡ b² ÚJ›J6!/7%(8^ #&,./739/1'¨%(:;6[^ < #-, † /1FœE$#&%('¨%(/7/TŠ=)!+{FG/1'5#&6!+;3³+ C '7^D)$#-, < +;F )[^4>?/7%0/16’'¨/7,ÐF l '0+ HU#< +;6 a(2!6’'0+;,ƒ)B/ C #-,0/N/N+;,O%0/1,0"W/ < '7^¯ +;,'0/7FG"n+-,Ð)!/ d c † /7F—Fi^D62B'0+;,5Š¤b)!+-,/)YP²"³Š ¡ † )YP²"³Š


ˆ ²< /76’'¨/1Fa/16'0/-P$+–2B,0+{)!/LF l '0+^)B+;,й`cJ6Ÿ'¨/1F #&2!Fa/16’'5#-)!+}/7F )!/1'0%7^DFG/76’'0+{#-+;,.F l '0+^)B+;, d Ò5P§O/S +GF l '¨+ž)!+ d d ‹ Œ † ŠfP < +;F¿2!Fa# C #-,0/±,0+-V!,('/^ < #-)!#BP³"n+ž)!/N8;/7%0#-%%0/7,(2!39'¨#-)!+;,"$#-%0#G"B%0+ H_¯ +;3¯ /16!)!+G/76!/1%088^D# < +;Fœ2!F—6!j¯ /73Ó)!/“"!%0/ < ^9,¨i-+g)!/ Ï ‡ °_ · FG+;3ÀPB"$#-%0#{#{FM#-^9+;%7^D#"!%c^D/1)$#-)!/1,Ð/76OQPSRUT7ÂÃVÄ;ÀXWÆÅYFZRÃDVmÂ[PÇ{Ä\ZYŽÇƒÈ¡Z]O“ÃQZ[ZÂ\YFZ/16'0%0/f'5#-6’'¨+BP;+;,K/1,('¨#-)!+;,R/¤e < ^9'¨#-)!+;,U6$i-+L,0i-+ C /7F€)!/1, < %c^9'0+;,K"W+;%KF l '0+^)B+;,U)B/."n/1%('02!% C #&hTi-+Ǻ ˆ ‚Àbcd+;%È^D,0,(+!P.#¼/7, < +;39E$#¼)!+»F l '0+^)B+Ø)B/7"W/76!)!/k'5#&6'0+»)B+»,c^D,('0/7Fa#Ø@2$#&6'0+©)$#¼"!%(+;"!%7^9/7)$#&)!/k/7F/1,('¨2B)!+!b« Œ"W/7,0#-%d)!/*2!FÊFa#-^9+;%Ó'¨/1Fa"W+ < +;FG"!2B'¨# < ^9+;6$#-3ÀP\+-,U%(/7,02B39'5#&)!+;,d+ C '/^9)!+;,z6!/1,('¨/=6!j¯ /73ÃÈÃÈÅmÆ)!/N'¨/1+;%7^D#{6$i-+a>?+-%¨#-F—FG/739E!+;%(/7,O)!+M@2!/±+;,+ C '/^9)!+;, < +-F¿+aF l '0+^)!+M¹`c ‡ bOcd+;%ƒ/¤e^/7FG"!3D+!P$6B+/13ž)B/='¨/1+;%7^D# d d ‹ Œ · ²\H ˜B‰‹¡ † )YP²"³Šm+ ¯ #-3D+-%d)!#ƒ/76B/7%08-^ #>?+-^ H ‰;‰(ˆžP ‡ † ‡ º E!#-%('0%0/7/&P < +;F'¨/1Fa"W+)!/6!j¯3 < 2!3D+Á^D8;2$#&3n#Ȉ ¹ P¹ F„^96ž2^'¨+;,1b _ S 6!+{6!j¯ /13Ó)!/'0/7+;%c^ #{¹]c ‡ · ²\H ˜^‰‹¡ † )YP²"³ŠfPž+ ¯ #-3D+-%=)$#–/16!/7%(8^ #?+8^ÓFa/13<strong>DE</strong>!+;% † H ‰-‰(ˆ^P ‡ ‰;‰ ¹ E!#-%('0%0/7/TŠ./X+{'0/7FG"n+g)!/N"!%(+ < /7,¨#&Fa/16'0+G>?+-^YFa/16!+;% †?‡ ÜBP² Fi^D62B'0+;,5Š¤b²7ÉǼ(« ›J,('0/*F l '¨+ž)!+#-"!%(/7,(/76’'¨+;2}%0/7,(2!39'¨#-)!+;,dF–2[^4'¨+ C +;6!,7P&,0/1Fa/13<strong>DE</strong>$#-6’'0/7,U#-+;,d+ C '/^9)!+;,ÃÈÃÈÅmÆ+;Fœ+{F l '0+^)B+g¹`c ‡ b½ƒ+{/16’'5#-6’'¨+BP!"$#-%0#–@ž2!#-3D@2!/1%.2!F )B+;, < +-6 a(2!6’'¨+;,Ð)B/ C #-,0/&P!+–'¨/1Fa"W+–)!/?+8^ < +;6!,7^9)!/7%0# ¯ /739Fa/16’'¨/XFM#-^9+;%7bd'¨/1%0FG+;,R)!/O"!%(/ < ^D,¨i&+X)B+ ¯ #-39+;%R)$#“/16!/7%(8^ # < #-3 < 2!3 #-)!#BP;2B'7^D3h^µ #-6B)!+L2!Fa#>?2!6!h7i-+N)!/ C #-,0/›JF)!/'5#-Fa#-6!EB+}F l )[^9+!P+;,*%(/7,02B39'5#&)!+;,*+ C '/^9)!+;, < +;6 < +;%0)!#-F < +;F #},(/78;2[^96’'¨/+-%0)!/1Fœ)!/ƒF l '¨+ž)!+;,< ^9'5#&)$#–6$#g3h^9'0/7%0#&'¨2!%0#xºj² ‚ÀÚpŠÊ¯Ë ÌÎÍ ®Ï oÐÑUÒ’Ó oXoÁÑUÒ’ÓÔÌÎÍXíÓ oXo½ÑÕÒ ¾zÖ ¿†ˆ‡ bt;Š#–)$#-, ¯ / µ /7,1P ?2!6!h7ž/7,½#GFM#,^D+;%c^C #&,0/X,0+-V$,'/^ < #-)$#&,7P³+;,O%0/1,02!34'5#-)!+-,ƒ#,^D6!)$#{6$i&+a,0i-+a,0#&'/^9,(>ˆ#&'0”;%7^9+;,7P < +;F—8-%¨#-6!)B/7,)!/7, ¯ ^9+;,/7F)!/%(/73 #&hTi-+±#-+;, ¯ #&3D+;%(/7,/fe^"n/1%7^9Fa/16'¨#-^D,1b d +;6’'¨2B)!+!Pž/7,('0/7,Ð/1%0%0+-,*,0/18;2!/1F 2BF < /7%'¨+–"$#&)!%¨i-+BP^+±@ž2B/"W/7%(F„^4'¨/+–2!,0+{)B/ƒ>ˆ#&'0+;%0/1,.)!/ < +;%0%(/7hTi&+!b ‹ /16!)!+g#-,(,7^DF[P


²~²OQPSRUT7ÂÃVÄ;ÀXWÆÅYFZRÃDVmÂ[PÇ{Ä\ZYŽÇƒÈ¡Z]O“ÃQZ[ZÂ\YFZ,0/7%Ð2B,¨#-)!+-,.F l '¨+ž)!+;,.FG/76B+;, < +-Fa"!39/1'0+;, † < +;FG+g¹`c ‡ / d d ‹ Œ Š¤P$@2!/ < +;F C #-,(/7,ÐF lfH"W+^)B/7F"W+;% l F < +;F—2!F < 2!,('0+ < +;FG"!2B'5# < ^D+-6$#-3YFG/76!+-%1×)[^D#-,7Pž>?+;%06B/ < /1F %(/7,02B39'5#&)!+;, < +;F "!%(/ < ^D,¨i&+{)!/N#-3D8-2!6!, °_ · FG+;3Dº ˆ(‚b¹`#&,Ð,0/7% S @ž2B/“6$i-+{/fe^9,('¨/2!F FG+^)!+»)!/_,(/_+ C '0/7%M%(/7,(2!39'¨#-)!+;, < +;F #©@2$#-3h^9)$#-)!/[)!+ª6Bj¯ /13 d d ‹ Œ † Š · #-2


çéè ©¤­Ð!­ ƒ¡©B"ê©­ !£oë–¥c£E¦[ì§Ð+;FG+¨+ C ,(/7% ¯ #-)B+Æ6$#¨U# C /73 # ‡ b² P ?+-%¨#-F < +;6 < 392!jD)B+;,7P.+»@2!/_6$i-+Ø>?+8^²^ºOQPSRUT7ÂÃVÄ;ÀXWÆÅYFZRÃDVmÂ[PÇ{Ä\ZYŽÇƒÈ¡Z]O“ÃQZ[ZÂ\YFZ؃Ù/ÚÛKÜÝ'Þ'ßàÜÁá0âã ßàã ä å0æqãi߃ã+;6 a(2!6’'¨+-,Ÿ)!/ C #-,(/Ø,(+-V$,'/^ < #-)!+;, < +;6!,(+;Fa/1F 2BF /739/ ¯ #-)!+ª'0/7FG"n+ < +;FG"!2B'5# < ^D+-6$#-3PÐFG/7,(Fa+?+8^z#-"!3b^ < #-)$#g#-+;,ƒ#-3 < +^”-^D,/{'/^9”8^D,“)B/M#&' l )!+8^D, < #-% C +;6!+;,N/G,0/12!,±%(/7,("n/ < '/^¯ +;, Ä 6[^9+;6!,7Pd#ŸV$F)!/G%0/1"!%0+ž)!2 µ ^D%N+;,N%0/1,02!34'5# H/73z)!/N'¨/1+;%7^D# d d ‹ Œ † Š · #-2!8 H


OQPSRUT7ÂÃVÄ;ÀXWÆÅYFZRÃDVmÂ[PÇ{Ä\ZYŽÇƒÈ¡Z]O“ÃQZ[ZÂ\YFZ ² ¹C /73 # ‡ bº Ú›J6!/1%08^D#-,“›$í¤Pm› # /{› q îm/76!/1%08^D#•#-"!%(+Tè ^9FM#&)$# † ›J@³bY˜^b ‡ Š/–/76!/1%08^D#•6$i-+Ÿ#&"!%0+Te^ HU#† + C '/^D)!#X6!+±6!j¯ /73 d d ‹ Œ † Š · #&2!8 HÔ?+8^m2B'/^93h^µ< #-3 < 2!3D#-)!+;, < +-F¸+-,F l '¨+ž)!+;,ƒ#-"!%(+Tè ^9FM#&)!+g/}6$i-+M#-"!%(+¾e^9FM#-)B+a/±,0/72B,#&V!6[^D)$#&)!/±"W+;%"!%0”&'¨+;6%(/7,0"W/ < '/^¯ +;,)!/7, ¯ ^D+;,O,¨i&+a#&"!%0/1,0/76’'¨#-)!+;,6$#gK# C /73D# ‡ b¹ b½# < +;FG"$#-%¨#&hTi-+•/16’'¨%0/{+-,“%0/7,(2!39'¨#-)!+;,)!/{#&V$6`^D)$#-)B/–"n+-%L"!%0”&'¨+;6×+ C '/^D)B+;,7Pn6!+-'5# H ,0/}@ž2B/a##-"B%0+Te^DFa#-hTi-+ƒ"!%0+-"n+;,'5#“#-"B%0/7,(/76’'5# C +;6!,J%(/7,02B39'5#&)!+;,7P-"n+ž)!/76B)!+N,0/7%#&"!3h^ < #-)$#"$#-%0#


C /73 # ‡ bxÜBÚ.Û#-39+;%0/1,ƒ)!/}#&V$6[^9)$#-)!/1,"W+;%"!%0”-'0+;6 < #-3 < 2!3 #-)B+;, < +;F +•F l '0+^)!+-,#-)`^9'/^üö;+!P³/¤eB"W/ HU#C ,0+-3D2B'0+;, † /7F °`_5û Fa+;3 Š"$#&%¨#g,7^D,'¨/1FM#-,Ð,c^DFi^D3D#-%0/1,7b%c^DFG/76B'¨#-^D,=/X)B/7,cöX^9+;,# ‰ ‡ õ-˜BP‡ô8ô ‰ ‡ ô-ó ò ‰¾ ˆžPNô8ô‹ ¥¬ý ‰‹-ó5ˆ^P ‡ Ü ‰‹-ó;‹‰T˜ ˜^P ‡ Üd ¥ d ‰(ˆ-˜;ÜBPxÜB‰ ‰(ˆ;-ô ò óBP‡ó ‰T˜BPtÜ^‰ò# Š # d ¥N¥ ‰ ‡ ‰(ˆ^P‡ô8† ‰ ‡ -† ò ÜBPt ‡ P ‡ †‹Ó†~dî u §/1,02!34'5#-)B+;,Ð/fe^"W/7%7^9Fa/16’'5#-^9,Ð+ C '/^9)!+;,Ð6$#i§O/1>bm‡õ^‰!‚ÀbrŒ /7,cöX^9+aŒ C ,0+;392B'¨+BÚ‚’‘’“ŒLc í?î(ï²í H Œc ðÀñò`÷ br‘ô?u‚ô;ÜOQPSRUT7ÂÃVĘøXWÆÅYFZRÃDVmÂ[PÇ{Ä\ZYŽÇƒÈ¡Z]O“ÃQZ[Zúù\YFZŒ3 l F )!+;,X#-3 < +^”-^D,/{)B+;,“'/^D”-^D,L/1,('¨2B)$#-)!+;,1Pm>?+;%¨#-F /7, < +;39E[^D)!+-,N#-3D8;2B6!,“,7^9,('¨/1FM#&,“,7^DFi^D3D#-%0/1,< #&hTi-+_)!#Ø#&"!%0+Te^DFa#-hTi&+×#-)[^4'/^bö&#`/k"W+;,('0/7%c^D+;% ?+8^Ð#-"B3h^ < #-)$# < +;F,(2 < /1,0,0+a"$#-%0#g/1,('0/±8;%(2!"W+G)B/XFG+;3 l7< 2B3 #-,1bŒLc í?îïxí ŒLc r î u ðÀñò6`^D+;6rtô?uq ‰(õ-˜8óBPNõ-ó ‰(õ ‡ ˜ ò ^PxÜ ‡ P‘;¥“ ‰¢ô’-óBPt-ó ‰¢ô;˜-˜ ‡ PŽõ;d‹[d ‰ ‡ ô’^P ‡ † ‰ ‡ ô-Ü ò ‰¢õ ô^PNô8†d q ¥ dd ‰(õ^‰¢†BPt8ˆ ‰(õ-†;˜ ò óBP ‡ õžP‘8ˆ#q¤‹`d # ‰¢ô ‡ †BPxÜ8ô ‰¢ô;˜;˜ ò ôBPx˜ õžPtÜ8ôd# d d ¥N¥ ‰ ‡ ˜’^P4‰¾˜ ‰ ‡;‡ † ò ‰¾ õžPNó5õdd q¤d # d ¥N¥ ‰ ‡;‡;‡ P4‰¢ô ‰ ‡ ˆ ‡ ò ÜBPt Ü^PNó ‡d q¤d ¥N¥ ‰ ‡;‡ ôBP ‡ ô ‰ ‡ ˆ-ô ò ÜBPt Ü^PŽˆ ‡d q¤d ‹`d # ‰ ‡ ˆ-ÜBP ‡ õ ‰ ‡ ô-Ü ò ‰ ‡ Ü^PŽˆ-˜d # d ‹ ‰ ‡ ˆ^‰;P4‰(õ ‰ ‡ ˆ,ô ò ‰ ‡ ‡ PNó;˜d q¤‹ ¥ q ‰¾˜;˜’^Pt-ô ‰¾˜ ‡ ˜ ò ÜBPt ‰†BPŽõ ‡d q¤‹ ¥ ‰ ‡ ÜB‰;P ‡ õ ‰(ˆ-†; ò ‰T˜ ‰†BPŽˆ&˜d q¤‹ ¥ # d # ‰(ˆ-˜ ‡ Pt-Ü ‰(ˆ-˜B‰ ò ÜBPt ˜^P‘-Ü


õ-†çéèúþÿ ÿŽ ƒ þ "ê ÿ ¡ f룢¤ ¦¥[쨧©§ þ ¥§qê è ¡ ç úÿ v ÐOQPSRUT7ÂÃVĘøXWÆÅYFZRÃDVmÂ[PÇ{Ä\ZYŽÇƒÈ¡Z]O“ÃQZ[Zúù\YFZÿ ÿñþ ¢ ¨§+;6!,c^D)!/1%¨#-6B)!+M+a"!%0+ < /1)[^DFG/76’'¨+a)!/7, < %c^9'¨+a6$# ‹ /7hTi&+Ÿ˜Bbx˜BP$>?+8^z2B'/^93h^7#-)!+g+MF l '0+^)B+M#-)`^9'/^üö;+d)!/Ÿ/16!/7%(8^ #¼#&'0%¨#ö l ,a)B/[¥N½Ò¥N¹< +;FÖ"!,(/72!)!+-"n+-'0/76 < ^ #-3Ð"!#-%¨#_+ ?+-%¨#-F < #-3 < 2!3 #-)!#-,[#-,_#&V!6[^D)$#&)!/»/13D/f'¨%0:-6[^ < #-,]"!#-%¨#+;,],c^D,'¨/7Fa#-,]6!/72B'0%0+;,q\†~d # Š"ð d # ¥/ d q\†~d # Š%ð d # ‹ b\›J,('0/7,U%0/7,(2!39'¨#-)!+;,d,¨i&+#-"B%0/7,(/76’'5#&)!+;,K6!#ƒU# C /13 # ‡ b4‰;‰;bdl )[^D+;,J"!#-%¨#N+;,=#-3 < +^”8^9,J/Ð'/^D”-^D,R>?+;%0#-F †BP‡†5ˆ“/ Û¦/e†BP‡† ‡ / Û–P%0/1,0"W/ < '7^bö&#-FG/76’'¨/&bJÒÔ,('0+¥L,)!/7,¡öX^D+;,=FFG+;,('0%¨#G@ž2B/–+•F l '¨+ž)!+a/7FG"!%0/18’#-)!+a8;/7%0#M%0/1,02!34'5#-)!+-, < +;FC +’# < +;6 < +;%0)&6 < ^D# < +;F¸+;,ƒ)$#-)!+;,/¤eB"W/7%c^DFG/76’'5#,^D,7b


C /73 # ‡ b9‰†BÚ×Û#-3D+;%(/7,a)!/¼#&V$6[^9)$#-)!/1,•"W+;%M"!%(”-'¨+-6 < #-3 < 2!3D#-)!+;,a/_/fe^"W/7%7^9Fa/16’'5#-^9,M/×)!/1,cöX^D+;,U#C ,0+;392B'¨+;, † /7F °_5û FG+;3·Šƒ"!#-%¨#k+;,#-6[^D+-6!, d q\†~d # Š%ð d # ¥ / d q\†~d # Š"ð d # ‹ † 6‘ † H#6 d q\†|d # Š"ð d # ¥ d q\†|d # Š"ð d # ‹ ‚‰(ˆ8õ^‰-PtÜ’ ‰(ˆ8õ; ò ˆžP ‡ †BPN†-ó ‰ ‡ ó-˜BPŽˆ,ô ‰ ‡ ó; ò ÜBP‘ ‰;PŽˆ,ô‰‰(ˆ-ô;Ü^P‘ ‡ ‰(ˆ-ô5ˆ ò ó^PNó ‡ P‘ ‡ ‰ ‡ ó^‰;Pt˜-ô ‰ ‡ õ-ˆ ò ÜBPNô ôBPt˜-ô˜‡ ‰(ˆ-ô8ó^PNô5õ ‰(ˆ-ô5ˆ ò ó^PNó ˜BPNô8õ ‰ ‡ ó-†BPNó-óC /73 # ‡ b9‰-‰;ÚRÛ#-3D+-%0/7,*)!/N#&V$6[^9)$#-)!//73D/f'¨%(:;6[^ < # < #&3 < 2B3 #-)!+-,./“/fe^"W/7%7^9Fa/16’'5#-^9,*/“)!/1,cöX^D+;,# C ,0+ HU#† /7F—/ Û“Š*"$#-%0#G+;,Ð,c^D,'¨/7Fa#-, d q\†|d # Š"ð d # ¥Ù/ d q\†|d # Š%ð d # ‹»† 6‘ † H 󒊤b392B'¨+;,6 d q\†|d # Š%ð d # ¥ d q\†|d # Š"ð d # ‹ ‚‰;PxÜ8†8ô ‰;P‡ó;Ü ò †BP9‰T˜ †BP‡†’ ^PN†-†5ˆ ^P‡†;Ü ò †BP‡†’ †BP‡†8ó˜‰;PxÜB‰¾˜ ‰;P‡ó;Ü ò †BP9‰T˜ †BP‡†’ ^PN†^‰‹ˆ ‰;PxÜB‰(õ ‰;P‡ó8ô‡†BP9‰T˜ †BP‡†8ô ^PN†^‰(õ ò‚‚OQPSRUT7ÂÃVĘøXWÆÅYFZRÃDVmÂ[PÇ{Ä\ZYŽÇƒÈ¡Z]O“ÃQZ[Zúù\YFZõ^‰ó’Š¤bŒc í?îïxíŒLc ðÀñòŒc íˆîï²íŒLc ðˆñò† ‰(ˆ8õ8ˆžP ‡ ‰(ˆ-ó;˜ ò ‡ P‘ õ^PŽˆ,ó ‰ ‡ ó-ôBPt˜-ó ‰ ‡ ó-ó ò óBPNó ‰;PNô;‰(ˆ8õ-†^PŽˆ ‡ ‰(ˆ8õ-† ò ó^P ‡ †BPŽˆ ‡ ‰ ‡ ó;^P‘- ‰ ‡ ó-† ò ÜBP‘ ^P‘-‰(ˆ-ô8ó^Pt˜;˜ ‰(ˆ-ô5õ ò ó^PNó ‰;Pt˜-˜ ‰ ‡ ó-†BPNô-†ˆ‰(ˆ-ô8ó^P9‰¢† ‰(ˆ-ô8ô ò ó^PNó ^P9‰† ‰ ‡ ‡ ‰õ ‰(ˆ-ô5õžPtÜ’ ‰(ˆ-ô5õôó^PNó †BPtÜ; ‰ ‡ ó-†BP‘&Üó ‰(ˆ-ô5õžPNó;˜ ‰(ˆ-ô8† ò ‡ õ^PNó-˜ ‰ ‡ ó-†BP‘- ò›JŒ íˆîï²í›JŒ ðˆñò›JŒ í?î(ï²í›Œ ðÀñò‰;P‡ó;˜8† ‰;PtÜ ‡;‡ ‰;PxÜ5ˆ-˜ ò †BP‡†8† ‡ †BP‡†8†;܉ ‰;P‡ó5õ; ‰;PŽõ,ó;܆†BP‡†;˜ †BP‡†8ó;˜ ‰;PtÜ8õ-ó ^P‡†8†8† ò †BP‡†’-† †BP‡†’;‰;P‡ó;ÜB‰ ‰;PNõ-ó ò†BP9‰† †BP4‰;‰ ‰;PtÜ-Ü ‡ ^P‡† ‡ ò †BP4‰ ‡ †BP‡†5ˆòô ‰;PxÜ’-† ‰;P‡ó8ó ò †BP9‰T˜ †BP‡† ‡ ^PN†;^‰‰;PxÜ’; ‰;P‡ó8ô ò †BP9‰T˜ †BP‡†8ô ^PN†;-óó ‰;PxÜõò †BP9‰¾ ‡‡


§¤ m*§ §+¥-,#./¢ƒ § ‡ bt[/ ‡ bx˜[FG+;,'¨%¨#&F§+;,})!#-)!+;,X)!/a#&V$6[^9)$#-)!/G"n+-%X"B%0”-'0+;6 < +;6’'¨%0#]+`6Mj!FG/7%(+`)!/Œ,Á‰Q^98;,7bÍ21436514798;:=:=8 ¾@? ¿C /73 # ‡ b4‰‹^ÚacK#-%G-Fa/f'¨%(+;,}2B'7^D3b^T#&)!+;,X6!+×#(a(2!,'¨/Ÿ6$i&+_3h^96!/T#-%X)!+ < +;Fa"W+;%'5#-FG/76’'¨+])$#-,–"B%0+ HU#/Œ›ÐPB/7F %0/13 #-h7i-+–#&+–6Mj!Fa/1%0+–)B/ < #-% C +-6!+;,7Pž/7F d q\†|d # Š"ð d #0HJI † H ‘¥"!%c^D/1)$#-)!/1,*ŒLcAíõ;OQPSRUT7ÂÃVĘøXWÆÅYFZRÃDVmÂ[PÇ{Ä\ZYŽÇƒÈ¡Z]O“ÃQZ[Zúù\YFZ$ ¨§%'& ÿ ¤§ (¥ ÿ ¡¥B¨ m¡§¡ ë úÿ v ÿ §¬v) ¢ þÿ ¤§ÐBu#-% C +;6!+;,1PK"$#&%¨#]+-,±,c^D,('0/7Fa#-, d q\†~d # Š%ð d # ¥ / d q\†|d # Š%ð d # ‹ PK%(/7,0"W/ < '/^üö-#&Fa/16'0/-b?/!^4'¨+_)B/Ÿ# < +-%0)!+ < +;F#`›@³b ‡ bt˜BP < 2 a(+;,}"$#-%0&Fa/f'¨%0+-,},¨i&+¼#-"!%0/1,0/16'¨#-)!+;,{6!#U# C /73 # ‡ b9‰‹žbo B 8 BDF ð†ˆ‡ bx˜’ŠBDCE‹ /N@‘ H ‰X+-2†;Šfb+;2ŒLc ŒL›cK#&%0-FG/1'0%0+3 < +ž+;3 ^D+;3 K 3 < +^+;3 ^9+;3KE ‰¢ˆ-ô5õ^PNõ-Ü5ˆ8õ ‰ ‡ ó8†BPt-†5ˆ-˜ ‰-PtÜ’&˜’ ^P‡†’8õ;dí õ^PNˆ8ˆ;-˜ ô^P9‰¾˜;; H †BP‡†;Ü’,ô H †BPN†-óB‰¾Üd° H †^PŽˆ ‡ ˆ8ˆ H †BPNˆ-ô5õ,ó H †BPNˆ8ˆ8ˆ&Ü H †BP ‡-‡ Ü;Ü


‡ btÕ>?+8^ž#-"!3b^ < #&)$# < +;F€,02 < /7,(,0+“"$#-%0#ƒ+ ?+-%¨#-F /7,'/^9FM#-)B+;,ƒ+-,Sö&#-3D+;%(/7,ƒ"$#-%¨#›JF‘ ó † ‰-PtÜ’-/ ÛNŠfP’6‘Ü † ‰;PtÜ;;/ ÛNŠR/O6‘ ‰¢† † ‰-PtÜ’&Ñ/ Û“Šfb¥ ö-#&3D+;%R/¤e^"n/1%7^DFG/76’'¨#-3!"$#-%0#“6‘óN/1,(' S6< +;6’'¨%0#-)!+X>?+8^$)!/e†BPN†;N/ Û}b _ S "$#-%0#X+;,J'7^D”8^9,7P’+;,Uö&#-3D+;%(/7,)[^9,0"W+;6!jüö;/73$6!#±3h^4'¨/1%¨#&'02!%¨#L/+±)B/7,cöX^9+}/76/1,('/^9FM#&)!+;,."$#&%¨#g6‘Üg/N6‘‰¢†–>?+;%0#-F¿žPN†’-ˆ{/XžPN†’,ôg/ Û}P$%0/1,0"W/ < '7^bö&#-FG/76’'¨/&b


OQPSRUT7ÂÃVĘøXWÆÅYFZRÃDVmÂ[PÇ{Ä\ZYŽÇƒÈ¡Z]O“ÃQZ[Zúù\YFZ õ ‡15761574AP calculaday = C 0+ C 1e kxAP (kJ/mol)15721570156815660 2 4 6 8No. de Carbonos‡ bt^ÚaÛ#-39+;%0/1,{)!/k#&V$6`^D)$#-)B/•"n+-%{"!%0”-'0+;6 < #&3 < 2B3 #-)$#&, < +;FÕ+¼F l '¨+ž)!+Ø¥“½ƒÒ¥N¹ "$#-%¨#‰Q^98;2!%0#d q\†|d # Š"ð d # ¥ † 6‘ † H 󒊤b,c^D,('0/7Fa#-,14891487AP calculaday = C 0+ C 1e kxAP (kJ/mol)14851483148114790 2 4 6 8No. de Carbonos‡ bx˜BÚaÛ#-39+;%0/1,{)!/k#&V$6`^D)$#-)B/•"n+-%{"!%0”-'0+;6 < #&3 < 2B3 #-)$#&, < +;FÕ+¼F l '¨+ž)!+Ø¥“½ƒÒ¥N¹ "$#-%¨#‰Q^98;2!%0#d q\†|d # Š"ð d # ‹ † 6‘ † H ó’Šfb,c^D,('0/7Fa#-,


1.93õ8ˆOQPSRUT7ÂÃVĘøXWÆÅYFZRÃDVmÂ[PÇ{Ä\ZYŽÇƒÈ¡Z]O“ÃQZ[Zúù\YFZ1.911.89AE (eV)1.87AE calculaday = C 0+ C 1e kx1.851.830 2 4 6 8No. de Carbonos‡ b ‡ Ú»Û#&3D+;%(/7,•)!/¼#\V$6[^D)!#-)!/_/13D/1'0%0:;6`^ < # < #-3 < 2!3D#-)!+;, < +;F +F l '0+^)B+ ¥“½ƒÒ¥N¹ "$#-%¨#‰Q^98;2!%0#d q\†|d # Š"ð d # ¥ † 6‘ † H õ;Š¤b,c^D,('0/7Fa#-,2.032.011.99AE (eV)1.97AE calculaday = C 0+ C 1e kx1.951.930 2 4 6 8No. de Carbonos‡ bNˆ^Ú»Û#&3D+;%(/7,•)!/¼#\V$6[^D)!#-)!/_/13D/1'0%0:;6`^ < # < #-3 < 2!3D#-)!+;, < +;F +F l '0+^)B+ ¥“½ƒÒ¥N¹ "$#-%¨#‰Q^98;2!%0#d q\†|d # Š"ð d # ‹Ø† 6‘ † H ó;Šfb,c^D,('0/7Fa#-,


L ^D6’'¨/1%0/7,(,¨#-6’'0/{%0/7,(,¨#-34'5#-%#M%0/13 #-h7i-+M"B%¨#&'7^ < #&Fa/16'0/}3b^D6!/7#-%ƒ/16’'¨%0/}+;,Sö&#-3D+-%0/7,)!/–Œc%(/1'5# †@Ny‚‚õ-ôOQPSRUT7ÂÃVĘøXWÆÅYFZRÃDVmÂ[PÇ{Ä\ZYŽÇƒÈ¡Z]O“ÃQZ[Zúù\YFZ/}ŒL›"$#&%¨# +;,k,7^D,'¨/1FM#-,k/1,('¨2B)$#-)!+;,1b d +;FG+Æ+ C ,0/1%cö&# H ,(/»6!#-,&‰D^D8;,1b ‡ b‡ô/ ‡ bNõ^PL+ < +ž/1V < ^D/76’'0/»)!/%(/78;%(/7,0,0i-+ l †BPtÜ-ÜBP¾'5#-6’'¨+O"$#&%¨#Ð+;,z#-3 < +ž”8^D,n@ž2!#-6’'¨+"$#-%¨#Ð+;,Y'7^D”8^9,7bmŒ"$#-%'/^9%Y)$#Ð%0/13 #-h7i-+Ð+ C ,(/7%cö&#-)!#/16'0%0/a#-,N)!2$#-,N"!%(+;"!%c^D/7)!#-)!/7,1PU"W+ž)!/ H ,0/g/7,'/^DFa#-%¬ö&#-39+;%0/1,“)!/aŒc¦+;2ØŒL›"$#&%¨#Ÿ,7^9,('¨/1FM#&, < +;FFa#-^D+-%*6Mj!FG/7%0+g)!/ < #-% C +;6!+;,1P$"$#-%0#g+-,@2$#,^D,O)$#-)!+-,Ð/fe^"n/1%7^9Fa/16'¨#-^D,Ð6!i-+a/1,('¨i-+g)[^D,("n+;6Bjbö;/'^D,1bŒ£%(/73 #&hTi-+•Œc¢è ŒL›#-,L)B/±^D+;6`^T#&hTi-+#-^D6!)!#M"n+ž)!/–,(/7%N#-6!#-3h^9,¨#-)$#G/7F¸>?2!6!hTi&+Ÿ)$#-,“/76B/7%08-^›ÒŠR/)[^D,(,0+ < ^D#-hTi-+ † Œ Šfb d +;FG+NFa+-,('¨%0#-)!+±#X,(/78;2`^D%7P#N,0+-FM#N)$#-,›J@,7b ‡ b ‡ P ‡ bNˆ“/ ‡ bNô“>?+;%06B/ < /†#g›J@³b ‡ bŽõžb~ v p w~ pp í ~ Í †ˆ‡ b ‡ Š~ v 8 y ~ ‚p # ~JM †ˆ‡ bNˆ;Šp y p_w v 8 ‚p{q M Ð ¾ p ¿ †ˆ‡ b‡ô’Š~ v p y ~ pp ýÒ †ˆ‡ bNõ;ŠcU+-%('5#&6'0+•'¨/1F H ,0/ Ò ~ Í v ~JM v M Ð ¾ p ¿ Pn@2!/ < +;FG"$#-%0#-)!+ < +;Fš#•/1@2$#-hTi&+[)B/{2!FM#?+-%06!/ < /X#a›J@³b ‡ b‡óBbQ ~ Í M Ð ¾ p ¿ v Ò †ˆ‡ b‡ó’Š~JM+;6!,c^D)!/1%¨#-6B)!+M@2!/}#a›JÒ † Š l 2!Fa# < +;6!,'5#-6’'¨/&PY#-,O"!%(+;"!%c^D/7)!#-)!/7,ƒ#&V$6`^D)$#-)B/7,"n+;%"!%(”-'¨+;6d< #k"n+ž)!/7F ,(/7%}#-6$#-3b^D,¨#&)$#-,“/7F >?2!6BhTi-+])$#]/16!/7%(8^ #k)!/M)`^D,0,(+ < ^ #-h7i-+!bŸ›J,'5#]%(/73D#-hTi-+/G/739/1'¨%(:;6[^S ,(/7%OFa/13<strong>DE</strong>!+-%./7,'¨2!)$#&)$#G/1F—'¨%0# C #-39E!+;,*>?2B'02!%0+-,7b"W+^)B/7%


õ8õOQPSRUT7ÂÃVĘøXWÆÅYFZRÃDVmÂ[PÇ{Ä\ZYŽÇƒÈ¡Z]O“ÃQZ[Zúù\YFZ1.931.911.89AE (eV)1.871.851.831567 1569 1571 1573 1575 1577AP (kJ/mol)‡ b‡ôBÚ•Û#-3D+-%0/7,{)B/]#\V$6[^D)!#-)!/Ÿ"W+;%{"!%0”&'¨+;6ªe#&V!6[^D)$#&)!/Ÿ/739/1'¨%(:;6[^ < # < #&3 < 2B3 #-)!+-, < +;FÖ+‰Q^98;2!%0#l '0+^)!+G¥“½Ò¥X¹ "$#-%0#{,7^D,'¨/1FM#-, d q\†~d # Š%ð d # ¥ † 6‘ † H õ-ŠfbF2.032.011.99AE (eV)1.971.951.931480 1482 1484 1486 1488AP (kJ/mol)‡ bNõ^Ú•Û#-3D+-%0/7,{)B/]#\V$6[^D)!#-)!/Ÿ"W+;%{"!%0”&'¨+;6ªe#&V!6[^D)$#&)!/Ÿ/739/1'¨%(:;6[^ < # < #&3 < 2B3 #-)!+-, < +;FÖ+‰Q^98;2!%0#l '0+^)!+G¥“½Ò¥X¹ "$#-%0#{,7^D,'¨/1FM#-, d q\†~d # Š%ð d # ‹ † 6‘ † H ó’ŠfbF


C #-,(/ < +;F "!,(/72!)!+-"n+-'0/76 < ^ #-3Àb d +;FG+ª+ª/f'/^93ÐeB#-6^'5#&'0+ l 2!F ,7^9,('¨/1FM#Ø"n/1@2!/76!+BPƒ6$i&+©>?+8^)!/< /1,0, S %7^ #a#G2^'/^D3b^7#-hTi-+g)!+GF l '¨+ž)!+M¥“½ƒÒ¥N¹»P³@2!/},(+;Fa/16’'¨/N>?+8^z#-"!3b^ < #&)!+g"$#-%¨#g+M/1,('02!)!+M)B+6!/þ *mln§¢ þ § þÿ ë+;FG+kFa+;,'¨%0#[# ‰Q^98!bm^bx˜BPm>?+;%0#-Fš"!%(+;"W+;,('¨#-,N)!2$#-,X/7,'¨%02^'¨2!%0#-,±)B/G/1,('¨#-)!+;,X)!/{'¨%0#-6!,7^9hTi-+dOQPSRUT7ÂÃVĘøXWÆÅYFZRÃDVmÂ[PÇ{Ä\ZYŽÇƒÈ¡Z]O“ÃQZ[Zúù\YFZõ-ó؃ÙDS߃ã ä XY0Ü2ZƒÞ[U]\ ã ߣX ^_X\ܦá0âã ß`X T Ý'Þa\ Þ[Zàܦá0âãTU]æWVà߃ãZÇæ]XdceZ Ü ß£XgfÂÜ#ZÇæÜæqã#UbŒI‰Q^D8!b ‡ bNógFG+;,('0%¨#G#G/1,('¨%(2B'¨2B%¨#M8;/1%¨#-3m)B+;,OeB#-6’'¨#&'¨+;,/7,'¨2!)!#-)!+;,1b¥/1'/^93ÓeB#-6’'5#&'0+ † § ‘LŠ>?+8^2B'/^93h^7#-)!+ < +;FG+FG+ž)!/739+ª"$#-%0# +/7,'¨2!)B+Æ)!/¼2!F ,7^D,'¨/1FM#¨Fa#-^D, < +;FG"!3D/¤eB+BP+ªeB#-6’'5#&'0+"!%(/ < 2!%0,(+;%N)!+]/1,('7^D3 C /76B+ † § ‘ dih kj¤Šfba¥ÁFa/ < #-6[^9,0FG+Ÿ)!/g%0/7#-hTi-+k)!/g/13h^DFi^D6!#-hTi-+^D6’'¨/1%06$#Ÿ)!+;,)!+-^D,G,7^D,'¨/1FM#-,a>?+8^ƒ/1,('02!)$#-)!+¨/1Fa"B%0/78;#-6!)!+ H ,0/]+ªF l '¨+ž)!+ª#&)[^9'7^bö;+»)!/_/16!/7%(8^ # < +;F >?2!6!h7ž/7,FG/ < #-6[^D,(Fa+{)B/X%(/T#-h7i-+g)!+{e!#&6'¨#&'¨+g"!%(/ < 2!%0,(+;%ƒ)B+G/1,('7^D3 C /76B+!bHRCCHRHSCOCH 3S‰Q^D8-2!%¨# ‡ b‡óBÚ›J,('0%02B'02!%¨#g8;/1%¨#-3m)!+-,*e!#&6'¨#&'¨+-,ƒ/1,('¨2B)$#-)!+;,1bBu"$#&%¨#©#Ø%0/7#-hTi-+»)!/[/73h^9F„^96$#-h7i-+)^D6’'¨/1%06$#Ø)!+;,ge!#&6'¨#&'¨+-,7bcK#-%0#»+»/1'/^93.e!#&6'¨#&'¨+BP.,0/`#»%0/7#-hTi&++ < +;%(%0/1%G"W/73D#_'¨%¨#&6!,(>?/1% A 6 < ^ #Ø)!+» e^D)B%0+;8 A 6[^D+ Hpo "$#-%¨#¼+»›6žeB+&>?%0/-Pö^D#Ø ‹Ó† ‰‹Š¤P*,0/1% S >?+;%0Fa#-)!+/f'/^D39/76!+[/M2BFS %7^9+!P < E$#-Fa#-)!+])!/ S-< ^D)!+ke--6’'/^ < +!b]cU+;%±+;2B'¨%(+`3D#-)!+!Pd,0/Ÿ#"B%0+ž)!2B'¨+^D6’'¨/1%0FG/7)[^< +-%0%0/1%N"n/13 #•'¨%0#-6!,(>?/1% A 6 < ^D#[)!+] e^9)!%0+-8 A 6[^9+ Hpo "$#&%¨#k+_¥ƒe^D8 A 6[^D+BP]ö^D#[ ‹Ó† ;Š¤PU+ < +;%(%0/%(/T#-h7i-+]+#©>?+;%(FM#&hTi-+¨)[^9%0/f'5#ª)!/¼/1'7^D39/76!+!POFG/1'¨#-6!+;3L/×)`^D,0,(2!39>?/f'¨+¨)!/ < #-% C +;6!+!b ¥ S-< ^D)!+ªe--6’'/^ < + ,0/


õ-ÜOQPSRUT7ÂÃVĘøXWÆÅYFZRÃDVmÂ[PÇ{Ä\ZYŽÇƒÈ¡Z]O“ÃQZ[Zúù\YFZ)!/ < +;FG"W^/g/7FÉFG/1'¨#-6!+;3J/G)[^D,(,02!34>?/1'0+`)!/ < #-% C +-6!+!PK"!#-,0,0#-6!)!+]"n+;%X2!F /1,('5#&)!+_)!/g'¨%0#-6!,7^9hTi-+)!/16!+;Fi^D6$#&)!+{)!/N ‹Y† ˜;Šfb›J,('5#&,%(/T#-h1^/1,O,¨i-+GFa+-,('¨%0#-)$#-,Ð6!#i‰D^D8 ‡ bxÜBbHHCCHHHHCHCHHSCOCH 3H 3 COSCSHH 2 C = CH 2 +SHSCOCH 3SHSHHCCHHHHCSCSO CHH 3 CSHCCH 3 OH + CS 2HOCH 3HSCOCH 3H 2 C = CH 2 + CH 3 OH + CS 2S‰Q^98;2!%¨# ‡ btÜBÚ¹[/ < #&6[^D,(Fa+;,Ð)B/X%(/T#-h7i-+G"$#-%¨#{+g/1'7^D3neB#-6’'¨#&'¨+!b< +-Fa"W+;,('0+;,R/16Mö-+;3böX^9)!+;,R6!+-,JFa/ < #-6[^9,0FG+;,K/1FÙ@2!/1,('¨i-+“>?+;%¨#-FQ/7,'¨2!)!#-)!+;,J/1Fa"!%(/78’#&6!)!+ H¥L,^9FM#&hTi-+©#-)[^9'7^bö&#»)B/_/76!/1%08^D# < +-F +;, < +;6 a(2B6'0+;,•)!/]>?2!6!h7ž/7,Ÿ)B/ C #-,(/)¥0†ª/)¥‰,(/×#ª#-"!%(+Tè† )!/7, < %7^4'¨+;,O6$#{FG/1'0+^)!+-3D+;8^D# < +;Fa"B2B'5# < ^D+;6!#-3·Š¤P^)!/X# < +;%0)B+ < +;F—#-,O,(/78;2[^96’'¨/7,/1'¨#-"$#-,1Ú¥'7^DFi^T#&hTi-+±)$#G8-/7+;FG/1'0%7^ #±/ ?%(/7@2 A 6 < ^ #ÇöX^ C %0# < ^9+;6$#-3n6!+g6!jbö-/73z e‰ û ¥0†`îq§O/7+&'/^DFi^7#-hTi&+L)$#N8;/7+;FG/1'0%7^D#N/


ó8†OQPSRUT7ÂÃVĘøXWÆÅYFZRÃDVmÂ[PÇ{Ä\ZYŽÇƒÈ¡Z]O“ÃQZ[Zúù\YFZ# l )$#-)$#{"W/73D#G›J@³b ‡ bxÜBÚŒ€/fe^"!%(/7,0,0i-+M%(/7,(2!39'¨#-6’'¨/N"$#-%0#G#{/16!/7%(8^< #-%¨# < '¨/1%7^~T#-)!+-,`2!,0#-6!)!+ H ,0/ª+ÆF l '¨+ž)!+ ‹ kN½ †¨€‚ yƒ¥L,`/1,('5#&)!+;,_)!/Ø'¨%0#-6!,7^9hTi-+Æ>?+;%¨#-F£/} yú} œ5¢†…[£D‡-ỳ ¢¤wz{ˆƒˆ‰-œwB¡X 7¡tŠ0œ-‡ ¢¤w‹ƒ9Œ¦ ŽÕ{%} y ŠŽ=‘a’G‘[“5öw”P•böX^-”–—”P˜ ‹6š •~‘[›P‘a•—‘ ”P• œwž—”P˜Gœw”P˜D‘[’\‡õ8õÍ6„‚9Ÿ ”>”P’¤”P’ [¡ • a¢ •”w’k£@”P˜Gœw¤¥˜G‘[œw•h^~¦œw-”P’¤“-”y–˜G”w›P˜0œw¤§œa¡NŒ¨ ‹[‹ ÒÔŒL½ û Ü8óŠ‡õ-†,‚©Ÿ¥ª’¤˜G‘a’ ¢ •¬«6œ®­õ-ó# ‘› q ¤¦¯ ›°‘Jœw’ ”P˜G˜D‘[±7>‘[’²«0³[˜D¤„^ œw’²–œw˜Gœœ‘a“‘[˜D›8^ œ‘¡‘[“´«6œw•~–[^ œ’0µ4””w’iœw’i‘[“‘a˜G›8^œw’.›$íŽ!›‡ Ÿ9‰T˜-Ÿœw–-˜G‘[’D‘[“´«6œ4”P’k“œ{eœwž—‘[•œœ ‡ Ÿ9‰T˜BÚª›+“‘a˜G›8^œw’Ÿ›$펛 # ‘×› qœwž—‘[•Œ–œw˜D«7^˜ª”w’#œ4”P’œ] œwž—‘[•œ ‡ Ÿ9‰ ‡ ”Pž’D‘[˜¡öwœ½­p’G‘ ¾ ¢ ‘yœ£˜G‘[œw±¦µ4”`›¸º²–œw˜0œ£”¿‘a«/^~•e»-œw“´«6œ4«G”¨¡ÁŠ‚‹Y† ‰‹Šd‘“ ‹Y† ;Šd’Gµw” ‡ ‰Pt‘Áô ‡ Nô ° œw•û ¤ ”P•9˜G‘[’D–‘ «7^bö4œw¤ ‘[“´«0‘4ŸJŒI‰D^›Ÿ ‡ Ÿ9‰†Ã¤§”P’*«0˜GœÃ¾ ¢ ‘–œ4˜0œ–œm£@”P˜G¤§œw±¦µ4”§‘± ‹Y† ‰¾Š³2£ˆœ¢öw”P˜ ¡ öw‘[•e‘a¤Ä˜G‘[•œw±¦µ4”yÅ £@”w˜G¤§œw±¦µw” ‘± ‹Y† ;ŠÆÂ’D‘[“-” ”>‘[˜D‘[“´«0‘ ”P¤‚r Mts oXo½ÑÕÒ ¾zÖ ¿Guwv Ëax Mys oXo½ÑÕÒ ¾zÖ ¿Duwv Ï x v MtsÌÎÍ ®Puwv Ë[xMysÌÎÍ ®Puwv Ï x v z Í Mts p&Ê u4v Ï x-{ f;| ‘[’`«0³a˜G¤i^ œw’ †|d Št–œw˜0œ·‘a“‘[˜D›8^ œ·‘‘a“=«0œw•–`^ œ¤-”P’¸’7^~’D«G‘[¤§œw’¸‘[“5öw”P•böX^-”P’¸“”J¤ ‘ œw“[^~’G¤ ”¡‘¹˜D‘¦œw±[µw”“›¸º”ª‘Ž«/^•´»-œw“´«6œ4«G”Ÿñ§‘[’ ¢ •~«0œw”P’œw–-˜G‘[’D‘[“´«6œ4”P’k‘[¤ š œ4˜D«0˜D‘[‘4Ÿ‹ ^’*«0‘a¤tœ ›$í › # › q ¤¦¯ › d † ›=Š d † LŠ›¸«/^• H œw“´«6œ®«0” ­"ô’Nˆ;-†B‰ ­%ô;Nô-†B‰¢ô ­%ô;˜-x˜5õ-ó^‰ †-4‰‹ ‡ ˜ †-4‰¾˜;˜’ †-4‰¾˜ ‡›¸«/^•~‘[“” ­¨‰¾˜-x˜8ó;Ü’ ­5‰T˜- ‡ ‡ ‰ ­5‰¾˜-Nˆ-ó’- †-‡†5ˆ ‡ ‰ †-‡†5ˆ8õ^‰ †-‡†5ˆ-ó8† ^~” H w“´«/^ ” ­ ‡ Ü-‡†8ó5ˆ-ô ­ ‡ Ü-9‰T˜8ôB‰ ­ ‡ Ü-Nõ-˜;Ü8ˆ †-‡†8ô’-ˆ †-‡†8ô8ó5ˆ †-‡†8ô;Ü5ˆK­-˜-‡ô;˜’-˜ ­&˜-Nô8ˆ-ó5õ ­-˜-‡ó;Ü ‡ ô †-‡†5ˆ ‡ †-‡†5ˆ8õ ‡ †-‡†5ˆ-ó ‡¹¼‘a«0œw“”P•Œ ^’D’ ¢ •¬£@‘a«G” -‘ d œ4˜Gž—”P“” ­8ˆ ‡ ô ‡ õ ­-ˆ ‡ ó8†5ˆ ­8ˆ‡ó ‡ õ&܆-‡†8†5ˆ,ô †-‡†8†;Ü8† †-‡†8†;Ü;܉¾Š ­"ô’ ‡;‡ ô ‡ ­%ô;Žˆ&˜B‰ ‡ ­%ô;˜-x˜8†8†-† †-4‰;‰¢ô; †-4‰‹ ‡ †-4‰‹8ˆ^‰‹Y†-Š ­"ô’ ‡ 8ˆ-ô ­%ô;Žˆ,†5õ^‰ ­%ô;˜-t-ô5õ ‡ †-4‰;‰¢ô-ô †-4‰‹8ˆ8ˆ †-4‰‹-ô ‡‹Y†‹Y† ˜;Š ­ ‡ Ü-‡†;˜’-Ü ­ ‡ Ü-N†8õ-Ü ‡ ­ ‡ Ü-‡ô8ó8†-ó †-‡†5ˆ-ó ‡ †-‡†8ô ‡ ˜ †-‡†8ô5ˆ-˜‚¨LŠ¦‘˜8†-t ° œw•û ¤ ”P•4‘Uö4œw˜c^ œw±[µw”¹‘‘[“´«0œw•–[^œ †œw–-˜G‘[’D‘[“´«6œ ö4œw˜7^œw±¦µ4”¹‘‘[“‘a˜G›8^œ\^~“´«0‘[˜D“œ †LŠ‘N˜^‰Pt˜ ° œw•û ¤ ”P•9X^“`^ œ4“” ¢ ¤À–˜G” ‘a’G’G” ‘[“-”w«0³a˜G¤i^ ”ŸJŒ¡’¹‘a“‘[˜D›8^ œw’¹-‘œ4«/^üöwœ4±¦µw” †


‹Y† ;Š ­%ô-˜-‘&˜’-˜ ­%ô;˜‘;&˜ ‡ ­"ô;˜-t;;8ˆ˜’Š ­ ‡ Ü-Nô-ô8ó;Ü ­ ‡ ÜNô8ô-˜8† ­ ‡ Ü-‡ô8ô’-†‹Y†î u ¨ ‘› q¡É › # ­=›0í É d † ›Šr˜D‘¦œw±[µw”Ÿö4œw•~”P˜J˜G‘a• œ ^”P“œw”¿Å`žœw˜G˜D‘!^~˜0œ`”[ ‹Y† ‰‹Šª”Pž-«7^”`³ –˜(”;»^~¤§”¿œw”ƒö4œw•”w˜ª‘[“ ”P“´«0˜0œ4”¼“œ¥¢ ˜0œ †ˆ‡ ó-‡ô ° œw•û ¤ ”P• ŠŽ ¢ ’0œw“-”4­p’D‘ [¡ • a¢ •”P’ d d ‹ Œ † Š û œ ¢ ›®­ [ ­p–BÛ Œ¦¤ ‡õ-Ü,‚©¤§”w’D«0˜Gœw“”•b^~«0‘a˜0œ4«¢ ‘2œmœw–˜D”;»^~¤tœw±[µw”mœw[^¬«/^üöwœÃ³‘ŽÎ ^~‘[“´«0‘–œw˜Gœ†”§‘a’D« ¢ ”§-”P’¤§‘ œw“[^~’G¤ ”P’d‘˜D‘¦œw±[µw”Ÿ¾OQPSRUT7ÂÃVĘøXWÆÅYFZRÃDVmÂ[PÇ{Ä\ZYŽÇƒÈ¡Z]O“ÃQZ[Zúù\YFZóB‰œ ‡ Ÿ9‰ ‡ ÚR›+“‘a˜G›8^œ†œw–˜G”¦»^¤§œwœ † ›+¾‚Ÿ ‡ ŸxÜ’ŠÆ-‘[“-‘[˜G›-^ œ½^~“=«G‘[˜D“œÃ‘J‘[“´«0œw•–[^œ#–œ4˜0œÃ”P’d’c^’*«0‘[¤§œw’œwž—‘[•‘ œw“[^’D¤§”È‘£˜G‘¦œ4±¦µw”¼›¸º”"‘a«7^•»œ4“=«0œ4«0”-Ÿf§‘[’ ¢ •~«6œ4”P’†œw–-˜G‘[’D‘[“´«6œ4”P’ ‘[¤‘a“Möw”P•böX^~”P’†“”Ǥœ4˜D«0˜D‘[‘4Ÿ š‹ ^’*«0‘[¤§œ Ï › ¨ r î u r‘ô?u›+«7^• H œw“´«6œ4«G” ­%ô-˜-t˜-˜5ˆ-˜ ­%ô;˜t˜’,ô ‡ ­"ô;˜-x˜’8ˆ ‡›+«7^•~‘[“”­5‰T˜-Žˆ,ô;˜8† ­5‰¾˜Žˆ-ô-†8† ­¨‰¾˜-Nˆ8ˆ-ÜB‰K ^-” H w“´«/^ ”­ ‡ Ü-Žõ-8õ8ˆ ­ ‡ ÜŽõ;ž‰(ˆ ­ ‡ Ü-Nõ;-†5ˆ¹¼‘a«0œw“”P•­&˜-Nó-ô8ô8ó ­-˜Nó8ô-˜8ô ­-˜-‡ó8ô’-ôŒ ^’D’ ¢ •¬£@‘a«0”m‘ d œw˜DžÂ”w“” ­-ˆNó8ˆ-óB‰­8ˆ>Nó5ˆ ‡ õ ­8ˆ‡ó5ˆ-˜8ó‹Y† ‰‹Š­%ô-˜-‘,ô8ó8ó ­%ô;˜‘-ô-†8ó ­"ô;˜-t8ˆ-Ü;Ürtô?u› qJÉ › # ­=›$í ÉId † Š‘¢ ‘¿”»›+“»”w£@˜G‘£³`¤§œ-^’–”P•œw˜7^~ ¡ öP‘a•d¾ ¢ ‘£”»¥¡»^~›PÊ[“[^~”Ÿ d ”P¤ –œw˜Gœw“”®­p’G‘ ¡ «0”P¤ ”P’”Ç£ˆœ4«G”Ç‘£¾Ì•h^œ(œÍ«6œ4žÂ‘a• œË–—‘[˜c^D”>[^ œ-$öw‘[˜7^¬Î œ½­p’G‘Ⱦ ¢ ‘"œÍ˜G‘[œ4«/^üö^~œw‘ ”w¤§”·“ ¢ •‘1”wΕ”œË¤§‘a’G¤§œË£ˆœw¤¢ ¤§‘a“=«0œt’7^~›P“[^¬Î œ4«7^bö4œw¤ ‘[“´«0‘ ”w¤Ï”`œ ¢ ¤§‘a“´«0”`”y“Mj¤ ‘[˜D”£œ4«0Ðw¤„^ ”ŸƒÒp’D«0”£œ ”P“´«0‘ ‘†–—”P˜G¾ ¢ ‘œ¢ öP‘a“’`‘[•~‘a«0˜DÐP“[^ œw’ ‘ ¡ «0”P¤ ”P’ ¤tœ-^~’m–‘a’0œw”w’y‘[’*«6µw”·•b^›´œ4œw’ œw”P’ “Mj •~‘[”P’ ”P¤ ¤§‘a“”P˜œw’§“ ‘[˜G‘a¤Ñ–œw˜Gœ £@”P˜D¤tœ4˜ª”¼‘a’D«6œ4”È‘m«0˜Gœw“’c^±¦µ4”¿œ£@”P˜D±¦œ-]‘a’D«6œ4“”Ȥ§œ-^~’ª–˜G”P–—‘[“-’0œw’œ¿’D‘§[^~’D«G”P˜a¢ • œw’+–—”P•b^ œ4«GÐP¤„^ œw’W’0µ4”#¤§œ-^’ ”P¤ –•‘Æ»-œw’‘[¤)˜D‘[• œ4±¦µw”2Åw’[^œ4«0ÐP¤i^ œw’¸–—”P˜+–—”P’G’ ¢ ^˜D‘[¤¹¼”P•~³‘[“´«G”P’d–—”‘a¤_’G‘a˜kœw“œw•b^’0œ4”P’[^üöP‘a˜G’G”w’«7^–—”P’d‘¦öX^ž-˜0œw±1‘a’[Ÿ½¤”m‘[“´«0œw“´«0”«G””w’¹‘[’D«G‘[’k¤§”¢öX^¤”P¤§”¿œ`’ ¢ –‘a˜G–—”P’7^~±¦µw”¿‘ ¢ ¤Ò“Mj¤ ‘[˜D”¼•b^¤i^~«6œ4”t‘m¤ ”¢ö^~¤§‘a“´«0”P’J£ ¢ “-œw¤ ‘[“´«6œ-^~’ 6š œw¤§œw”P’”P•³ [¢ •œw’k–”P•b^ œ4«GÐP¤i^ œ4’¹“µw”y•b^“‘[œw˜G‘a’ ”w¤ Œ‘¤§”>”P’¤“”P˜G¤§œ-^~’¤‘Áö^~ž˜0œ4±¦µw”ŸL›¤Ó›P‘a˜0œw•©Â¤«G”P¤ ”P’–”P’D’ ¢ ‘a¤ † ˜;½­"ô’Š¸¤§”>”P’/‘ö^~ž˜0œ4±¦µw”„‡ó-†,‚9ŸR½¤” œw’G”#”P’i‘a’D«0œw”P’²‘¤«G˜0œw“’c^±[µw” † ‰‹Š‘¡;ŠŽ‚œw’¹£@˜D‘[¾M€Ê[“ ^ œ4’öX^ž-˜0œ ^”P“œ,^’d¾ ¢ ‘ œw˜Gœ «G‘[˜c^¦œ4¤¥œm«G˜0œw“-’D£@‘[˜DÊ[“ ^ œm”a e^-˜G”P›PÊa“[^”®­ o –œw˜0œ†”G›+“»”w£@˜G‘” ¢ –œw˜Gœ†”M¥¤»^›wÊ[“[^~”†’0µw”†­5‰;‰¾-ó- ‡ † ¤ í ‘ª­¨‰¢ô ‡ >t˜8† ¤ í ˜G‘a’G–—‘ «7^bö4œw¤ ‘[“´«0‘4Ÿ


OQPSRUT7ÂÃVĘøXWÆÅYFZRÃDVmÂ[PÇ{Ä\ZYŽÇƒÈ¡Z]O“ÃQZ[Zúù\YFZ ó’TS (2)64,6∆ U (kcal/mol)TS (1)H 2C=CH 2+CH 3OH + CS 241,2 30,2CH 3CH 2SC(=S)OCH 3Perfil de Reação.‰D^› ¢ ˜Gœ ‡ Ÿ4‰¢†BÚ Œ ^œw›P˜Gœw¤tœÃœm˜D‘¦œw±[µw”m‘‘[•b^¤i^“œw±[µw”±^~“=«G‘[˜D“œ†”m‘a«/^~•Â»-œw“´«6œ4«G”Ÿ


˜’Ši³‘X˜8ô-Nõ ° œ4•û ¤ ”P• † ‰Q^›Ÿ ‡ Ÿ4‰;‰‹ŠŽŸ‹Y† œw˜Gœ «G‘[˜7^~¦œw-”P’¡”P’L^‰¤ ”>”P’k“”P˜G¤§œ-^~’k-‘ÁöX^ž˜Gœw±¦µ4”t–œw˜Gœ§”y‘a’D«0œw”y‘2«0˜Gœw“’7^~±¦µw”‰”P˜0œ4¤¢ ‘œ#£@˜G‘a¾M€Ê[“ ^ œ±öX^ž˜Gœ ^~”P“œw•‚˜D‘[• œ ^”w“œwœ#Å«0˜0œ4“’D£@‘a˜GÊ[“ ^ œÁ^“-«G˜0œw¤ ”P•‘Æ­‘a’D«0œÃ˜G‘¦œ4±¦µw”’G‘a“”m¾• œwĩ”M ^˜D”P›PÊa“[^”†”G›+“»”w£@˜D‘2–œw˜0œm”a¥¡»^~›PÊ[“[^~”†³J­5‰¢ó’-ˆ ‡ ô ¤ í Ÿa¢OQPSRUT7ÂÃVĘøXWÆÅYFZRÃDVmÂ[PÇ{Ä\ZYŽÇƒÈ¡Z]O“ÃQZ[Zúù\YFZó;˜š œÔ«0˜0œ ‘%aGœ4œ·“”°[^ œ4›P˜0œw¤§œÍœ4–˜G‘a’G‘[“´«0œw”°“œ ‰Q^›-Ÿ ‡ Ÿ9‰¢†·˜D‘[–˜D‘[’D‘[“´«6œRœ˜G‘¦œ4±¦µw”‘ŒÒ•b^“ ”P¤ –—”P’7^~±¦µw”m” ¡w ^~”û-w“´«/^ ”£@”P˜D¤tœw-”†“œ ˜D‘¦œw±[µw”a›+ºöX^ œ{ ‹Y† ‰‹ŠŽŸ=›+’D«6œ ˜G‘[œw±¦µw”m«6œ4¤ÃžÂ³a¤‘”P’D«G˜G” ¢Ô¢ ¤Õ–˜G” ‘a’G’D”Ç‘[“”4«0³[˜D¤„^ ” œw–˜D‘[’D‘[“´«6œw-”&ö4œw˜7^œw±¦µw”¿‘§‘[“‘a˜G›8^œ^“´«G‘[˜G“œ¼‘•N†’D‘t¤ œw•û ¤§”w•¸‘Çöwœ4˜7^ œ4±¦µw”`‘ ‘[“´«0œw•–[^œy‘MNô ° œw•û ¤§”P•©Ÿ–ŒÖžœw˜D˜G‘!^~˜0œ`‘ ‘[“‘a˜G›8^œ`˜G‘[•œ ^~”P“œwœ¿œ°


OQPSRUT7ÂÃVĘøXWÆÅYFZRÃDVmÂ[PÇ{Ä\ZYŽÇƒÈ¡Z]O“ÃQZ[Zúù\YFZ ó ‡TS (3)∆ U (kcal/mol)36,7CH 3OH + CS 22,0HSC(=S)OCH 3Perfil de Reação.‰Q^› ¢ ˜0œ ‡ Ÿ4‰;‰;Ú Œ ^œw›P˜Gœw¤tœ#œ ˜D‘¦œw±[µw”m‘‘ ”P¤ –”P’c^±[µw”m” ¡w ^~”û4“=«7^ ”Ÿ


”"¤ ‘[’G¤ ”"¤§”>”Ç’ ¢ ›P‘[˜c^”"–œ4˜0œÇ”"’7^’*«0‘a¤tœ d q¤d # ‹[d“† ‘ ‹ Š † ¥ d q ŠŽ/”P’m‘[’D«0œw”P’m‘Œ† ‰‹Šª‘ † -ŠŽe–œw˜0œ¿”È’7^~’D«G‘[¤§œ †|dih ¤jfŠ d # †~dih kjfŠ d ‹[d“† ‘ ‹ Š † ¥ d q Šª˜G‘a£@‘a˜G‘a¤m­ß’G‘yÅ«G˜0œw“’c^±[µw”r Mtsãâ2â ÑUÒ ¾tÖ ¿Guwv Ë2ä5ÌÎÍ ®wuwv Ï xv z Í Mys pŠÊ uwv Ï äpŠÊ uwv Ï x-{ f½| ”L¥“½Ò¥X¹Ô®’D‘[› ¢ “”ªœ[^böX^~’0µw”k¤§”w’D«0˜Gœ®­½¤”¤‘[’*«‡ Ÿ9‰‹>Ÿ*Œà–œw˜D«G‘œ®«/^bö4œmœm¤§”P•~³ a¢ • œ-˜D‘[–˜D‘[’D‘[“´«6œwœt‘[¤Äœw ¢ •9£@”8^]‘a’ ˜7^~«0œ –—”P˜ ¢ ¤œm“œ„‰Q^›Ÿœ †~d d ‹ Œ † Š û ¥ƒ‰‹ŠÃ‘`”Ô˜D‘[’*«6œw“´«0‘£œÇ¤ ”P•³ [¢ •œ-¸‘a¤ öP‘a˜G¤ ‘[• š ”+£@”8^“ÌüöP‘a•d¤tœ,^’Ãœ4•~«0”È‘`«0‘[”w˜7^ ˜7^~«0œ(–”w˜ ¢ ¤á“-ÌböP‘a•d¤§œ-^’#žœ-^¬»”Ç‘y«G‘[”P˜c^ œ † ¹ ¯ û ¥0†;ŠŽŸØŒ_‘[“‘a˜G›8^œÈΓœw•i”Ç’7^~’D«0‘a¤tœ(³‘a’‘a’ ˜7^~«0œ†–‘a• œg›+¾—Ÿ ‡ Ÿ9‰¢†^ÚMysåâ#â ÑÕÒ ¾tÖ ¿Gu4v Ï äpŠÊ uwv Ï x vv MtsÌ Í ®Pu4v Ë#ä5ÌÎÍ ®wuwv Ï x MtsÌ Í ®Pu4v Ï äpŠÊ uwv Ï x v†ˆ‡ Ÿ4‰¢†’Š


a¢ ˜G’D”P˜”†‘[’*«/^•~žÂ‘a“”ŸJŒ¤’¹‘[“‘a˜G›8^œw’¹‘œ4«7^bö4œw±¦µ4”†‘[“ ”P“´«0˜0œ4œw’–œw˜Gœ– ‹Y† ‰‹Ši‘N ‹Y† ;Š²£@”P˜Gœw¤–˜D‘‡ tÜJ‘ ‡ Ü- ‡ ° œw•û ¤ ”P•©w˜G‘a’G–—‘ «/^bö4œw¤ ‘[“´«G‘wŸRŒè[^~¤„^~“ ¢ ^±¦µ4”¡œ‘[“‘a˜G›8^œª‘œ4«/^üö4œw±¦µw”-P‘[¤)˜D‘[•œw±¦µw”˜‹Y† ‰¾Š†¾ ¢ œ4“=«G”Í–œ4˜0œ× ‹Y† -ŠŽ²«0œw¤Ãž—³[¤é–—”>‘£’G‘[˜ œ4«G˜7^~ž ¢ ÌœÔÅœw”"‘Ž«/^•i»-œw“´«0œ4«0”«6œ4“=«G”Ë–œw˜0œ¼‘[’*«6œw-”P’y‘£«0˜Gœw“’7^~±¦µw”˖”w˜ ”P“ a ¢ ›´œ4±¦µw”Ë‘¼˜D‘[’G’D”P“w“ ^ œË‘[“´«0˜D‘È”P’ ›P˜ ¢ –”P’‘a’D«6œ4ž[^•b^¦œ4±¦µw”"”P’ ^ œ4’öX^ž˜Gœ ^~”P“œ-^~’¾ ¢ ‘ œw˜Gœ «G‘[˜c^¦œ4¤Öœ#«0˜Gœw“’D£@‘a˜GÊa“ ^œ½^“´«0˜Gœw¤ ”P•‘ [¢ •œw˜¸”{ ^˜D”P›PÊa“[^”£@˜D‘[¾M€Ê[“¢ –œw˜0œ†”a¥¤»^›PÊa“[^”†’Gµw”m­ÔÜ5ˆ-Ü-t-˜Ã‘J­5‰¢ˆ ‡ õ‡ô5ˆ ¤ í ˜D‘[’D–‘ «/^üö4œw¤§‘a“´«0‘wŸ–œ4˜0œ†”G›“>»-”4£@˜G‘”OQPSRUT7ÂÃVĘøXWÆÅYFZRÃDVmÂ[PÇ{Ä\ZYŽÇƒÈ¡Z]O“ÃQZ[Zúù\YFZó8ôSCOCH 3S¢ ˜Gœ ‡ Ÿ4‰‹^Ú Œ ^böX^’Gµw”(”(’c^’*«0‘[¤§œ †|dih ¤j¤Š d # †|dih ¤jfŠ d ‹[d“† ‘ ‹ Š † ¥ d q Š–œw˜Gœ(œw–•b^ œ4±¦µw”‰Q^~›³a«G””a¥“½ƒÒ¥N¹ËŸ ”m¤Œ€eœ4žÂ‘a• œ ‡ Ÿ4‰(ˆÃ¤§”P’*«0˜Gœ ”P’˜D‘[’ ¢ •~«6œ4”P’”Pž-«7^”P’¹–œw˜0œ œw’‘[“‘a˜G›8^œw’›$íÆW› # ‘±› q¤¦¯ ›æ‘2œw’”P˜G˜D‘[±7>‘[’«0³a˜G¤i^ œw’–œw˜0œ#œ2‘a“‘[˜D›8^ œ‘k‘[“´«6œw•~–[^ œ>’D‘[› ¢ ^“”®­p’G‘¤œw’/‘a«0œw–œw’/‘ ¦¡ • [¢ •~”P’‘[’ ˜7^¬«6œw’‹ ‘a±¦µw”˜-Ÿx˜-Ÿ ½¡œ eœwž—‘[•œ ‡ Ÿ9‰ô°’Gµw”œw–˜G‘a’G‘a“=«0œw”P’¿”P’ƒö4œw•”w˜G‘[’£œ‘a“‘[˜D›8^ œRœw–˜D”;»^~¤tœwœ-“œœ ^“´«G‘[˜G“œk‘/‘[“´«6œ4•–[^œ-”P’]’7^’*«0‘a¤tœw’]‘a“Möw”P•böX^~”P’W“” ¤ ‘ œw“[^~’G¤ ”k-‘/˜D‘¦œw±[µw”ƒ›+º”¹»-œw“´«6œ4«G”‘a“‘[˜D›8^a¢ ˜G’D”P˜¤-”t‘[’*«/^~•ž—‘[“”Ÿ Œ ^¬£@‘[˜G‘a“´«0‘[¤ ‘[“´«G‘#”§’7^~’D«0‘a¤tœmœw“´«G‘[˜7^~”P˜[‘a’D«0œ§˜G‘[œw±¦µ4”t³ ¢ ¤¥–˜D” ‘[’G’D”–˜D‘‘[“´«G‘²‘Æ»-”4«0³[˜D¤„^ ”Pœw–˜G‘a’G‘a“=«0œw“””P’Döwœ4•”P˜D‘[’e-‘ ‡ ô-Nõ¤‘ ‡ õ>9‰ ° œw•û ¤ ”P•–œw˜0œJœ4’Qö4œw˜7^œw±7>‘[’œw•¬«6œw¤œ„^~“´«0‘[˜D“œm‘œm‘[“´«6œ4•–[^œ-˜G‘a’G–—‘ «7^bö4œw¤ ‘[“´«0‘4ŸO›+’D«6œ§›P˜0œw“-‘#‘a’D«0œwž[^•b^[œw±¦µw”†’D‘‘¤öP‘†Åœm‘[“-‘[˜G›-^”P“ a ¢ ›´œ4±¦µw”#œw’/ ¢ –•œw’²•b^›´œ4±7>‘[’”P’²›P˜ ¢ –—”P’£@‘[“[^~• œ ”w¤Àœ2•h^~›´œw±¦µ4”ç¼£@”P˜G¤§œwœ“” ”P¤ –”w’D«0”¢ ¤§‘a“´«6œw“-”Jœ‘[•~” œw•b^[œw±¦µw”‘a•‘a«G˜GÐP“`^ œ®–-˜G”8^~ž[^~«7^bö4œd“” œw’G”¤”¡˜D‘¦œw›w‘[“´«0‘+»-œw“´«6œ4«G”‘a’D«/^~•ž—‘[“”-4œ¢ –•œ-ŸÆÛ‘a˜7^~Î œ®­ß’G‘¿“œ ‰D^›Ÿ ‡ Ÿ9‰¾˜"¾ ¢ ‘¼œÔ£@”P˜D¤tœw±[µw”Ç”» ‹Y† ‰‹ŠÃ«6œ4¤ÃžÂ³a¤£@‘a“[^•œ(‘Èœ"•h^~›´œw±¦µ4”Ç£ˆœöP”P˜ ¡ öw‘[•k‘[¤ê˜D‘[• œ4±¦µw”Ëœ» ‹Y† ;ŠŽ²–‘a•”Ô¤§‘a’G¤ ”ˤ ”w«7^böP”Ôœw–-˜G‘[’D‘[“´«6œ4”œw“´«0‘a˜7^~”P˜G¤ ‘[“´«0‘4ŸŽŒ¡’³


‹ ^~’D«G‘[¤§œ ›$í › # › q ¤¦¯ › d rìëWu d rìíKu‹Y† ;Š ­5‰¾˜’>Nô8ô-ó;Ü ­5‰¾˜’>Žõ-˜-˜5õ ­¨‰¾˜ ‡ ‡ ˜5ˆ,ó †-t-Ü8†-˜ †-x˜8†5õ&Ü †-x˜8†8ó8óî u ¨ ‘› qJÉ › # ­=›$í ÉId rìëWur‘› q¡É › # ­=›$í É d rìíKur‘ô?uOQPSRUT7ÂÃVĘøXWÆÅYFZRÃDVmÂ[PÇ{Ä\ZYŽÇƒÈ¡Z]O“ÃQZ[Zúù\YFZó5õœwž—‘[• œ ‡ Ÿ9‰¢ˆ^Úª›+“‘a˜G›8^œw’Ÿ›$펛 # ‘×› q¤¦¯ ›‘ ”w˜G˜G‘a±7>‘[’`«0³a˜G¤i^ œw’ †|d Št–œw˜0œ·‘a“‘[˜D›8^ œ·‘‘a“=«0œw•–`^ œm–œw˜0œ§”P’¡’c^’D«G‘[¤§œw’k‘[“5öP”P•üöX^”P’¤“”y¤ ‘ œw“[^’D¤§” ‘ØD‘¦œw±[µw”•›¸º+-” »-œw“´«6œ4«G”y–˜D‘ [¢ ˜G’G”w˜”m‘a’D«/^~•ž—‘[“”-ŸU§k‘a’ ¢ •¬«6œw”w’œw–˜G‘a’G‘a“=«0œw”P’k‘[¤ š œw˜D«G˜G‘a‘wŸH œw“´«6œ4«G” ­5‰¾˜’>Žõ-˜-ó8† ­5‰¾˜’>Nó8† ‡;‡ ­¨‰¾˜ ‡ Nˆ^‰¾Ü-ó †-t-Ü5õ ‡ †-x˜B‰ ‡ ó †-x˜B‰(ˆ8õ›+’D«7^•~žÂ‘a“” ­%ó;˜Žõ^‰ó;˜ ­%ó;˜-Nõ8ˆ;,ó ­%ó ‡ ‡ó;˜ ‡ ô †-t-˜8†8õ †-t ‡ †-Ü †-t ‡ ‰¢ó¹¼‘Ž«6œw“-”P• ­-˜Nô;˜;-˜ ­-˜-‡ô5ˆ-ó8õ ­-˜-‡ó;Ü ‡ ô †-‡†5ˆ ‡ †-‡†5ˆ8õ ‡ †-‡†5ˆ-ó ‡Œ ^~’G’ ¢ •~£@‘Ž«0” ‘ d œw˜Gž—”P“” ­8ˆ> ‡ ô ‡ õ ­8ˆ ‡ ó8†8ˆ ­8ˆ‡ó ‡ õ&Ü †-‡†8†5ˆ,ô †-‡†8†;Ü-† †-‡†8†;Ü;Ü‹Y† ‰‹Š­5‰¾˜’>Nô8ó8ˆ-† ­5‰¾˜’>Žõ8ˆ,ó8ó ­¨‰¾˜ ‡ ‡;‡ Ü-ô †-t-Ü8†-† †-x˜8†5õ,ô †-x˜8†8ó5ˆœ ‡ Ÿ9‰ôBÚK›+“‘a˜G›8^œªœw–˜D”;»^~¤tœwœ † ›+¾‚Ÿ ‡ Ÿ4‰¢†’ŠÆP‘[“‘a˜G›8^œ¬^“´«0‘a˜G“œJ‘¹‘a“´«6œw•~–[^ œ¡–œw˜0œJ”P’+’c^’*«0‘[¤§œw’œwž—‘[•‘ œw“[^~’G¤ ”y‘†˜G‘[œw±¦µ4”k›+º-”t»œ4“=«0œ4«0”`–-˜G‘ a¢ ˜G’D”P˜”`‘[’*«/^~•ž—‘[“”Ÿ§‘[’ ¢ •~«0œw”P’‘a“Möw”P•böX^~”P’J“”`¤š œ4˜D«0˜D‘[‘4Ÿ œw–-˜G‘[’D‘[“´«6œ4”P’k‘[¤‹ ^~’D«G‘[¤§œ Ï › ¨ r î u rtô?uœw“´«6œ4«G” ­5‰¾˜ ‡ ‘,ó8ó5õ ­5‰¾˜ ‡ ‘8õž‰ ‡ ­¨‰¾˜ ‡ t8õ-†8ˆH­%ó ‡ Nô;˜-ó ‡ ­%ó ‡ Nô’,ó’ ­%ó ‡ ‡ô’8õ&˜›+’D«7^•~žÂ‘a“”¹¼‘Ž«6œw“-”P• ­-˜Nó8ô-ô8ó ­-˜Nó8ô-˜8ô ­-˜-‡ó8ô’,ô^~’G’ ¢ •~£@‘Ž«0”m‘ d œw˜Gž—”P“” ­8ˆ>Nó5ˆ,óB‰ ­8ˆ>Nó5ˆ ‡ õ ­8ˆ‡ó5ˆ-˜-󌉋Š ­5‰¾˜ ‡ ‘&˜;˜ ‡ ­5‰¾˜ ‡ ‘^‰¢ˆ-ó ­¨‰¾˜ ‡ t^‰ ‡ Ü‹Y†;Š ­5‰¾˜ ‡ ‘ž‰¢†;˜ ­5‰¾˜ ‡ 9‰¾Ü;8õ ­¨‰¾˜ ‡ 4‰¾ÜB‰ó‹Y†


TS (2)ó8óOQPSRUT7ÂÃVĘøXWÆÅYFZRÃDVmÂ[PÇ{Ä\ZYŽÇƒÈ¡Z]O“ÃQZ[Zúù\YFZ49,4TS (1)∆ U (kcal/mol)(Ph)CH2(Ph)CHSC(=S)OCH334,947,1(Ph)HC=CH(Ph) +CH 3 OH + CS 2Perfil de Reação.¢ ˜Gœ ‡ Ÿ4‰¾˜BÚ Œ ^ œw›w˜0œw¤§œ œt˜G‘[œw±¦µw”§‘Ña•h^¤i^“œw±¦µw”Ç^~“´«0‘[˜D“œt”m»-œw“´«6œ4«G”y–˜G‘ [¢ ˜D’G”P˜¡”y‘[’*«/^~•¬ž—‘[“”-Ÿ‰Q^~›


ó;ÜOQPSRUT7ÂÃVĘøXWÆÅYFZRÃDVmÂ[PÇ{Ä\ZYŽÇƒÈ¡Z]O“ÃQZ[Zúù\YFZ‡ Ÿ4‰;‰t‘ ‡ Ÿ4‰¾˜£¤§”P’*«0˜Gœw˜0œw¤Ñ¾ ¢ ‘tœ¿£@”P˜D¤tœ4±¦µw”£”_ ‹Ó† ‰‹Šª³§£ˆœöP”w˜ ¡ öP‘a•²‘a¤g˜D‘[•œw±¦µw”Œ¡’½‰Q^›w’[Ÿ‹Y† ;Š–œw˜0œm”P’k”8^’¹»-œw“´«6œ4«G”P’k‘[’D« ¢ œw-”P’[ŸO½k”t‘[“´«0œw“´«0”—”Pž’D‘[˜cö4œ®­ß’G‘2“œ‰D^›Ÿ ‡ Ÿ9‰ ‡ ¾ ¢ ‘#“œœw”G ‘[’G’D”P’2’0µw”£‘[“-‘[˜G›w‘a«/^ œw¤ ‘[“´«G‘†–”P’D’GÌüöP‘!^~’[˜D‘¦œw±[µw”£‘†‘[•b^¤i^“œw±[µw”t-”¿‘Ž«/^~•W»-œw“´«6œ4«G””P’”8^~’J–˜D”¡ ¾ ¢ ‘2œw’žœw˜D˜G‘!^~˜0œw’¹-‘2‘a“‘[˜D›8^ œ†’Gµw”m–˜0”¦»^¤§œw’[Ÿa¡ –œw˜0œ"”(»-œw“´«6œ4«G”Ë–˜D‘ a¢ ˜G’D”P˜t”Ô‘[’*«/^~•ž—‘[“”³¿–˜G”¢ö ¡ öP‘a•k¾ ¢ ‘¼œ"˜G‘¦œ4±¦µw”Ô‘¿‘[•h^~¤„^~“œw±[µw”_ ”P˜D˜0œxöX^ œŸ ‹Y† ‰‹ŠŽ[a ¡ ¾ ¢ ‘§œ£žœw˜G˜D‘!^~˜0œ`‘G ‹Y† ‰‹ŠJ³ ¤§‘a“”P˜ª¾ ¢ ‘tœ¿žœ4˜G˜G‘'^˜Gœ£-‘G ‹Ó† ;ŠÆ ”P¤§””¤ ”P’D«G˜0œ†œi‰Q^›-Ÿ ‡ Ÿ4‰(ˆŸ70TS(2)TS(3)H2C=CH250TS(1)∆H (kcal/mol)30HSC(=S)OCH3H2C=CH2H2C=CH2CS2CH3OH10H3C−CH2SC(=S)OCH3−100.00000 10.00000 20.00000 30.00000Perfil de Reação‰Q^› ¢ ˜0œ ‡ Ÿ4‰ ‡ Ú Œ ^ œw›P˜Gœw¤§œÃ›P‘[˜Gœw•¦œm˜G‘[œw±¦µw”m‘‘a•h^¤i^“œw±¦µw”Á^“´«0‘a˜G“œ†” ‘a«7^•Â»-œw“´«0œ4«0”Ÿ


80OQPSRUT7ÂÃVĘøXWÆÅYFZRÃDVmÂ[PÇ{Ä\ZYŽÇƒÈ¡Z]O“ÃQZ[Zúù\YFZ Ü8†TS(2)40TS(1)∆H (kcal/mol)0(Ph)H2CC(Ph)(H)SC(=S)OCH3TS(3)(Ph)HC=CH(Ph)−40HSC(=S)OCH3(Ph)HC=CH(Ph)CH3OH(Ph)HC=CH(Ph)−800.00000 10.00000 20.00000 30.00000Perfil de ReaçãoCS2¢ ˜Gœ ‡ Ÿ4‰(ˆ^Ú Œ ^ œw›w˜0œw¤§œ ›w‘[˜0œ4• œ§˜G‘¦œ4±¦µw”§‘Ñ[•b^¤i^“œ4±¦µw”Ç^~“=«G‘[˜D“œt”§»-œw“´«0œ4«0”§–˜G‘ [¢ ˜D’G”P˜J-”‰Q^~›‘a’D«/^~•ž—‘[“”`Ÿ


Œ””w˜G‘a“œwœ ^“´«0˜DÌ“’D‘ œR‘͘D‘¦œw±[µw” †©ñ ÿ {B£wzỳ ¢¤w ÍÇò G‡ Í {Bw~} yÖó}¢} £c¡-wzy—‡-{% Ò%§ d Š¿³ ¢ ¤tœ‘a«G””w•”P›8^œ¿žœw’G‘[œwœ"“œw’m‘[¾ ¢ œw±1‘a’ • ¡ ’D’7^ œw’†‘£¤ ”¢ö^~¤§‘a“´«0”Ç‘£–”>‘`’D‘[˜m‘aΓ[^œ ”P¤§”¤‘a«7^•Â»-œw“´«0œ4«0”Ÿ‘‘a•h^¤i^“œw±¦µw”Á^“´«0‘a˜G“œ†”Ò%§ d –œ4˜0œ£œy˜G‘[œw±¦µw”[›¸ºÕöX^ œ• ‹Y† ‰‹Š¡³†¤ ”P’D«G˜0œw”`“œ ‰D^›Ÿ ‡ Ÿ4‰¢ồ ‘†”Pž’G‘a˜cö4œ®­ß’G‘†¾ ¢ ‘m”k ‹¥”P“‘ «6œ`”`˜G‘[œw›P‘a“=«G‘mœw”P’ª–˜D” ¢ «0”P’aŸ±Œ)«G˜0œw“-’D£@‘[˜DÊ[“ ^ œy”[ ^˜D”P›PÊ[“`^”4­ o –”>‘Ã’D‘[˜œw“œ4•h^’Gœwœ ”w¤§–˜c^¤ ‘[“´«0”w’Wœw’e•b^›´œw±1‘a’[ŸU¥ ”P¤ –˜c^¤ ‘[“´«0”‘[’D–‘a˜0œw-”ªœ¤•b^›´œw±[µw” d ­ °³‰P‡†8ó;Üœ4«G˜0œöP³a’e”w’¡ «G”P¤§”†-‘ d œ4˜Gž—”P“”m–œw˜Gœm”a›+“»”w£@˜G‘4Ÿ«G˜0œw“’*£@‘[˜c^”m”‰Q^›-Ÿ ‡ Ÿ4‰(õ£¤ ”P’*«0˜0œ`”[Ò%§ d –œ4˜0œ¿œ¿‘ ”P¤ –—”P’7^~±¦µw”£” ¡w ^~”`»4“=«7^ ”ŸaŒ‘[’*«0˜ ¢ « ¢ ˜Gœ¿-”Œ˜’Š/¤ ”P’*«0˜0œ2¾ ¢ ‘ª”{ e^~˜G”w›PÊ[“[^~”#‘a’D« ¡ ’G‘[“-”ë0˜Gœw“’D£@‘a˜7^~””g›+“»”w£@˜D‘J–œw˜Gœ#”g¥¤»^›wÊ[“[^~”–—”8^’‹Y†[^’*«6w“ ^ œ4’ ‹ ­Ô † ‰PŽõž‰¢ô ö ŠW‘Ð¥¤­Ô † ‰P‘,ó;˜ ö ŠW’0µ4”J¤tœ,^”P˜D‘[’]¾ ¢ ‘d”P’ ”P¤ –˜7^~¤§‘a“´«0”P’W‘[’D–‘a˜0œw”w’œw’ ^ œw’ d ­ æ‘¥¤­Ô ’0µ4”{‰Pt˜-ó5õ¤‘L‰Pt8ˆ ‡ ö w˜D‘[’G–—‘ «/^üöwœ4¤§‘a“=«G‘w5^~“[^ œw“”Jœ¤«0˜Gœw“’D£@‘a˜GÊa“ ^œœw’e[^’*«6w“^˜D”P›PÊ[“`^”4­ o –œw˜0œ†”a¥¤»`^~›PÊ[“`^”¢a ¡ ¾ ¢ ‘2” ”P¤ –˜c^¤ ‘[“´«0”†‘a’G–—‘[˜0œ4”§-‘ ¢ ¤tœ†•h^~›´œw±[µw”g¥¤­”GOQPSRUT7ÂÃVĘøXWÆÅYFZRÃDVmÂ[PÇ{Ä\ZYŽÇƒÈ¡Z]O“ÃQZ[Zúù\YFZÜB‰×kØBukØBu $Rî ¥- ï6 ¦¥ ¢ þ "§ ÿ ç §¢ Þ¨ v ÿ Ü¡ $ §%'& ÿ ë`ð+Ü ÿ ë þÞ ²lݧ/¢ þ § þÿ œw¤„^~“ š ”y«G˜0œw±[œw”`–—”P˜ ¢ ¤§œy–œw˜D«GÌ a¢ • œ-Â’G‘m¤ ”(öw‘[“-” ”P¤Âöw‘[•~” ^œw-‘Ç^“-Γ`^~«6œ'”£‘[’*«6œw-”” œwœ ¢ ¤”P’i¤§Ì~“[^¤ ”P’‘J‘a“‘[˜D›8^ œ-ŸR›¤” ¢ «G˜0œw’i–œw• œö>˜0œ4’[>³J” œw¤i^“ š ”‘‘¤«0˜0œ4“’7^~±¦µw”†œ®«0³Ì“[^~¤tœ2‘[“‘a˜G›8^œ ”P“‘ «0œw“” ˜G‘[œw›P‘[“´«G‘[’k‘2–-˜G”> ¢ «0”w’[[öX^ œÃ‘a’D«6œ4”§-‘«G˜0œw“-’7^±[µw” ‡ó^‰!‚9Ÿ¤‘a“=«G˜G‘Ç”P’§[^böw‘[˜D’G”P’`œ4•›P”P˜c^~«G¤§”P’m‘a’G‘a“Möw”P•böX^~”P’y–œ4˜0œ [¡ • a¢ •”P’GÒ%§ d ²”œw•›w”P˜7^¬«0¤ ”Ô–-˜G”4­Œ‹6š •~‘[›P‘a•SöP‘a¤ ’G‘a“”°• œ4˜G›´œw¤ ‘[“´«G‘ ¢ «7^•b^¦œ4”Ô‡õ8õ!ó’ ‚©Ÿô¨k«/^~•h^~¦œw“-”Í”–˜D”P›P˜0œ4¤tœ–—”P’D«G”–”w˜‘[’G’È@ó;˜,‚©£@”P˜0œ4¤õ˜G‘[œw•h^~¦œw-”P’ ¦¡ • [¢ •”P’“Ò%§ d –œw˜Gœ¿œ4’2˜D‘¦œw±1‘a’‘[“5öP”P•üöX^œw’“”¿¤ ‘ œ4“[^’D¤§”¡œw¤‘†œ£•b^›´œ4±¦µw” ‹ ­ )³Ÿ‰P‡†8†8ó ö Ÿz¥Jž’G‘a˜cö4œ®­ß’G‘†“œ`‘[’*«0˜ ¢ « ¢ ˜Gœ`”k ‹Y† ‰‹Š¡¾ ¢ ‘mœ`[^~’D«0w“ ^œ d ­öö ‘tœ¼[^~’D«0w“ ^œ ‹ ­ Ö³t‘]‰PŽõ,†8ó ö D^~“[^ œw“”¿¾ ¢ ‘t”_ e^-˜G”P›PÊa“[^”£‘a’D« ¡ ’G‘[“-”³§‘`‰Px˜;˜;˜–œ4˜0œ†‘[’*«6œw’•h^~›´œw±1‘a’[Ÿ‡ Ÿ4‰¢óóJ¤ ”P’D«G˜0œw”†”{Ò%§ d –œ4˜0œ†œÃ˜G‘[œw±¦µ4”g›+ºmöX^œ} ‹Y† -ŠŽŸ½¡œÃ‘a’D«0˜ ¢ « ¢ ˜0œ†”{ ‹Y† ;ŠŽ½¡œÇ‰D^›Ÿ³¦†-xÜ5ˆ-†8† ö Ÿ


.OQPSRUT7ÂÃVĘøXWÆÅYFZRÃDVmÂ[PÇ{Ä\ZYŽÇƒÈ¡Z]O“ÃQZ[Zúù\YFZ Ü’−61.876−61.896Energia (hartree)−61.916−61.936−61.956Perfil de Reação‰D^› ¢ ˜Gœ ‡ Ÿ4‰¢ôBÚJÒ%§ d –œw˜0œmœm˜G‘[œw±¦µw”m‘‘a•h^¤i^“œw±¦µw”Á^“´«0‘a˜G“œm”m‘a«7^•Â»-œw“´«0œ4«0”ÈöX^ œ– ‹Y† ‰‹ŠŽŸ


.Ü;˜OQPSRUT7ÂÃVĘøXWÆÅYFZRÃDVmÂ[PÇ{Ä\ZYŽÇƒÈ¡Z]O“ÃQZ[Zúù\YFZ−48.63−48.65Energia (hartree)−48.67−48.69−48.71Perfil de Reação‰Q^~› ¢ ˜0œ ‡ Ÿ9‰¢õ^ÚJÒ%§ d –œw˜0œ œ†˜G‘¦œ4±¦µw”m‘‘ ”P¤ –”w’7^±[µw”m” ¡w ^~”û-w“´«/^ ”`öX^ œ{ ‹Y† ˜’ŠŽŸ


.OQPSRUT7ÂÃVĘøXWÆÅYFZRÃDVmÂ[PÇ{Ä\ZYŽÇƒÈ¡Z]O“ÃQZ[Zúù\YFZ Ü ‡−61.86−61.88Energia (hartree)−61.91−61.94−61.96Perfil de Reação‰D^› ¢ ˜Gœ ‡ Ÿ4‰¢óBÚJÒ%§ d –œw˜0œmœm˜G‘[œw±¦µw”m‘‘a•h^¤i^“œw±¦µw”Á^“´«0‘a˜G“œm”m‘a«7^•Â»-œw“´«0œ4«0”ÈöX^ œ– ‹Y† ;ŠŽŸ


÷ ÿ¢¡¤£°þý¤¥§¦©¨¥ ¨ ¨¥yù ¨Ëü ø¥ œÔ‘Çœw• ”-,’m‘È« .,~’ ”P¤ œw‘ œw’ œw˜DžÂÐw“ œw’t•/“‘[œw˜G‘a’t‘04œw˜$ ¡ 0P‘’aŸ ’104œw•”P˜D‘[’‘a•‘a«G˜GÐP“¢ œ4’+–˜G”P–-˜ ‘aœw‘a’+‘[’*« ¢ œ4œw’+£@”P˜0œ4¤ú–˜$,¦»~¤§”w’+œw”P’204œw•~”P˜G‘a’¸‘Ž»–—‘[˜ ~¤§‘a“´«6œ~’[”Pž«-”P’¸–œw˜Gœªœw’+”P¤)‘a’$0-”2¤§³a”ª“œ”w˜G‘a¤Û‘43-65&798;:4¤ ”P•–œ4˜0œœ=< ¯ ‘45->5?‘A@–œw˜0œœ&”P’¡’D”wÎ’*« œw”P’¡‘ ”w“ ¢ “´«0”P’ª-‘£ ¢ “±‘a’J‘žœw’G‘†‘Æ»«G‘[“’Gœw’ª’0µ4” ”P¤ – ¢ «0œ ~”P“œw•­‘[“´«0‘ œw˜G”w’[]’G‘a“”¿–˜G”~ž~« böw”P’¡–œ4˜0œ`’ ~’D«0‘a¤tœ4’ ”P¤ –•‘Æ»”P’[Ÿ†¨k¤tœ`œ4•~«0‘a˜G“œ®«bö4œt‘a“ ”w“=«G˜0œwœ¤¢ ’D”È”¿¤ ³a«0”>”¿œw¬«üöP”£‘m‘[“‘a˜G›œ ”P¤õ£ ¢ “-±!>‘[’2‘§žœw’G‘ ”P¤õ–’G‘ ¢ ”P–—”w«0‘a“ œw•9Ÿ#"£@”e”¢ ’G” ” ¤§³Ž«0”>” &%(')+* Ÿœ~“œ-–œw˜Gœm’$’*«0‘[¤§œw’¤§œ”P˜D‘[’a-”œ(£@”k«0‘[’*«6œwœ ”P¤ ’ ¢ ‘[’D’G”R“” ¦¡ • [¢ •~”Í‘(œ4Γ~œw‘a’y–”w˜t–˜$,w«0”P“n‘"+’D«0œ·¤§‘Ž«0”>”P•”w›¢ « ¢ ˜G”w’[Ÿ £’G”m”m¤§³Ž«0”>”mœw¬«D0P”†‘‘[“-‘[˜G› œ†œ4«G˜0œE0P³a’k-‘ &%4')=*Ò ”P¤ £ ¢ “±‘a’‘ªžœw’D‘#œ4œw–­à¢¢ ”P–—”w«0‘a“ œw•e¤ ”P’*«0˜G” ¢ ­p’D‘ ”P¤ ” ¢ ¤§œt¤ ‘a«0”>”P•~”P›œ ‘ŽÎ ~‘[“´«0‘ë0œw¤Ãž—³[¤Ó–œw˜0œy”«0œwœw’ªœ4”`–’G‘¢ ”Í”w’§¤ ‘ œw“’D¤§”w’†‘¼˜D‘¦œw±[µw”Í-‘¼‘a•.¤F“œw±¦µw”G“´«0‘a˜G“œ"‘`»œ4“=«0œ4«0”w’[Ÿ ’ ˜G‘[’ ¢ •~«0œw”P’‘a’D«S;T


‘[’D’G”£‘[“-”w«0³a˜G¤F ”-œw–˜D‘[’G‘a“´«6œw“-”x04œw˜$ œw±[µw”y‘m‘[“´«0œw•–œt‘y35{z17 œw•|:4¤§”w•9ŸC8 ¡ –œw˜Gœ£”–˜D” ”P¤ –•~‘Ž»”#­(M}H h q¤j~Q$Hrq(uMwH h qkj~Q HrqYKH&Mwv+KQM Hrq(sQƔÖ˜D” ‘[’G’D”m³ªœw•~«0œw¤ ‘[“´«0‘»-œw“´«6œ®«0”†¤§œ’ ” ”P¤€FqYv¤­ ? T S 7 œ4•‚:4¤ ”P•9Ÿr"’*«6œt~£@‘[˜D‘[“±[œt’G‘#‘0w‘†Å £@”w˜G¤§œw±¦µw” ” ”P¤ –”w’D«0”‘Æ»-”4«0³[˜D¤#¢ ‘–”P˜k’ ¢ œyœw•~«0œ –-• œw“œ4˜ œw‘‘‘a•” œw•/.ƒ[œw±¦µw”m‘a•‘a«G˜GÐP“ œ ³¤§œ’‘a’D« ¡ 0w‘[•¸¾ ¢ ‘Ô‘a’D«~•ž—‘[“”-—¾ œw˜Gœ «G‘[˜$.ƒ¦œ4”P’J–—‘[•~”P’¡¤ ³a«G””w’&K9Ok % ‘ '…„ H¡Ÿ ¯ œw˜Gœy”y‘a« •»-œw“´«6œ4«G”¦”Pž’D‘[˜)0wœ½­p’G‘¾ ¢ ‘£@”P˜Gœw¤–˜G” ‘a’G’D”P’e’Gµw”J‘[“-‘[˜G›w‘a« œw¤ ‘[“´«G‘²–—”P’G’DÌ/0w‘!’aw–—”’ œw’Wžœw˜D˜G‘!~˜0œw’W‘²‘[“‘a˜G›œk’Gµw”¡–˜$,4»9¬­œw¤žÂ”P’]”P’UWVYXZ![Y\I]_^a`cbdUJ^JefU2](\hgjiJk_gkXklYg9X_k4U4[Imon-V&gSpœ4˜0œ†” ”P¤ –”w’D«0”†¤§œ~’d’ ~¤§–•~‘[’²­_Hrq(stHrq(utKH&Mwv+KQ Hrq4s®œm˜D‘¦œw±[µw”F"¸º]¤§”P’*«0˜D” ¢ ­p’D‘ ¢ ¤¯‘Ž«•~‘[“”-Ÿ’‘[’D«0œw”P’k‘«0˜Gœw“’ ~±¦µw”m–˜D”P–—”P’D«G”P’–œw˜0œ†”P’k¤ ‘ œ4“’D¤§”P’¹-‘2˜D‘¦œw±[µw” ”P’”~’¹»-œw“´«0œ4«0”P’¡ –œw˜0œ#”#»-œw“´«6œ4«G”†–˜G‘ [¢ ˜D’G”P˜¹”†‘a’D« •ž—‘[“-””–˜G” ‘a’G’G”N0- œCO4KjM)‡ˆQ/³J‘[“‘a˜G›P‘Ž« œw¤ ‘[“´«0‘¤§œw’[Ÿ†8¡ 0P‘a•J‘[¤ ˜G‘[•œw±¦µ4”œw”‰O4KjM}zQŽŸŠ‘Ž­ß’G‘(‘Æ»-–-•”P˜Gœwỹ”·‘a’D« ¢ ”°”¤§‘ œw“’G¤ ”·‘£ˆœE0P”w˜˜D‘¦œw±[µw”m‘” ¢ «0˜D”P’d»-œw“´«6œ4«G”P’–˜G‘ [¢ ˜D’G”P˜D‘[’[ ¢ ’Gœw“”§œm¤§‘Ž«0”>”P•”w› œ2œw–•/ œ4œÃ“‘[’*«0‘«0˜Gœwžœw• š ”Ÿ


‹ ù Œ¡¤¤Ž ¨ ‹¥ üx¼ýÓü¼ý‘Èøa¥ Ñøa¥ ’ ÿ)þj“°ýÑþø¥ ¨¥ ü¼ý¤ÑøaÑø¥


SžVYX_–e(—YmtU2k˜VbxkšgŽ[hlN\J[Y\Il4VBg—JV&g›‰^J]Iœ4U&\I] VBgxk_g [Y\I—JVB—JV&gS(9)H(4)H(5)C(2)C(6)H(8)H(3)O(1)S(7)Ÿ › ¢ ˜0œ


SSVYX_–e(—YmtU2k˜VbxkšgŽ[hlN\J[Y\Il4VBg—JV&g›‰^J]Iœ4U&\I] VBgxk_g [Y\I—JVB—JV&gS(2)C(1)S(3)Ÿ › ¢ ˜0œ


­ 5-Ÿ65 S 35? ž 5-Ÿ>555555 ­…5-Ÿpž;••¥p;T­ 5-Ÿ•¥Sžp z¥? 5-Ÿ>555555 ‡wŸ63 T ‡o35 •H(14)H(13)C(8)C(9)C(10)H(15)H(12)C(7)C(6)C(11)H(16)H(3)C(1)C(2)H(4)H(26)C(21)C(5)C(17)H(22)H(25)C(20)C(19)C(18)H(23)H(24)‡o55VYX_–e(—YmtU2k˜VbxkšgŽ[hlN\J[Y\Il4VBg—JV&g›‰^J]Iœ4U&\I] VBgxk_g [Y\I—JVB—JV&gŸ › ¢ ˜0œf


‡o5‡VYX_–e(—YmtU2k˜VbxkšgŽ[hlN\J[Y\Il4VBg—JV&g›‰^J]Iœ4U&\I] VBgxk_g [Y\I—JVB—JV&gS(2)H(9)H(8)C(5)C(1)H(11)H(12)C(6)C(10)H(13)H(7)O(4)S(3)H(15)H(14)Ÿ › ¢ ˜0œ


5-ŸS ? S z T 5 5-Ÿ>555555 ‡wŸ{z •¥pS 3 S­5-ŸS ? S z T 5 5-Ÿ>555555 ­ª‡PŸ6z •pS 3 S­‡o5;zVYX_–e(—YmtU2k˜VbxkšgŽ[hlN\J[Y\Il4VBg—JV&g›‰^J]Iœ4U&\I] VBgxk_g [Y\I—JVB—JV&gH(3)H(4)C(1)C(2)H(6)H(5)Ÿ › ¢ ˜Gœ


‡o53VYX_–e(—YmtU2k˜VbxkšgŽ[hlN\J[Y\Il4VBg—JV&g›‰^J]Iœ4U&\I] VBgxk_g [Y\I—JVB—JV&gH(3)O(2)C(1)H(6)H(5)H(4)Ÿ › ¢ ˜0œ


‡o5?VYX_–e(—YmtU2k˜VbxkšgŽ[hlN\J[Y\Il4VBg—JV&g›‰^J]Iœ4U&\I] VBgxk_g [Y\I—JVB—JV&gS(7)H(10)H(11)C(1)H(12)O(5)C(4)H(13)C(2)C(6)S(3)H(9) H(8)H(14) H(15)Ÿ › ¢ ˜Gœ


‡o5 TVYX_–e(—YmtU2k˜VbxkšgŽ[hlN\J[Y\Il4VBg—JV&g›‰^J]Iœ4U&\I] VBgxk_g [Y\I—JVB—JV&gH(28)H(29)C(19)C(18)H(27)C(17)C(20)H(30)C(14)C(16)H(26)H(13) C(10)H(12)C(11)H(31)H(1)C(21) C(15) S(3)H(32) C(22)C(25) H(35)C(23) C(24)H(33) H(34)S(2)C(4)O(5)H(9)C(6)H(7)H(8)Ÿ ~› ¢ ˜Gœ


VYX_–e(—YmtU2k˜VbxkšgŽ[hlN\J[Y\Il4VBg—JV&g›‰^J]Iœ4U&\I] VBgxk_g [Y\I—JVB—JV&g‡o5 pœwžÂ‘a• œN”P˜G-‘[“œwœw’(Hdœw˜D«G‘[’ œw“œw’”yO4KjM…‡ˆQd”y¢ªœw“´«6œ®«0” ¯ ˜G‘ a¢ ˜G’D”P˜k”F"’*«~•ž—‘[“”O” » ¤ ƒ3 Sžž 55 ‡PŸp z¥? pT ‡K©MwzQ ­ª‡PŸ>5;z53z p ­ 5-Ÿ• z5 ž ? S ­ 5-Ÿž ‡o5? p 5K©M}3;Q­…5-Ÿ6z5 ž ‡‡o5 ­‡PŸžS 55 T ? ‡PŸS;T 3;z ••HMP?cQ­ª‡PŸD‡ •T ‡ • z ­‡PŸž;•žSS 5 5-Ÿ¦? ••T 35 M T Q ­)zŸ>5 • 55 •ž ­…zŸžpž;• 5 ž 5-Ÿ¦?cz S;T¥S 5HM p Q­…3-Ÿ>55‡ pp ‡ ­ 3-Ÿ>5 • 3 •TT ­ 5-Ÿppžpžžq§M • Q­…3-ŸT• z Sž;• ­ 3-ŸS;TT• z¥3 ­ 5-Ÿ>3 • ‡ p 33q§M ž Q­…3-Ÿp;T ‡o5 • ? ­…zŸD‡ SS 33 p ­ 5-Ÿ••• ?‡‡q§M S Q ­)zŸ¦? T z T 53 ­ 3-Ÿ6z T ‡ •p ? ­‡PŸTSžpp ‡HM…‡o5;Q ‡PŸž ‡ ž ??cz 5-Ÿpž 53 ž 3 5-ŸD‡ p ? p ??HM…‡‡ˆQ ‡PŸp ? p 3? p 5-ŸTžSS z¥? ‡PŸTpp 39‡ˆzq§M)‡ˆzQ ‡PŸ6z3 Sp z ž ‡PŸ¦?;3;z¥35 ž ­ 5-Ÿ>3 p;• 3;z¥5q§M)‡o3Q zŸ¦? •T 5;z p 5-ŸD‡o333‡o3 zŸD‡‡ˆz T ‡ THM…‡E?cQ zŸp ? p 5‡ T ­ 5-ŸD‡ ••ž ? S ­ 5-Ÿpp;T 5‡ THM…‡ T Q 5-ŸSS;•TS 5 ‡PŸ• 3 • 35 T zŸ>353 SS ‡HM…‡ p Q zŸpžSS 33 5-Ÿ>5 ž z-‡ˆz T ­…zŸ>5 Tp ? SpHM…‡ • Q 3-Ÿ¦? p ?;zz • ­ 5-Ÿ• ‡ Tp ? p ­…zŸS 5 T 353HM…‡ ž Q ?ŸD‡ žSTS ‡ ­‡PŸ•S;• ‡‡ p ­…zŸ>3 • 5;z p•HM…‡ S Q ?ŸD‡E?cz?;53 ­…zŸ>5 •p;TT¥ž ­ 5-ŸSžžž z¥3HM}z5;Q 3-Ÿ>3 •ž 3? S ­‡PŸ6z • ‡ T• 5 ­ 5-ŸD‡o3 S ‡ T¥pHM}z9‡ˆQ ‡PŸp;T ? Sp z zŸ>3;z9‡ p;T 3 3-Ÿ¦?;53 TT 5HM}zzQ ‡PŸ>5 p ?3;zz 3-Ÿ>3 žpž 5 T ?ŸD‡o5? pS;•HM}z3;Q ­…5-ŸD‡ S z T 3 S 3-Ÿž;•SpS ‡ 3-Ÿ• ‡‡ˆzz žHM}z¥?cQ ­…5-Ÿž;TTT¥S 3 3-Ÿ6z S 39‡ S;T zŸp ‡ •T¥ž 5HM}z T Q ­…5-Ÿ6z pž;T ?? zŸ6zz3 S;Tž ‡PŸS z9‡ ST•q§Mwz p Q zŸD‡o53 TT ? 5-ŸS 5‡E3 ž 5 ­…zŸ¦? pp ‡o3 •q§Mwz • Q 3-Ÿ¦? S z •Tp ­ 5-ŸT ‡o5 •pT ­ 3-ŸS;• z¥? ž ‡q§Mwz ž Q ?Ÿ•ž ? S 35 ­…zŸ¦?cz •TT• ­ 3-Ÿ>5;z ž 5;z Tq§Mwz S Q ?ŸpS 3 Tpp ­…zŸS z9‡ ž ‡ S ­ 5-ŸTž ? p ? •q§M}35Q 3-Ÿ>33 T ‡o53 ­‡PŸT 5 p z33 5-ŸS ‡ S ‡ T ‡q§M}3‡oQ zŸp z S ‡o3 • ‡PŸS ? ppS 5 3-Ÿ• ‡E?cz¥5 pq§M}3;zQ ‡PŸTž 3¥? T• 3-Ÿž z S ‡ S ? ?ŸS;T 3‡ S 5q§M}33Q ­…5-Ÿp;T z3 Tp ?Ÿ• 53 S ? S ?Ÿ6z T 3;z p 3q§M}3?;Q ­ª‡PŸž 3 TpTž 3-Ÿp;T• z •T zŸ>3‡ T 5z pq§M}3 T Q ­…5-Ÿž 5 T zz T ‡PŸ•T 3¥?;3? ‡PŸD‡o5‡ ž 3 ž


‡o5 •VYX_–e(—YmtU2k˜VbxkšgŽ[hlN\J[Y\Il4VBg—JV&g›‰^J]Iœ4U&\I] VBgxk_g [Y\I—JVB—JV&gS(8)H(6)C(2)H(7)S(10)C(9)O(11)H(4)C(1)H(3)H(5)H(15)C(12)H(14)H(13)Ÿ › ¢ ˜Gœ


‡o5 žVYX_–e(—YmtU2k˜VbxkšgŽ[hlN\J[Y\Il4VBg—JV&g›‰^J]Iœ4U&\I] VBgxk_g [Y\I—JVB—JV&gH(23)H(24)C(14)C(15)H(25) C(9)C(13) H(22)C(12)C(11)H(21)H(27)H(8)C(6)C(5)H(7)H(26) H(35)C(16)C(10)O(2)C(20) H(30) H(34)H(32)C(17)C(31)C(18)C(19)H(29)H(33)H(28)C(3)S(1)S(4)Ÿ ~› ¢ ˜0œ


VYX_–e(—YmtU2k˜VbxkšgŽ[hlN\J[Y\Il4VBg—JV&g›‰^J]Iœ4U&\I] VBgxk_g [Y\I—JVB—JV&g‡o5 SœN”P˜G-‘[“œwœw’(Hdœw˜D«G‘[’ œw“œw’¹-”#O4KjM}zQd”N¢ªœw“´«0œ4«0” ¯ ˜G‘ [¢ ˜D’G”P˜k”F"+’D«~•ž—‘[“”Oeœ4žÂ‘a•” » ¤ ƒ53?cz¥35 ­ 5-Ÿp ‡ S ?? p ­‡PŸ>5‡ p 5;z? M}zQ ­…5-Ÿ>3 Tž;T ‡ • ­‡PŸ>3 • 3‡ ž ? ‡PŸ¦?cz9‡ • z9‡HM¨3;Q ­ª‡PŸD‡ T z • 3 T ­‡PŸ•T ? T 33 5-Ÿ6z S 35 S ‡K©M¨?cQ ­)zŸ>5? p ‡oz9‡ ­ 3-Ÿ6z5?cz3z 5-Ÿ¦?;5‡o5 ž ‡HM T Q‡PŸž 5‡ • 5 S 5-ŸT•p 3‡ S 5-ŸD‡ˆzzz¥35HM p Q‡PŸTTp z¥? ž 5-Ÿ¦??‡ S 3 S ‡PŸ¦? S;T z¥3 pq§M • Q‡PŸ6z T 5 T ‡o3 ‡PŸ>3? pT 5;z ­ 5-Ÿ¦?‡‡o3;z?q§M ž QzŸ6z •p z S ? ­ 5-ŸD‡E? • ‡ T• zŸ>5 p;Tp•SHM S QzŸpp;• z S;• ­ 5-Ÿ6z Tp 5 pp ­ 5-Ÿ• 5 ž ? T¥žHM…‡o5;Q 5-ŸžSST z5 ‡PŸT ? žTp 5 zŸ6z ž;T ‡!?;5HM…‡‡ˆQ zŸp zz žS z ­ 5-Ÿ>5 TS ? Sž ­…zŸD‡o5 •TS 3HM…‡ˆzQ 3-Ÿ¦?‡ SS;• 3 ­ 5-Ÿž 3;z •ž 3 ­…zŸSp 5 • ? žHM…‡o3;Q ?Ÿ6z p;T•• z ­‡PŸž ‡ Tž z¥3 ­…zŸ¦?‡ •ž;•THM…‡E?cQ ?Ÿ>3;z9‡‡ ž 3 ­…zŸ>5;z53‡ T ­‡PŸ>5;zz •žžHM…‡ T Q 3-ŸT z • 3 T z ­‡PŸ6z¥? p ‡ ž ? ­ 5-ŸD‡ • z ž z?HM…‡ p Q ‡PŸ¦? ž ‡ SSp ‡PŸS;• ‡ T•ž 3-Ÿ¦? S;T ?‡E?HM…‡ • Q 5-Ÿžž;T ‡ • 5 zŸSžS• ‡ ž ?Ÿ6z Tž;T¥ž zHM…‡ ž Q ­…5-Ÿ>3533 S ‡ 3-ŸTSpS;T z 3-Ÿž ‡ p ‡oz SHM…‡ S Q ­…5-ŸžS z9‡ •ž 3-ŸD‡ • ‡ žSS zŸp ‡o5 žžSHM}z5;Q ­…5-Ÿ6z SS;•¥p;T zŸD‡ T 59‡ •ž ‡PŸž;T ‡ S z9‡q§Mwz9‡oQ ‡PŸS ?‡ T ? • 5-Ÿp;•žp;TS ­…zŸT zz Tžpq§MwzzQ 3-Ÿ>3 • 5¥?czz ­ 5-Ÿpž ?? S• ­A?Ÿ>53 p z T 5q§Mwz3Q ?Ÿž;•Sž ‡ S ­…zŸ¦?cz p 3 pS ­ 3-Ÿ>5 •• 5;z Tq§Mwz¥?;Q ?ŸS;•pž 3 S ­…zŸ•ž 35;z ž ­ 5-Ÿp 5 SS;TTq§Mwz T Q 3-ŸT•S z33 ­‡PŸ¦?‡o3 Tp ‡ 5-ŸžSž;T ‡ •q§Mwz p Q zŸ¦?;5 p ‡ ž z ‡PŸT ‡‡E33 T 3-Ÿž ?cz5 •Tq§Mwz • Q ‡PŸ>3? ž z¥?;3 3-Ÿ>35 ž••S T ŸD‡ S 5 p 3 pq§Mwz ž Q ­…5-Ÿ•p;•S•p ?Ÿ>3 ž;T• 53 ?Ÿ¦?;5? p ‡ pq§Mwz S Q ­ª‡PŸž ‡ S;T z¥? 3-Ÿp z T ? • 3 zŸ6z pp;•TTq§M}35Q ­…5-Ÿ•ž;T z TS ‡PŸž 5? TSp 5-ŸS ?cz •¥ž;•HM¨3‡ˆQ ­…5-Ÿ¦? p;T 3 •T ­…zŸ>5‡ • 33 S zŸ• 33‡ žžq§M}3;zQ 5-ŸD‡ S;T z pS ­‡PŸ¦?;3 SS 3 ž 3-Ÿ>3 ž;TTT ?q§M}33Q ­ª‡PŸT 5‡ˆz • z ­‡PŸS;Tž z¥? p 3-Ÿ>5 • z S 5?q§M}3?;Q ­…5-ŸD‡E? • 3 S 5 ­ 3-Ÿ>5 TžS 5¥? zŸp;TT 5z pq§M}3 T Q 5-ŸTppžž;• ­ 5-Ÿ¦? ppž 5 T ‡PŸ>3‡ˆz S z5


‡‡o5VYX_–e(—YmtU2k˜VbxkšgŽ[hlN\J[Y\Il4VBg—JV&g›‰^J]Iœ4U&\I] VBgxk_g [Y\I—JVB—JV&gH(6)S(5)H(8)O(2)C(3)H(7)C(1)S(4)H(9)Ÿ ~› ¢ ˜Gœ


‡‡‡VYX_–e(—YmtU2k˜VbxkšgŽ[hlN\J[Y\Il4VBg—JV&g›‰^J]Iœ4U&\I] VBgxk_g [Y\I—JVB—JV&gH(28)C(15)C(16)H(29)H(27)C(14)C(17)H(30)C(13)C(12)H(26)H(34)C(6)C(1)C(2)H(35)H(22)C(11) C(7)H(20)H(21)H(33)H(32)C(5)C(4)C(3)H(31)S(8)S(10)C(9)O(18)H(24)C(19)H(25)H(23)Ÿ › ¢ ˜Gœ


VYX_–e(—YmtU2k˜VbxkšgŽ[hlN\J[Y\Il4VBg—JV&g›‰^J]Iœ4U&\I] VBgxk_g [Y\I—JVB—JV&g‡‡ˆzœwžÂ‘a• œ


÷ ÿ¢¡°ȳý¤¡Öü£ÿ¢¥ ‘¨ ±õý¤¡¤² ¦©¨¥ ‘¨ ® ø¥§¨_H¹¸ô $»º;¼¸F½µ&¾P»º¿!-µ!ÀÁ½µ+´Â³¥À µC”r5xM}3‡ˆQ¹µ=”Y‡;M}3‡‡o:9‡‡ˆQóijy¸Fq(/½Ä ¸ÅÆ!º/¸·Oh³´µ!|³y”Y·D‡H¹¸9µtÈÂÉ!/µ!º;¼µ "WÇ9í¸-µ!º;¼µ‹ ù Œ¡¤¤Ž ¨ ®‡K ‡o3·>55 •• 5·>533 Tz#K ‡·Sp z9‡ 5·6z3? •5·¦??? T 5·ž ‡o3 ž 31K5·D‡ˆz9‡ S ‡·>5555 ‡K5·>53 p 5 ‡·>5555 ‡Kz9·6z555 ‡·>5555 ‡fʇfÊ 5·TT 55 ‡·>5555‡‡o3


HKVYX_–e(—YmtU2kÌËBbÍUJ^Je+έ\hey[¹^ÁgÏ—Bk˜Ð&\IeÑJiJk_gx—Bk˹V&gk‡‡E?”(·{z9 H¹¸º$»º;¼¸Ò½µÓ¾P»º¿!-µ!ÀϽµÓ´Â³À$µÔ”r5ÌM}3‡‡ˆ:9‡‡ˆQFµ©”Y‡ÕM}3‡‡o:9‡‡ˆ:9‡‡ˆ:9‡ˆQNÃÂ³Ä ³Ò¸Hr³Ä$´­¸º¸Ö Ç9.Åƺ.Ņµ="†º9Ç9¸¾PÄ$µ·Oh³´µ!|³"WÇ9í¸-µ!º;¼ µ H¹¸9µtÈÂÉ!/µ!º;¼µ H¹¸9µtÈÂÉ!/µ!º;¼µ‡CKÊ ?·6z žp 5 ×…5·6z5‡ T 5·D‡ˆz S zzyKÊ ‡·>5? p 5 59·/‡‡‡ˆz 5·¦?‡ T¥p3FKÊ 5·>3?? • 59·S;•¥pž 5·p 5 • ?‡CKÊ 5·D‡‡ˆz ž ‡·65555 ‡·>55555·>5?;3 ž ‡·65555 ‡·>5555‡CKʇ·p 555 ‡·65555 ‡=L‡=L 5·¦?;555 ‡·65555‡ Ÿ 5·ž 555 ‡·65555‡CKÊ ?·6z žp 5 ×…5·6z5‡ T 5·D‡ˆz S zzyKÊ ‡·>5? p 5 59·/‡‡‡ˆz 5·¦?‡ T¥p3FKÊ 5·>3?? • 59·S;•¥pž 5·p 5 • ?‡CKÊ 5·D‡‡ˆz ž ‡·65555 ‡·>55555·>5?;3 ž ‡·65555 ‡·>5555‡CKʇ·p 555 ‡·65555 ‡=L‡=L 5·¦?;555 ‡·65555‡ Ÿ 5·ž 555 ‡·65555‡CKÊ ?·6z žp 5 ×…5·6z5‡ T 5·D‡ˆz S zzyKÊ ‡·>5? p 5 59·/‡‡‡ˆz 5·¦?‡ T¥p3FKÊ 5·>3?? • 59·S;•¥pž 5·p 5 • ?‡CKÊ 5·D‡‡ˆz ž ‡·65555 ‡·>55555·>5?;3 ž ‡·65555 ‡·>5555‡CKʇ·p 555 ‡·65555 ‡=L‡=L 5·¦?;555 ‡·65555‡ Ÿ 5·ž 555 ‡·65555


Ø ¨ÕÙ_¨ÕŒ¡¤ÒŽÚ¥ ® jÛÕþŽ¦ÿÜaGÝßÞàÒÚ¥Ä µ/¼ ãÁ.µÀ µÄ!Ö


• â&ÿ«¸/¼ µ!ÄÖ Ÿ ·Dä1P4.Ä /ɪåjÖÂK·/ä K-¼µ.ºjÖæ8·!8 < ï9ë¨ì FIHHIC< @#REJE%3z9‡ S ·á‡ž âCH¹.³µ!ÀÖS¤†·Dä çÁãr³À$º.µtãÁÀ 7cwÖBK­·Dä LYµ.µ!»ƒ!µÖ * ·YK­·/ä Ÿ ijº¿¸.ÀÖ(8·YÊI·.8 M«í( T; ë¨ì~ïæðtë á‡-jöÂ÷ªíoðªöÂ÷ ùSV FIHHI ` JW,% p 3·US â .D0µ.ij9Öq=·ÂÊh· * ·/äxH¹¸À$À /µ!./¸Ö „ · Ÿ ·/äèHIC #R,JE%3? •¥S ·á‡p â * Å´­¸º;¤µ!´}Ö ·æÊI·/ä „ »À À$¸Ö­8·/ä „ »À À ¸Ö ' ·æqC·étêÂë 8 òrê¬ðªí( >! #"% žp;T ·á‡FHH>X! "]%­z ž ‡·¡ ³À$¼ µ!/ŵ!ÄÖæ8·/äq(»9¼Éªå/ºÅÀ!Ö * · ¡ ·^8 :9Yù õhöÂ÷ ù:; íoð DC< @#,AE?B% p ? žS ·ázzâ„ ·^¤·jétê¬íì}ó;ôêÂñwð1õhöÂ÷ ù ñ.útë}ì~û,_¥¹ì~ñ‚ê¬ðtñ`*>(.÷ªú#íáz3¥â=q4»åµ!µt¤ÖI8·¬"Á·DäÒç&µ!D¼µ!ÄÖj"J·j


l4kÐ2kl(–eUWm VBgxËšm…Ër]Žmt^.KÁl'LBÐWmtUWVBg‡‡ •³ý#µÄ!ÖHY·­8·^&úªúo÷têÂë}ñ¨ô,(6úNíFõší ù *ï-ëwôë}ñwíêô,(õhöÂ÷ ù ñ.útë¨ûE_i-jöÂ÷ªíì~ñw÷ªúfôêîMÔí!î-÷)(6úªü_8¸åºá3;zâCH¹Ä"ºÅ|³º½jÖæz55z9·ÿÌ/.µ¤G¢K9¸ºÀ!Ö¤-OÁLf„ ·Dä#ÊI¸.D¼}Ö „ ·K­·Dä#K9µ!Å;³¥|³Ö * ·DäFqY³/½»7µ¥Ö „ ·3¤·cH>F! ^" ` %á33¥âCH¹»À)¼¸-½.¸ÖT¥S · ‡7-/ºÀ!Ö9Êh·;ÿ ·Däyq(¸/7µÄ!Ö98·9K­·-"Á·Däyq(¸../½Â³E¤Ö


zâ=ʆ»Ä)09/À ' ' ' Ö ¡ ·ÂLf·Dä ”¹³Ä /µ¼ ¼!Ö „ ·8·^8 õhöÂ÷ ù ö-ûˆú >F! 0Z6?B% ‡ S ‡E5·áT3¥âCK9É»À µÄ .³Ö ¡ ·"Á·DäfK9ɪåµ!/ºµ!ÄÖc


U ¦Á÷)oñ.útñwíê 9. „ V ü ¡ ³»À$À |³¥ºjÖ ' ºÉ¥·/ _ʆ/¼$¼À ´»Ä ÅåxÊå;¼ýFwÖ-³Éµ!À$À³½Â³Fµ!ý * ³.¸Fz55 T ·ápS5¥â Ÿ Ä /À ɪåjÖ * ·28·/ä°OhÄ$»Éª7cÀ!Ö ¡ ·Žÿ ·/ä K9ɪå.µÅµ!}ÖWq=·W”(·/ä K9É!»À$µ!Ä$|³Ö ¡ ·I"J·/ä „ ¸´´jÖ * ·W=! §R,RE%æ?? S ·á•žá•S âCH¹.³µ!ÀÖ¤·Dä Ÿ Ä ³º¿¸.ÀÖæ8·ÂÊh·Dä L(µ!.µ»ƒ!µ¥Ö * ·æK­·!8 õší ù *ï-ë õhöÂ÷ ù FIHHY=! "JE%­z5;z¥3·


9 ê étêÂë¨ìªí!îïÂðtë¨ñwíêl4kÐ2kl(–eUWm VBgxËšm…Ër]Žmt^.KÁl'LBÐWmtUWVBg‡ˆz5áž 5¥â=q(³Ä Ä$.À!ÖLC·_


¼¸-½¸ *k“Cñ‚êÂñ‚ë¨ñwíÖæz S

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!